Bioinspired Fabrication of Superhydrophobic Graphene Films by Two‐Beam Laser Interference

Reported here is a bioinspired fabrication of superhydrophobic graphene surfaces by means of two‐beam laser interference (TBLI) treatment of graphene oxide (GO) films. Microscale grating‐like structures with tunable periods and additional nanoscale roughness are readily created on graphene films due to laser induced ablation effect. Synchronously, abundant hydrophilic oxygen‐containing groups (OCGs) on GO sheets can be drastically removed after TBLI treatment, which lower its surface energy significantly. The synergistic effect of micro‐nanostructuring and the OCGs removal endows the resultant graphene films with unique superhydrophobicity. Additionally, dual TBLI treatment with 90° rotation is implemented to fabricate superhydrophobic graphene films with two‐dimensional grating‐like structures that can effectively avoid the anisotropic hydrophobicity originated from the grooved structures. Moreover, the superhydrophobic graphene films become conductive due to the laser reduction effect. Unique optical characteristics including transmission diffraction and brilliant structural color are also observed due to the presence of periodic microstructures. As a mask‐free, chemical‐free, and cost‐effective method, the TBLI processing of GO may open up a new way to biomimetic graphene surfaces, and thus hold great promise for the development of novel graphene‐based microdevices.     

Switching rate and receiver performance of binary modulations with the selection‐and‐stay combining over independent and correlated Nakagami‐m fading channels

The dual‐branch selection‐and‐stay combining (SSTC) is analyzed for diversity reception on independent and correlated Nakagami‐m fading channels, where the conventional selection combining (SC) is employed only at the switching instance, and the receiver uses the selected branch till its signal‐to‐noise ratio (SNR) estimation is lower than a preset threshold. In this combining scheme, the receiver only needs to continuously estimate the SNR of the single selected branch. For the performance analysis of SSTC, the switching rate and the average bit error rates (BERs) of different binary coherent and non‐coherent modulations are evaluated. Numerical results based on the analysis and simulations are illustrated. According to the analysis and numerical results, the SSTC outperforms the existing switch‐and‐stay combining in the senses of the average BER and switching rate. Copyright © 2011 John Wiley & Sons, Ltd.     

Core‐stateless fair rate estimation fair queuing

Core‐stateless mechanisms, such as core‐stateless fair queuing (CSFQ), reduce the complexity of fair queuing, which usually need to maintain states, manage buffers, and perform flow scheduling on a per‐flow basis. However, they require executing label rewriting and dropping decision on a per‐packet basis, thus preventing them from being widely deployed. In this paper, we propose a novel architecture based on CSFQ without per‐packet labelling. Similarly, we distinguish between edge routers and core routers. Edge routers maintain the per‐flow state by employing a fair queuing mechanism to allocate each flow a fair bandwidth share locally and a token bucket mechanism to regulate those flows with feedback packets sent from egress edge routers. Core routers do not maintain per‐flow state; they use FIFO packet scheduling extended by a fare rate alarm mechanism by estimating the arrival rate and the number of flows using a matching–mismatching algorithm. The novel scheme is called core‐stateless fair rate estimation fair queuing (CSFREFQ). CSFREFQ is proven to be capable of achieving max–min fairness. Furthermore, we present and discuss simulations and experiments on the performance under different traffic scenarios. Copyright © 2005 John Wiley & Sons, Ltd.     

Comparative analysis of passive algorithms in adaptive control

Representative passive adaptive algorithms have been developed with a wide variety of applications. However, to the best of our knowledge, the attempt to unify or to compare them has not been clearly established in literature. In this article, we provide a passive adaptive framework which encompasses all those algorithms including the recently developed proportional‐integral (PI) adaptive scheme. A comparative analysis among performances of the passive algorithms is carried out by means of simulations considering the problem of passivity‐based adaptive tracking control of a simple pendulum. In addition, passivity property for PI algorithm is rigorously shown in case of linear parametrization. Copyright © 2013 John Wiley & Sons, Ltd.     

Bread and durum wheat compared for antioxidants contents,and lipoxygenase and peroxidase activities

Potential beneficial components, including proteins, total phenolics, total flavonoids, carotenoids, tocopherols, and DPPH radical scavenging activity, were investigated in wholemeal of ten bread (T. aestivum L.) and ten durum (T. durum Desf.) novel wheat genotypes. In addition, the activity rate of lipoxygenase (LOX) and peroxidase (POD) enzymes implicated in the antioxidant metabolism was determined. The protein contnet and the antioxidant properties varied according to the two different wheat species, as well as, between the different bread and durum wheat genotypes themselves. The results indicated significant differences in proteins and antioxidant compounds between bread and durum wheat. Higher total proteins, wet gluten and antioxidants contents, combined with lower LOX and POD activities, point to a higher nutritive value of durum wheat than bread wheat.     

Transistor Paint: Environmentally Stable N‐alkyldithienopyrrole and Bithiazole‐Based Copolymer Thin‐Film Transistors Show Reproducible High Mobilities without Annealing

New solution processable 4‐(2‐hexyldecan)‐4H‐bisthieno[2,3‐d:3′,2′‐b]pyrrole and 4,4′‐dialkyl‐2,2′‐bithiazole‐based copolymers (PBTzDTPs) are synthesized with excellent FET performance. These novel copolymers have considerable potential in printable electronics as they have high charge carrier mobilities, excellent air stability, good solution processibility, and no requirement for post‐deposition thermal annealing, all requirements for this field of application. The thin film transistors fabricated from PBTzDTPs achieve field effect mobilities as high as 0.14 cm² V^?1 s^?1 with current on/off ratios up to 10⁶ without thermal annealing. In addition, the devices exhibit stable performance in air, showing no significant degradation over 60 days. Moreover, the polymers described here provide an excellent example of the systems in which higher mobility performance does not require higher crystalline, long‐range ordered structures. Such a system appears to be particularly promising for rapid fabrication techniques, where kinetic conditions usually prevent the development of long‐range order.