全文获取类型
收费全文 | 81022篇 |
免费 | 6676篇 |
国内免费 | 3121篇 |
专业分类
电工技术 | 4177篇 |
技术理论 | 4篇 |
综合类 | 4343篇 |
化学工业 | 14192篇 |
金属工艺 | 4169篇 |
机械仪表 | 5244篇 |
建筑科学 | 5019篇 |
矿业工程 | 1324篇 |
能源动力 | 2429篇 |
轻工业 | 6282篇 |
水利工程 | 1308篇 |
石油天然气 | 2672篇 |
武器工业 | 484篇 |
无线电 | 11030篇 |
一般工业技术 | 11980篇 |
冶金工业 | 4723篇 |
原子能技术 | 1044篇 |
自动化技术 | 10395篇 |
出版年
2024年 | 262篇 |
2023年 | 1073篇 |
2022年 | 2007篇 |
2021年 | 2922篇 |
2020年 | 2095篇 |
2019年 | 1966篇 |
2018年 | 2149篇 |
2017年 | 2394篇 |
2016年 | 2504篇 |
2015年 | 3028篇 |
2014年 | 3828篇 |
2013年 | 4973篇 |
2012年 | 5158篇 |
2011年 | 5834篇 |
2010年 | 5002篇 |
2009年 | 4696篇 |
2008年 | 4703篇 |
2007年 | 4198篇 |
2006年 | 4020篇 |
2005年 | 3520篇 |
2004年 | 2745篇 |
2003年 | 2586篇 |
2002年 | 2855篇 |
2001年 | 2348篇 |
2000年 | 1936篇 |
1999年 | 1737篇 |
1998年 | 1930篇 |
1997年 | 1471篇 |
1996年 | 1186篇 |
1995年 | 978篇 |
1994年 | 865篇 |
1993年 | 702篇 |
1992年 | 499篇 |
1991年 | 414篇 |
1990年 | 337篇 |
1989年 | 306篇 |
1988年 | 226篇 |
1987年 | 170篇 |
1986年 | 140篇 |
1985年 | 151篇 |
1984年 | 120篇 |
1983年 | 71篇 |
1982年 | 80篇 |
1981年 | 75篇 |
1980年 | 66篇 |
1979年 | 52篇 |
1977年 | 63篇 |
1976年 | 105篇 |
1975年 | 56篇 |
1973年 | 40篇 |
排序方式: 共有10000条查询结果,搜索用时 10 毫秒
91.
B. A. Young J. R. Williams S. W. Deiker S. T. Ruggiero B. Cabrera 《Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment》2004,520(1-3):307-310
We summarize a continuing investigation into using ion implantation to alter the transition temperature of superconducting thin films. The primary motivation for the work presented here was to study the feasibility of using magnetic ion doping to replace the bi-layer Tc control process currently used for certain cryogenic detector applications at National Institute for Standards and Technology. The results from work with various ion species implanted into aluminum, molybdenum, titanium and tungsten host films are presented. 相似文献
92.
The effects of gallia additions on the sintering behavior of gadolinia-doped ceria were systematically investigated from the following aspects: the variation in sintered density, the variation in grain size, and the existing forms of Ga2O3 in CeO2.Sintered density increased with increasing Ga2O3 content up to 5 mol.% and then it decreased with further addition of Ga2O3. Grain size also increased with increasing Ga2O3 content up to 5 mol.% and then decreased with further addition of Ga2O3. Decrease in grain size was caused by a pinning effect of Ga2O3 precipitation at grain boundaries. Lattice constant decreased with increasing Ga2O3 content up to 5 mol.%. This decrease will be due to the substitution of smaller Ga3+ ions for Ce4+ ions in the CeO2 structure. According to the results obtained from scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses, the solubility limit of Ga2O3 in Ce0.8Gd0.2O1.9 ceramics can be estimated to be nearly 5 mol.%. The addition of Ga2O3 up to the solubility limit was found to promote the sintering properties of Gd2O3-doped CeO2. 相似文献
93.
Grazing incidence reflection absorption Fourier transform infrared (GIRA-FTIR) spectroscopy was used to characterize the ferroelectric behavior of a thin poly(vinylidene fluoride–trifluoroethylene) P(VDF–TrFE) copolymer. The lab-built GIRA-FTIR apparatus allowed the heating and corona poling process to be carried out whilst collecting the GIRA spectra of the thin polymer film. The Curie transition from the ferroelectric to paraelectric phase was confirmed from the abrupt change in intensity of the 849 cm−1 band in the RA-FTIR spectrum. It was found that the Curie temperature dropped dramatically when the film thickness was lowered to below a certain critical value of approximately 100 nm. The switching of the CF2 dipoles in the ferroelectric crystals after applying the external electric field could be determined by monitoring the change in the 849 cm−1 band intensity. For the 600 nm thick P(VDF–TrFE) film, the switching of the dipoles appears to occur almost instantaneously, while the kinetics of dipole switching of the 75 nm thick film were significantly retarded. The repeated switchability of the CF2 dipoles upon the application of a bipolar cyclic electric field was also confirmed. The bistability of the film due to remnant polarization was also confirmed from the absorbance of the 849 cm−1 band after removing the applied voltage during corona poling. 相似文献
94.
Jeongsoo Choi 《Polymer》2005,46(23):9725-9735
A series of star-branched poly(ε-caprolactone)s (SPCLs) was synthesized with structural variation of the arm numbers and lengths through ring-opening polymerization under bulk condition. Arm numbers were varied to be 3, 4, and 6 by using multifunctional initiating cores such as trimethylol propane, pentaerythritol, and dipentaerythritol, respectively. The lengths of the poly(ε-caprolactone) arms were varied by controlling the molar ratio of monomer-to-initiating hydroxyl group molar ratio ([CL]0/[-OH]0=5, 10, 15). Molecular weights were determined by both 1H NMR end-group analysis and MALDI-TOF mass spectrometry, which gave reasonably consistent values. On the contrary, the GPC method failed to give accurate values of molecular weight of SPCLs due to the discrepancy with the linear standard. The branching architecture of SPCLs was evaluated by the branching ratio, g, which is the ratio of the mean-square radius of SPCL to that of liner counterpart, linear poly(ε-caprolactone) (LPCL), which is of the same chemistry and having the same molecular weight. The radii of gyration of SPCLs and LPCLs were determined using small-angle X-ray scattering (SAXS) from the initial slopes of Zimm plots, represented as 1/I(q) vs q2 with I(q) and q being the scattered intensity and scattering vector, respectively. The g values were observed to decrease with increasing arm numbers, indicating more compact molecular structure for SPCLs with higher arm numbers, while no such effect was observed for arm length variation. Thermal properties as well as the degree of crystallinity of SPCLs were found to be also dependent on structural variations. The melting points and the degradation temperatures were observed to increase with increasing arm lengths but with constant arm number. On the other hand, arm number variation with constant arm length gave no such changes to the thermal transitions of SPCLs. However, for the SPCLs with equivalent molecular weights, the degree of crystallinity was found to decrease with increasing arm numbers. 相似文献
95.
Du Young Choi Long Mei Jin Dexian Wang Kyung Ho Row 《Korean Journal of Chemical Engineering》2005,22(3):465-469
High-performance frontal analysis (HPFA) was used for a protein binding study of isoflavones (daidzein, genistin, and genistein),
enantiomers of perillyl alcohol and S-ibuprofen to human serum albumin (HSA). The analyses were performed on a Develosil and
Inertsil 100-Diol-5 column (10 cm×4.6mm). Sodium phosphate solution (pH 7.4, ionic strength 0.17) was used as the mobile phase
at a flow rate of 1 ml/min. To ensure the drug to be eluted as a trapezoidal peak with a plateau, injection volumes were each
fixed up the zonal profile with an evident plateau appears. The unbound drug concentration was determined from a plateau height
of the plateau region after that experimental data were fitted by Scatchard equation. The binding constants (K) and total
binding affinities (nK) of drugs to HSA were calculated, respectively. 相似文献
96.
A simple mathematical analysis on the effect of sand in Cr(VI) reduction using zero valent iron 总被引:1,自引:0,他引:1
A simple mathematical model was proposed to analyze the enhancement of Cr(VI) reduction when sand materials are added to the
zero valent iron (ZVI). Natural decay of Cr(VI) in a control experiment was analyzed by using a zero-order decay reaction.
Adsorption kinetics of Cr(VI) to sand was modeled as a first-order reversible process, and the reduction rate by ZVI was treated
as a first-order reaction. Natural decay of Cr(VI) was also included in other experiments, i.e., the adsorption to sand, the
reduction by ZVI, and both adsorption and reduction when sand and ZVI are present together. The model parameters were estimated
by fitting the solution of each model to the corresponding experimental data. To observe the effect of sand addition to ZVI,
both adsorption and reduction rate models were considered simultaneously including the natural decay. The solution of the
combined model was fitted to the experimental data to determine the first-order adsorption and reduction rate constants when
sand as well as ZVI is present. The first-order reduction rate constant in the presence of sand was about 35 times higher
than that with ZVI only. 相似文献
97.
Y. K. Cheung W. G. Jin O. C. Zienkiewicz 《International journal for numerical methods in engineering》1991,32(1):63-78
The application of the Trefftz method for calculating wave forces on offshore structures is presented. Indirect and direct formulations using complete and non-singular systems of Trefftz functions for the Helmholtz equation are posed in this paper. An effective technique using different interpolation functions for the velocity potential and wave force are suggested to improve the computational accuracy of the wave force. The numerical examples show that the present method is highly efficient and accurate. 相似文献
98.
A W-band divide-by-3 frequency divider with wide bandwidth and low power dissipation is presented using harmonic injection-locking technique. A cascode FET is employed for a self-oscillating second-harmonic mixer which is injection-locked by third-harmonic input to obtain the division order of three. The fabricated frequency divider using 0.1 /spl mu/m GaAs metamorphic HEMT technology shows superior performance such as large bandwidth of 6.1 GHz around 83.1 GHz (7.3%) under small DC power consumption of 12 mW. 相似文献
99.
100.
渤中13-1油田井身结构优化研究 总被引:1,自引:0,他引:1
针对渤中 1 3- 1油田钻井过程中存在的主要问题 ,利用测井、地质、录井和钻井资料 ,对该油田的井身结构进行研究 ,设计出合理的井身结构 ,优化了套管程序 ,为进一步减少钻井过程中漏、喷、塌、卡等复杂情况的发生 ,提供了科学的理论依据 相似文献