金属蜂窝负载Pd催化甲烷部分氧化制合成气

采用浸渍法制备负载金属Pd(其中金属Pd含量0.6g/L)活性组分的金属蜂窝载体催化剂,应用于甲烷部分氧化制合成气。实验表明,焙烧温度为950℃的催化剂较600℃的催化剂甲烷转化率、CO和H2的选择性更高,焙烧温度为950℃的催化剂在反应温度800℃,GHSV=1×105ml/g·h条件下,甲烷转化率为91%,CO和H2的选择性分别达到90%和89%。用SEM与XPS对催化剂进行表征,结果表明,950℃焙烧催化剂并没有出现明显的烧结现象,且可能由于更多零价Pd的出现,使得该催化剂的性能更好。由于金属蜂窝载体优良的导热性,对950℃焙烧温度制备的金属蜂窝催化剂,催化剂床层的飞温点温度小于880℃,可以解决其它类型催化剂在甲烷部分氧化反应中出现的飞温问题,具有一定的工业化意义。     

Zr基非晶合金在过冷液相区静液挤压的变形行为及结构

研究了Zr41.2Ti13.8Cu12.5Ni10Be22.5非晶合金在过冷液相区内静液挤压的变形行为以及结构变化。结果表明:非晶合金在高应变速率下产生了明显的塑性变形,直径从16 mm变为12 mm,断裂为4段,且样品断口上随机分布着充分发展与未充分发展的脉纹式切变带,由此可看出非晶合金的变形为非牛顿体变形行为;挤压后的样品约有3%的非晶相发生晶化,在非晶基体上析出10~20 nm的纳米晶粒,导致挤压后非晶合金的热稳定性降低;静液挤压高应变速率变形条件使非晶合金产生非均匀流变,是造成非晶合金断裂的主要原因。     

喷射成形A356铝合金组织及力学性能的研究

采用自行开发的控制往复喷射成形专利技术,以产业化规模制备了铝合金锭坯,研究了对传统铸造A356铝合金的组织及其力学性能的影响.结果表明:喷射成形态合金组织均匀,致密度达到95.8%;挤压态合金中均匀分布大量细小Si颗粒;固溶温度为540℃,时效温度为160℃,时效10 h时硬度达到峰值,继续延长时效时间对硬度值影响甚微;经过固溶时效处理的A356铝合金常温抗拉强度σb=337 MPa,屈服强度σ0.2=281 MPa,伸长率δ5=18.3%,分别提高21.2%,35.7%,205%.     

Experimental and numerical study of warm deep drawing of AZ31 magnesium alloy sheet

Warm forming of magnesium alloy sheet has attracted more and more attention in recent years. The formability of magnesium alloy sheet at elevated temperature depends on appropriate processes, and the fabrication of high-performance sheet. In this research, an AZ31 magnesium alloy sheet with excellent performances is fabricated by the cross-rolling and the uniform annealing treatments. The uniaxial tensile tests are conducted using a Gleeble 3500 thermal–mechanical simulator, and the mechanical properties of AZ31 magnesium alloy sheet are analyzed. Finally, some limiting drawing ratio (LDR) experiments are performed. The experiments show that the LDR can reach 2.0 at the forming temperature of 150 °C and the drawing velocity of 15 mm/s. A warm deep drawing process is also simulated by the finite element method. The influences of drawing temperature and blank holder force on the formability are numerically investigated. The simulation demonstrated that variable blank holder force technology can improve the LDR from 3.0 to 3.5, and decrease the wall thinning ratio from 15.21% to 12.35%.     

NdFeB磁体的二次化学镀耐蚀性能

研究了NdFeB磁体表面超声波化学镀和二次化学镀Ni- P合金的耐腐蚀性，用扫描电子显微镜和X射线衍射仪分析了镀层的组织结构，结果表明，该工艺制备的镀层明显地提高了NdFeB磁体的耐蚀性能.     

Dynamic Young’s modulus and internal friction in polycrystalline copper

An attempt has been made to measure the temperature dependence of dynamic Young’s modulus together with the related variation of internal friction in polycrystalline copper. A mechanical spectroscopy study was employed using a standard servo hydraulic fatigue testing machine equipped with a scanning laser extensometer. Dynamic Young’s modulus and internal friction were measured over a temperature range of 298 to 873 K at very low frequencies of 0.1, 0.05, and 0.01 Hz. One internal friction peak was observed over the ranges 450 to 700 K, together with marked decreases in the dynamic Young’s modulus in the same temperature range. From a quantitative analysis of the experimental data with the relaxation strength, relaxation time, and activation energy, it is concluded that the peak phenomenon is due to grain-boundary sliding relaxation.     

炭素阳极焙烧解组站自动控制系统设计

通过对炭素阳极焙烧解组站系统的工艺原理的分析,以炭素阳极一焙烧二系列炭块解组站系统为例,设计了一种基于美国A-B可编程序控制器(PLC)技术的焙烧炭块解组站生产线计算机自动控制系统,阐述了控制系统的组成结构、控制功能、网络拓扑的实现和上位计算机监控软件IFIX在该系统的应用。实践证明,该解组站自动控制程序针对了现场工艺特点,是一套经济、可靠、易于维护的解组站自动控制系统方案,系统达到较好的应用效果。     

炼铁高炉炉前液压站油品离心净化的应用分析北大核心

冶金生产过程中,液压和润滑系统在设备正常运行中起着举足轻重的作用。因此,油品净化的管控,是各企业长期面临的一项持续性工作。最常见的净化方式有过滤式、真空过滤式两种方式。根据原理和优缺点进行对比分析,过滤式和真空过滤式方法净化效果一般、性价比低、适用工况少,而离心式油品净化方式可以真正达到高效率低消耗的净化。对离心式油品净化方式进行调研、试用和运行追踪,实测数据表明该离心净化方式确实能够满足炉前液压油油品净化的需求。     

大尺寸TiB2-Cu-Ni金属陶瓷块体的燃烧合成及准热等静压致密化

利用燃烧合成结合准热等静压 (PHIP)技术成功制备了直径为 2 40mm的大尺寸TiB2 Cu Ni金属陶瓷 ,对合成产物进行了X射线衍射 (XRD)、扫描电镜 (SEM)和力学性能等实验研究。XRD结果表明反应产物中只有TiB2 和 (Cu ,Ni)两相。SEM分析发现增强相TiB2 陶瓷颗粒已经形成骨架状 ,其间为 (Cu ,Ni)基体相 ,TiB2 颗粒形貌为近等轴状 ,尺寸细小且较均匀。合成产物的致密度为 94.2 % ,弯曲强度和断裂韧性分别达到 5 99.4MPa和12 .5 6MPa·m1/ 2 。