Phosphorus‐containing epoxy resin for an electronic application

A phosphorus‐containing epoxy resin, 6‐H‐dibenz[c,e][1,2] oxaphosphorin‐6‐[2,5‐bis(oxiranylmethoxy)phenyl]‐6‐oxide (DOPO epoxy resin), was synthesized and cured with phenolic novolac (Ph Nov), 4,4′‐diaminodiphenylsulfone (DDS), or dicyandiamide (DICY). The reactivity of these three curing agents toward DOPO epoxy resin was found in the order of DICY > DDS > Ph Nov. Thermal stability and the weight loss behavior of the cured polymers were studied by TGA. The phosphorus‐containing epoxy resin showed lower weight loss temperature and higher char yield than that of bisphenol‐A based epoxy resin. The high char yields and limiting oxygen index (LOI) values as well as excellent UL‐94 vertical burn test results of DOPO epoxy resin indicated the flame‐retardant effectiveness of phosphorus‐containing epoxy resins. The DOPO epoxy resin was investigated as a reactive flame‐retardant additive in an electronic encapsulation application. Owing to the rigid structure of DOPO and the pendant P group, the resulting phosphorus‐containing encapsulant exhibited better flame retardancy, higher glass transition temperature, and thermal stability than the regular encapsulant containing a brominated epoxy resin. High LOI value and UL‐94 V‐0 rating could be achieved with a phosphorus content of as low as 1.03% (comparable to bromine content of 7.24%) in the cured epoxy, and no fume and toxic gas emission were observed. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 73: 353–361, 1999     

Optimizing the mixture blending for castable aluminized plastic-bonded explosives

Castable aluminized plastic-bonded explosive (PBX) is a multiple components blending. To find an optimum mixture blending (formulation) for PBX to meet several required specifications is formidable. This is due to the fact that there are unlimited candidate formulations from which an appropriate one could be chosen. In general, trial and error type of engineering judgement is still the primary approach to reach the desired goal. This paper, however, employs a statistical approach named Mixture Experiments as well as an optimization routine called Eureka to find the optimum formulation, which meets five required specifications. Finally, two confirmation runs are performed. The results justify that the theroretical solution derived from the systematic statistical approach is indeed applicable.     

MIMO spread spectrum GFDM communication systems with index modulation

In the fourth-generation communication system (4G), orthogonal frequency division multiplexing (OFDM) is widely used. However, due to the cyclic prefix (CP) being added, the low spectrum efficiency and high out-of-band radiation (OOB) cause OFDM not to be suitable for the beyond fifth-generation (B5G) communication system. Therefore, to meet the rigorous demands in B5G for the Internet of Things (IoT) and massive machine-type communications (MMTC), generalized frequency division multiplexing (GFDM) technology has received significant attention. On the other hand, index modulation (IM) can provide flexible settings of different parameters to achieve the ideal system goals. Therefore, this paper considers the combination of spread spectrum (SS) and IM under the framework of GFDM, called SS-IM-GFDM. In this scheme, the information bits are jointly conveyed by the indices of spreading codes and the conventional M-ary modulated symbols, which increase the spectrum efficiency and improve the bit error rate performance. Furthermore, a low-complexity maximum likelihood (ML) detector is proposed to recover the transmitted signal effectively at the receiver. Finally, the space-time block code (STBC) is employed to construct the multi-input multi-output SS-GFDM-IM (MIMO SS-GFDM-IM) system to improve the system's reliability. The simulation results show that the proposed scheme is superior to the existing systems.     

Dual-Additive-Driven Morphology Optimization for Solvent-Annealing-Free All-Small-Molecule Organic Solar Cells

All-small-molecule organic solar cells (ASM-OSCs), which consist of small-molecule donors and acceptors, have recently been studied extensively to eliminate the batch-to-batch variation from polymer-based donor or acceptor. On the other hand, the control of their active layer morphology is more challenging due to the similar chemical structure and miscibility of small-molecule donor and small-molecule accepter. Hence, this study develops a dual-additive-driven morphology optimization method for ASM-OSCs based on BTR-Cl:Y6. One solid additive – 1,4-diiodobenzene (DIB) and one liquid additive – diiodomethane (DIM) are selected, making use of their distinct interaction mechanisms with Y6 and BTR-Cl. It is found that DIB can form a eutectic phase with Y6, which can increase the intermolecular interactions and modulate the acceptor phase separation, while the simultaneous volatilization of DIM suppresses the over-aggregation of BTR-Cl during the film casting process. As a result of the synergistic morphology tuning, the optimized device delivers a power conversion efficiency (PCE) as high as 15.2%, among the highest PCE reported to date for binary ASM-OSCs without solvent annealing treatment. This work demonstrates the potential of morphology tuning via the incorporation of dual additives into ASM-OSCs, enabling them to achieve comparable efficiencies to those of conventional polymer/small-molecule based OSCs.