Preparation of high toughness and high transparency polylactide blends resin based on multiarmed polycaprolactone‐block‐poly(l‐lactide)

Modification of poly(l ‐lactide) (PLLA) via blending with two or more polymers is one of the effective approaches used to overcome the brittleness of PLLA, which often requires the addition of a compatibilizer and generate opaque materials. To solve this problem, multiarmed polycaprolactone‐block‐PLLA (PCL‐b‐PLLA) was synthesized by consecutive ring‐opening polymerization of ε‐caprolactone and l ‐lactide using multihydroxyl alcohols as initiator. The structure and composition was confirmed by proton nuclear magnetic resonance and gel permeation chromatography. PLLA/multiarmed PCL‐b‐PLLA blends with various blend ratios were prepared via melt mixing. The presence of multiarmed PCL‐b‐PLLA (30%) in the PLLA matrix exhibited more than 80 times improvement in the elongation at break, as compared to unmodified PLLA. The addition of multiarmed PCL‐b‐PLLA in the PLLA contributed to the enhancement of the storage modulus in the low frequency, which was related to the entanglement of the PLLA and multiarmed PCL‐b‐PLLA. The blend interface had no obvious phase separation, and showed good adhesion between dispersed block copolymer phases within the continuous PLLA phase. The compatibilization mechanism and toughing mechanism were proposed. The resulting PLLA blends also showed good transparency. The current research opened a new route available to prepare transparent PLA‐based resin with enhanced properties. POLYM. ENG. SCI., 56:1125–1137, 2016. © 2016 Society of Plastics Engineers     

埋地钢制管道阴极保护技术应用及研究进展

随着钢制管道建设速度的日趋增大,其腐蚀问题也日趋显著。文章从现阶段钢制管道的腐蚀损失情况、腐蚀机理、腐蚀解决方案得出在管道外部涂覆防腐层并采用阴极保护的双层保护体系是解决钢制管道腐蚀的一种可行方法。通过介绍国内外关于阴极保护的发展和进展,指出我国在阴极保护技术上的不足和发展方向。     

Permeabilization of Escherichia coli with ampicillin for a whole cell biocatalyst with enhanced glutamate decarboxylase activity

The activity of whole-cell biocatalysts is strongly compromised by the cell envelope, which is a permeability barrier against the diffusion of substrates and products. Although common chemical or physical permeabilization methods used in cultured cells enhance cell permeability, these methods inevitably add several extra processing steps after cell cultivation, as well as impede large scale processing. To increase membrane permeability and cellbound glutamate decarboxylase(GAD) activity of recombinant Escherichia coli(BL21(DE3)-p ET28a-gad B) cells without the need for an additional permeabilization step, we investigated the permeabilizing effects of adding cell wall synthesis inhibitors or surfactants to the culture media. Ampicillin was the most effective at improving cell-bound GAD activity of the BL21(DE3)-p ET28a-gad B, although it decreased the cell biomass yield. The best permeabilization effect was observed using an ampicillin concentration of 5 μg·ml-1. Using this concentration,the cell biomass did decrease by 40.58%, but the cell-bound GAD activity of BL21(DE3)-p ET28a-gad B and total cell-bound GAD activity per milliliter of culture was enhanced by 6.24- and 3.64-fold, respectively. Treatment of BL21(DE3)-p ET28a-gad B cells with 5 μg·ml-1ampicillin resulted in structural changes to the cell envelope,but did not substantially affect GAD expression. By entrapping the ampicillin-treated cells in an open pore gelation matrix, which is a polymer derived from polyvinyl alcohol(PVA), alginate, and boric acid, the transformation rate of γ-aminobutyric acid(GABA) at the 10 th cycle produced by immobilized and permeabilized cells remained 46% of the first cycle. GAD activity of the immobilized, permeabilized cells remained over 90% after30 days of storage at 4 °C.     

模拟高放废液碱矿渣水泥固化体稳定性的研究

本文主要研究了碱矿渣水泥固化体的热力学稳定性、热稳定性和在地下水中的稳定性.研究结果表明,水化到28天时,固化体中处于介稳态的矿渣玻璃体基本消失,转化为稳定的水化产物,固化体的热力学稳定性良好;固化体在500℃的高温下仍具有足够的强度,热稳定性良好;同时,在地下水中,固化体也具有良好的稳定性.     

EAK分子间炸药的热分解

通过 Ｄ Ｓ Ｃ分析研究了 Ｅ Ａ Ｋ（乙二胺二硝酸盐硝酸铵硝酸钾）低共熔物分子间炸药的热分解特性,测定了 Ｅ Ａ Ｋ 的分解动力学参数。研究表明氧化剂 Ａ Ｋ 和还原剂 Ｅ Ｄ Ｄ 相互作用的结果导致 Ｅ Ａ Ｋ 表现为快速的自催化分解。     

甲醇氧化生产甲醛装置的工艺查定及分析(Ⅱ)

采用简捷法对两个吸收塔分别进行了计算 ,求出了理论级数、液气比、吸收率及尾气与吸收液的量和组成     

负载钛催化体系合成聚1-丁烯的序列结构

通过聚1－丁烯（PBt）的^13C-NMR谱图中对立体结构的实测值与Bernoulli模型计算值比较，表明该体系基本符合Bernoulli模型提出的机理，同时计算出甲苯不溶物、可溶物和空白试样BPt的全同（m）和间同（r）平均链长，并作出r和m连接的分布曲线，3个试样的间同平均链长都接近1，并且分布非常窄，而全同平均链长虽然各不相同但都较, 分布非常宽，这表明PBt的序列结构为主体嵌段结构。     

大分子键合处理氢氧化铝的表面性质及其与常用聚合物的界面特性

本文研究了经大分子以键合方式包覆处理的氢氧化铝粉末的表面性质以及其与常用聚合物的界面特性。结果表明：（１）与末处理过的氢氧化铝相比,非极性液体与处理过的氢氧化铝压片的接触角变化较小,而极性液体与它的接触角一般明显增大。（２）改性后的氢氧化铝的表面张力均明显下降,其中表面张力有极性分量大幅度下降而色散分量稍有提高。与常见聚合物的界面张力以及它的极性分量和色散分量均降而色散分量稍有提高。与常见聚合物的     

基于特征编码的字符识别方法研究

本文在分析了常用模板匹配字符识别方法的问题之后,以车牌字符中常用的字母、数字为例,提出了一种新的基于数字字母特征的编码方法,解决了模板匹配法中的字符图像与模板尺寸不符等问题,提高了识别率。     

离心风机转子临界转速计算方法的对比分析

风机转子临界转速分析计算是风机结构设计中最关键的一个环节,对风机转子的安全运行和全寿命管理具有非常重要的意义。本文分别采取工程计算法、传递矩阵法和有限元法来计算转子的临界转速,并对上述计算方法进行了相应的对比和对其适应性作出了总结,在实际工程中具有很高的实用价值。