Effect of high polymerization temperature on the microstructure of isotactic polypropylene prepared using heterogeneous ticl4/mgcl2 catalysts

The effects of alkylaluminum and polymerization temperature on propylene polymerization without an external donor in the use of a TiCl₄–MgCl₂–diether(BMMF) catalyst were investigated. The results indicated that with increasing polymerization temperature the concentrations of [mmmm] of heptane‐insoluble poly(propylene) (PP) fraction increased. Crystallization analysis fractionation (CRYSTAF) results showed the fractions of different crystallization temperatures were changed according to various polymerization temperatures. The activity with Et₃Al as cocatalyst at 100°C was much lower than that at 70°C. However, the activity with i‐Bu₃Al at 100°C was as high as that at 70°C. The fraction of high‐crystallization temperature of PPs obtained with i‐Bu₃Al increased with increasing polymerization temperature, which was opposite to that with Et₃Al, thus implying that the copolymerization of propylene with the monomer arising from Et₃Al led to the lower crystallization ability of PPs obtained with Et₃Al. The terminal groups of PP suggested that the chain‐transfer reaction by β‐H abstraction was the main chain‐transfer reaction at 120°C. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3980–3986, 2003     

Preparation and properties of T300 carbon fiber‐reinforced thermoplastic polyimide composites

In this study, a series of T300 carbon fiber‐reinforced polyimide (CFRPI) composites were prepared by laminating premolding polyimide (PI) films with unidirectional carbon fiber (CF) layers. On the basis of PI systems design, the effect of CF volume fraction, processing conditions, and PI molecular structure on the properties of CFRPI composites was studied in detail. In addition, two kinds of nano‐particles, including carbon nano‐tube (CNT) and SiO₂ were filled into the premolding PI films with different concentrations. And the effect of nano‐particles on the properties of CFRPI composites was also investigated. The surface characteristic of T300 CF was measured by X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR). The properties of premolding PI film and CFRPI composites were measured by dynamic mechanical analysis (DMTA), SANS testing machine, scanning electron microscopy (SEM), and so forth. These experimental results showed that the properties of CFRPI composites were mainly affected by the premolding PI film and molding condition. The change of CF volume fraction from 55% to 65% took little effect on the mechanical properties of CFRPI composites. In addition, the incorporation of nano‐particle SiO₂ could further improve the properties of CFRPI composites, but CNT hardly improved the properties of CFRPI composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 646–654, 2006     

缩放管内CaCO_3污垢形成过程的数值模拟

利用从传热传质角度结合表面化学反应知识模拟CaCO3污垢形成过程的数学模型,对缩放管不同工况进行了数值模拟计算.得出不同工况下,缩放管内CaCO3污垢的沉积率、剥蚀率、污垢热阻随时间的变化规律以及它们与流速、工质浓度、温差的关系.     

Numerical simulation on the rheo-diecasting of the semi-solid A356 aluminum alloy

The effect of injection pressure, piston velocity, and the forming temperature of semisolid slurry on the filling behavior of the semi-solid A356 aluminum alloy was investigated by simulation methods. The simulation results show that these processing parameters have an important effect on the filling behavior of the semi-solid A356 aluminum alloy. The slurry flows steadily in the cavity when the injection pressure, the piston velocity, and the forming temperature are low, but it is prone to turbulent flow w...     

构建新形势下大学生党员发展质量保障体系

做好当代大学生党员发展工作是加强新形势下党的建设的重要举措。分析了目前高校大学生党员发展工作存在的问题,根据党建的有关原则和精神,提出了构建新形势下大学生党员发展质量保障体系的对策。     

高职旅游英语专业英语课程设置与人才培养

以ESP理论为指导,从旅游英语专业学生的学习需求及用人单位的人才规格需求出发,通过对高职旅游英语专业学生及用人单位设计的问卷访谈分析,解读旅游英语专业英语课程设置与人才培养的关系。     

基于博弈论的多机器人任务分配算法

为了寻找一种合理有效的多机器人任务分配算法,基于多机器人协作救火任务环境,以博弈论纳什均衡为基础,研究多机器人的任务分配问题。根据任务模型特点和纳什均衡的主要特征提出了一种基于博弈论的任务分配算法。博弈的效用函数同时考虑了距离、火势和燃烧时间等因素,机器人根据此效用函数选择行为策略,促使机器人尽快扑灭惩罚值较大的火灾而获得较大的奖励值。利用任务总收益函数值的大小评价算法的优劣性。收益函数与火势、燃烧时间和机器人扑灭火灾数有关,这切合实际救火模型。实验结果证明了该任务分配算法的有效性。     

碳纳米管在乙二醇水溶液中的分散性

采用硫酸和硝酸混合酸对催化裂解法(CVD法)制备的多壁碳纳米管(CNTs)进行纯化,以超声仪为分散设备,分别研究了在乙二醇水溶液中加入不同类型的阳离子、阴离子、非离子型等表面活性剂对碳纳米管分散性的影响,通过记录碳纳米管悬浮液的稳定保存时间观察其分散性.结果表明:十六烷基三甲基溴化铵和乳化剂OP作为分散剂的分散效果最好.     

气化炉油气掺烧技术探讨

简要叙述了九江合成氨装置五通道气化烧嘴掺烧干气试验过程，实践证明渣油掺烧干气工艺是可行的。通过对掺烧干气试验结果的理论分析，渣油雾滴的减小和雾化角的减小。使燃烧区上移，在保证渣油充分燃烧的前提下，减少火焰对气化炉壁的冲蚀，会有效增加装置运行周期。     

Thermogravimetric analysis of methyl methacrylate‐graft‐natural rubber

The thermal degradations of methyl methacrylate‐graft‐natural rubber (MG) at different heating rates (B) in nitrogen were studied by thermogravimetric analysis. The results indicate that the thermal degradation of MG in nitrogen is a one‐step reaction. The degradation temperatures increase along with the increment of heating rates. The temperature of initial degradation (T₀) is 0.448B + 362.4°C, the temperature at maximum degradation rate, that is, the peak temperature on a differential thermogravimetric curve (T_p) is 0.545B + 380.7°C, and the temperature of final degradation (T_f) is 0.476B + 409.4°C. The degradation rate at T_p is not affected by B, and its average value is 48.9%; the degradation rate at T_f is not affected by B either, and its average value is 99.3%. The reaction order (n) is 2.1 and is not affected by B. The reaction activation energy (E) and the frequency factor (A) increase along with B, and the apparent reaction activation energy (E₀) is 254.6 kJ/mol. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 2952–2955, 2002