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41.
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Bai H Sun R Ju J Yao X Zheng Y Jiang L 《Small (Weinheim an der Bergstrasse, Germany)》2011,7(24):3429-3433
Spider-silk inspired functional fibers with periodic spindle-knots and the ability to collect water in a directional manner are fabricated on a large scale using a fluid coating method. The fabrication process is investigated in detail, considering factors like the fiber-drawing velocity, solution viscosity, and surface tension. These bioinspired fibers are inexpensive and durable, which makes it possible to collect water from fog in a similar manner to a spider's web. 相似文献
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Pb(Zn1/3Nb2/3)O3 ceramics with the perovskite structure can be stabilized by substituting 6–7 mol % BaTiO3 (BT). Piezoelectric and dielectric properties of the pseudo-binary system (1–x)(0.94PZN-0.06BT) -xPb(Zr(1–y)Tiy)O3 were studied, and the effects of Zr/Ti ratios and thermal annealing process on the piezoelectric and dielectric properties were also discussed. The results show that the piezoelectric properties of this ceramic system are very good when x is about 0.50 and y is about 0.47 with Kp = 70%, d33=560 pC/N, m #x2248;23,000. These ceramics are favorable to piezoelectric actuators. 相似文献
45.
Donglin He Ping Li Wei Wang Qi Wan Jian Zhang Kai Xi Xiumei Ma Zhiwei Liu Lin Zhang Xuanhui Qu 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(5)
Although silicon‐based materials are ideal candidate anodes for high energy density lithium‐ion batteries, the large volumetric expansion seriously damages the integrity of the electrodes and impedes commercial processes. Reasonable electrode design based on adjustable structures of silicon and strong binders prepared by a facile method is still a great challenge. Herein, a three‐pronged collaborative strategy via hollow nanocubes, amorphous Void@SiOx@C, and in situ cross‐linked polyacrylic acid and d ‐sorbitol 3D network binder (c‐PAA‐DS) is adopted to maintain structural/electrode integrality and stability. The all‐integrated c‐PAA‐DS/Void@SiOx@C electrode delivers excellent mechanical property, which is attributed to ductility of the c‐PAA‐DS binder and high adhesion energy between Void@SiOx@C and c‐PAA‐DS calculated by density functional theory. Benefiting from the synergistic effect of accommodation of the hollow structure, protection of outer carbon shell, amorphous Void@SiOx@C, and strong adhesive c‐PAA‐DS binder, c‐PAA‐DS/Void@SiOx@C shows excellent electrochemical performance. Long cycling stability with a reversible capacity of 696 mAh g?1 is obtained, as well as tiny capacity decay after 500 cycles at 0.5 A g?1 and high‐rate performance. The prelithiated Void@SiOx@C||LiNi0.5Co0.2Mn0.3O2 (NCM523) full cell is also assembled and shows a reversible capacity of 157 mAh g?1 at 0.5 C, delivering an excellent capacity retention of 94% after 160 cycles. 相似文献
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Runnan Yu Huifeng Yao Zhenyu Chen Jingmin Xin Ling Hong Ye Xu Yunfei Zu Wei Ma Jianhui Hou 《Advanced materials (Deerfield Beach, Fla.)》2019,31(18)
Fine‐tuning of the nanoscale morphologies of the active layers in polymer solar cells (PSCs) through various techniques plays a vital role in improving the photovoltaic performance. However, for emerging nonfullerene (NF) PSCs, the morphology optimization of the active‐layer films empirically follows the methods originally developed in fullerene‐based blends and lacks systematic studies. In this work, two solid additives with different volatilities, SA‐4 and SA‐7, are applied to investigate their influence on the morphologies and photovoltaic performances of NF‐PSCs. Although both solid additives effectively promote the molecular packing of the NF acceptors, due to the higher volatility of SA‐4, the devices processed with SA‐4 exhibit a power conversion efficiency of 13.5%, higher than that of the control devices, and the devices processed with SA‐7 exhibit poor performances. Through a series of detailed morphological analyses, it is found that the volatilization of SA‐4 after thermal annealing is beneficial for the self‐assembly packing of acceptors, while the residuals due to the incomplete volatilization of SA‐7 have a negative effect on the film morphology. The results delineate the feasibility of applying volatilizable solid additives and provide deeper insights into the working mechanism, establishing guidelines for further material design of solid additives. 相似文献
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