柴油机内部EGR的数值模拟分析

应用大型通用CFD软件STAR-CD及网格生成软件ES-ICE,对带有内部EGR的柴油机进气及压缩过程缸内三维瞬态流场进行数值模拟研究,并分析其组分浓度及温度的分布情况,通过研究掌握内部EGR对缸内温度、浓度场的影响,为进一步研究内部EGR对缸内燃烧的影响奠定基础。     

Event vertex and time reconstruction in large-volume liquid scintillator detectors

Large-volume liquid scintillator detectors with ultra-low background levels have been widely used to study neutrino physics and search for dark matter. Event ve...     

低温甲醇洗系统贫富甲醇换热器泄漏原因分析及处理

介绍了晋煤天溪煤制油分公司低温甲醇洗系统贫富甲醇换热器的泄漏情况。分析了贫富甲醇换热器泄漏初期生产运行指标的异常现象和造成泄漏的原因,认为泄漏是不同物质对设备的腐蚀、冲刷造成的,并针对泄漏的具体情况,提出了不同的检修处理措施:管束泄漏量低于10%时,可采用焊接锲形堵头将泄漏列管两端进行封堵;管束泄漏量高于10%时,如换热器设计余量足,可将封头内部隔板取出,短接进出口;将换热管材质由10#钢换为06Cr19Ni10不锈钢。     

碳酸镉转化制备氢氧化镉及产物光催化降解性

用碳酸钠溶液直接混合硫酸镉溶液制备了沉淀碳酸镉,再以沉淀碳酸镉为基体,氢氧化钠溶液为转化剂,通过阴离子交换制备出氢氧化镉纳米材料。采用X射线衍射仪（XRD）和场发射扫描电子显微镜（FESEM）对沉淀碳酸镉和转化产物的结构和形貌进行了表征。结果表明,沉淀碳酸镉的结构遭到破坏,转化完全所得到的氢氧化镉的形貌完全不同于沉淀碳酸镉,为片状组装的不规则球体。紫外光照射下光催化降解罗丹明B染料测试表明,转化产物比沉淀碳酸镉具有更好的光催化降解性能,转化时间不同的产物表现出不同的降解效率。当20 mg的转化产物分散到50 mL 8 mg/L的罗丹明B染料中,在黑暗环境中磁力搅拌吸附120 min达吸附平衡,开启300 W紫外汞灯后,效率最高的转化产物可在180 min内将染料完全降解。     

水泥厂余热发电对系统短路电流的影响 及限制措施

某些旧水泥厂设计时未考虑短路电流余量,余热发电与水泥线总降压站系统并网运行后,最大短路电流会超过断路器的遮断容量,会对水泥厂原有电力系统造成损害。为了保证系统的安全运行需采取相应的限流措施保证电力设备安全,以伊拉克MASS集团25 MW余热发电改造项目为例,说明采用限流电抗器,采用快速限流装置和改变接线方式这三种不同限流方案的应用结果。     

用于矿山等极端环境中的高精度定位算法

高精度室内定位技术在矿山、建筑、施工等多种极端环境下都有需求。基于超宽带通信(Ultra Wideband,UWB)的室内定位技术能够提供较高的定位精度,但超宽带信号易受到障碍物的干扰,并且在类似矿山等极端环境中,障碍物不可避免。因此,超宽带非视线传输(Non-Line-of-Sight,NLoS)测距成为当前的一个研究热点。当前研究大多集中在识别和消除非视线传输对超宽带测距的影响上,实际应用中,大多数情形下超宽带信号根本无法穿透障碍物,会导致定位标签只能够与2个或1个信标节点通信,但完成三边定位至少需要3个信标节点。为此,提出了一种基于目标行为分析的定位算法,该算法能够在短时间内仅剩余一个信标节点与标签通信时,也可实现高精度定位。该算法以超宽带通信为基础,使用信号飞行时间(Time of Flight,TOF)算法测距并定位。通过分析信号正常时的目标运动轨迹来判断其速度和方向,当信号不正常时(可通信的信标节点减少),可利用预测的速度和方向参数来实现辅助定位。将该算法部署在一个基于超宽带定位的系统中进行了测试,结果表明:当能够与标签通信并完成TOF算法的信标节点数量少于3个时,基于NLoS传输识别和消除的算法无法完成定位,而基于目标行为分析的定位算法依然能够实现定位,在单信标节点区域的平均定位误差为0.93 m,最大误差为1.41 m,在2个信标节点测距的区域,平均定位误差为0.64 m,最大误差为1.2 m。     

基于昂普分析的黄冈大别山世界地质公园旅游开发研究

黄冈大别山世界地质公园拥有4大类12亚类53处地质遗迹资源,为中国自太古代以来的中央造山带形成演化的天然实验室,大别山地区旅游资源丰富。游客量和旅游收入逐年稳步增加,但公园旅游客源地空间的集中程度高,以湖北省武汉市游客为主,外省游客以周边地区居多。游客出游距离以短程为主。旅游业向着多元化和融合创新的全域旅游发展,而地学旅游资源产品单一化对于大众游客缺乏吸引力,以地学旅游为核心的旅游形式和内容需要再进一步开发。通过昂普分析,提出了具体的地学旅游资源开发对策与措施,旅游产业融合产业创新,提高公园旅游一体化服务水平,打造地质与人文一体旅游,发展以世界级地质公园地学旅游为主的多元化旅游活动和旅游产品,打造有效的地学旅游宣传推广体系。公园作为地学和文化综合旅游目的地,应加强区域间旅游合作建设,拓宽公园旅游市场。     

Structural and Functional Characterization of 4-Hydroxyphenylacetate 3-Hydroxylase from Escherichia coli

The hydroxylation of phenols into polyphenols, which are valuable chemicals and pharmaceutical products, is a challenging reaction. The search for green synthetic processes has led to considering microorganisms and pure hydroxylases as catalysts for phenol hydroxylation. Herein, we report the structural and functional characterization of the flavin adenine dinucleotide (FAD)-dependent 4-hydroxyphenylacetate 3-monooxygenase from Escherichia coli, named HpaB. It is shown that this enzyme enjoys a relatively broad substrate specificity, which allows the conversion of a number of non-natural phenolic compounds, such as tyrosol, hydroxymandelic acid, coumaric acid, hydroxybenzoic acid and its methyl ester, and phenol, into the corresponding catechols. The reaction can be performed by using a simple chemical assay based on formate as the electron donor and the organometallic complex [Rh(bpy)Cp*(H₂O)]²⁺ (Cp*: 1,2,3,4,5-pentamethylcyclopentadiene, bpy: 2,2′-bipyridyl) as the catalyst for FAD reduction. The availability of a crystal structure of HpaB in complex with FAD at 1.8 Å resolution opens up the possibility of the rational tuning of the substrate specificity and activity of this interesting class of phenol hydroxylases.     

Microstructure and mechanical property of (TiB2-SiC) agglomerate-toughened B4C-TiB2-SiC composites

B₄C-TiB₂-SiC composites toughened by (TiB₂-SiC) agglomerates were prepared via reactive hot pressing with B₄C and TiSi₂ as raw materials. Phase composition, microstructure, and mechanical properties of the fabricated composites were investigated. The function of (TiB₂-SiC) agglomerates was analyzed, and the strengthening and toughening mechanism were also discussed. Results indicated that some of the in situ formed TiB₂ and SiC were interlocked to form special (TiB₂-SiC) agglomerates in the matrix. The good comprehensive performances of 510 MPa flexural strength, 5.84 MPa·m^1/2 fracture toughness, and 31.93 GPa hardness were obtained in the composites fabricated with 30 wt% TiSi₂. The in situ introduced fine TiB₂ and SiC grains refined the grains of B₄C due to the pinning effect, which enhanced the strength. The special (TiB₂-SiC) agglomerates and the existing toughening phenomena such as crack deflection, branching, and microcrack regions induced by the mismatch of thermal expansion coefficients, had cumulative effects on improving the fracture toughness.