Solution copolymerization of methyl methacrylate and alkyl methacrylates in a continuous stirred tank reactor(CSTR)

Continuous solution copolymerization of methyl methacrylate with ethyl methacrylate or n-butyl methacrylate was carried out in a continuous stirred tank reactor. Solvent and initiator used were toluene and benzoyl peroxide, respectively. Reaction volume was 1.2 litters, residence time 3 hours and polymerization temperature 80°C. The copolymerization conversions were analyzed by UV spectrophotometry and confirmed by measuring the solid weights of copolymers obtained after evaporating solvent. The copolymerization of methyl methacrylate and alkyl methacrylates followed the second order kinetics. The simulated conversions and copolymerization rates were compared with the experimental results. The average time to reach dynamic steady-state was three and half times of the residence time.     

A high performance parallel DCT with OpenCL on heterogeneous computing environment

A noteworthy thing in desktop PCs is that they can provide a great opportunity to increase the performance of processing multimedia data by exploiting task- and data-parallelism with multi-core CPU and many-core GPU. This paper presents a high performance parallel implementation of 2D DCT on this heterogeneous computing environment. For this purpose, Intel TBB (threading building blocks) and OpenCL (Open Compute Language) are utilized for task- and data-parallelism, respectively. The simulation result shows that the parallel DCT implementations far the serial ones in processing speed. Especially, OpenCL implementation shows a linear speedup, a typical SIMD characteristic as the increase of 2D data sets.     

A finite memory filtering for end-to-end available bandwidth estimation

In this paper, a finite memory filter is proposed to estimate the available bandwidth through real-time tracking unknown parameters of the sloping straight line while removing undesired system and measurement noises. The finite memory filter is developed under a weighted least square criterion using only the most recent finite probe-packet measurements on the window. The proposed finite memory filtering based available bandwidth estimate is shown to have several inherent properties such as unbiasedness, deadbeat, and robustness. A guideline for choosing appropriate window length is described as it can significantly affect the estimation performance. Finally, computer simulations show that the proposed finite memory filtering based approach can be comparable with the Kalman filtering based approach with infinite memory structure for constantly or slowly changing available bandwidth and outperform that for dynamically changing available bandwidth.     

Nanotextured superhydrophobic micromesh

A superhydrophobic micromesh covered with nanoprotrusions has been introduced and its applicability to a waterproof mobile phone speaker has been evaluated. The nanotextured superhydrophobic micromesh showed excellent water repellency, self-cleaning and waterproofing performances. In a waterproof speaker test using the fabricated nanotextured micromesh, the micromesh did not lose its waterproof function at 2 m water depth and did not form a remnant water film after being removed from the water. The packaged speaker showed almost the same sound quality before and after dipping at a 2 m water depth. These results demonstrate that the superhydrophobic nanotextured micromesh could be directly applicable for various products that need to resist water penetration, yet allow the transmission of gases and sound/light waves.     

Counting clicks and beeps: Exploring numerosity based haptic and audio PIN entry

Haptic and audio cues now appear commonly in computer interfaces, partially due to inherent advantages such as their support for eyes-free interaction. Their invisible, unobservable nature also makes them ideal candidates for security interfaces in which users have to enter secret information such as passwords. In particular, researchers have explored this idea through the design of PIN entry authentication systems based on multi-modal combinations of visual and non-visual content or on the recognition of small sets of unimodal haptic or audio stimuli. This paper highlights the benefits and performance limitations of these approaches and introduces an alternative based on unimodal audio or haptic temporal numerosity – the ability to accurately and rapidly determine the number of cues presented in rapid temporal succession. In essence, in a numerosity interface, rather than recognizing distinct cues, users must count the number of times that a single cue occurs. In an iterative process of design and evaluation, three prototypes implementing this concept are presented and studies of their use reported. The results show the fastest PIN entry times and lowest error rates to be 8 s and 2%, figures that improve substantially on previous research. These results are attained while maintaining low levels of workload and substantial resistance to observation attack (as determined via camera attack security studies). In sum, this paper argues that unimodal audio and haptic numerosity is a valuable and relatively unexplored metaphor for non-visual input and demonstrates the validity of this claim in the demanding task of unobservable authentication systems.     

Leak behavior of SCC degraded steam generator tubings of nuclear power plant

A forced outage due to a steam generator tube leak in a Korean nuclear power plant has been reported [Kim, J.S., Hwang, S.S., et al., 1999. KAERI Internal Report (Korean). Destructive analysis on pulled tubes from Ulchin unit 1. Korea Atomic Energy Research Institute]. Primary water stress corrosion cracking has occurred in many tubes in the plant, and they were repaired using sleeves or plugs. In order to develop proper repair criteria, it is necessary to understand the leak behavior of the tubes containing stress corrosion cracks. Cracked specimens were prepared using a room temperature cracking technique, and the leak rates and burst pressures of the degraded tubes were determined both at room temperature and at a high temperature. Some tubes with 100% through wall cracks did not show a leakage at 10.8 MPa, which is the typical pressure difference of the pressurized water reactors (PWRs) during a normal operation. In some tests, the leak rates of the tubes increased with time at a constant pressure. In a high temperature pressure test at 282 °C one specimen showed a very small leakage at 18.6 MPa, which stopped after a small increase in the test pressure. Because stress corrosion cracks can develop at relatively low stresses, even 100% through wall cracks can be so tight that they will not leak at a normal operating pressure.     

Effect of irradiation on the impact and seismic response of a spent fuel storage and transport cask

The spent fuel storage and transport cask must withstand various accident conditions such as fire, free drop and puncture in accordance with the requirement of the IAEA and domestic regulations. The spent fuel storage and transport cask should maintain the structural safety not to release radioactive material in any condition. And also the effects of the irradiation should be considered because the spent fuels stored in the cask for a long time and be possible to change the mechanical properties of the cask.In this study, the changed mechanical properties of the cask after irradiation for the 30 years storage periods are assumed and applied to the impact analysis using ABAQUS/Explicit code and seismic analysis using ANSYS code. The stress intensity on each part of the cask is calculated and the effects of irradiation are studied and structural integrity of the package is evaluated.     

Trans-Reduction of Cerebral Small Vessel Disease Proteins by Notch-Derived EGF-like Sequences

Cysteine oxidation states of extracellular proteins participate in functional regulation and in disease pathophysiology. In the most common inherited dementia, cerebral autosomal dominant arteriopathy with subcortical infarcts and leukoencephalopathy (CADASIL), mutations in NOTCH3 that alter extracellular cysteine number have implicated NOTCH3 cysteine states as potential triggers of cerebral vascular smooth muscle cytopathology. In this report, we describe a novel property of the second EGF-like domain of NOTCH3: its capacity to alter the cysteine redox state of the NOTCH3 ectodomain. Synthetic peptides corresponding to this sequence (NOTCH3 N-terminal fragment 2, NTF2) readily reduce NOTCH3 N-terminal ectodomain polypeptides in a dose- and time-dependent fashion. Furthermore, NTF2 preferentially reduces regional domains of NOTCH3 with the highest intensity against EGF-like domains 12–15. This process requires cysteine residues of NTF2 and is also capable of targeting selected extracellular proteins that include TSP2 and CTSH. CADASIL mutations in NOTCH3 increase susceptibility to NTF2-facilitated reduction and to trans-reduction by NOTCH3 produced in cells. Moreover, NTF2 forms complexes with the NOTCH3 ectodomain, and cleaved NOTCH3 co-localizes with the NOTCH3 ectodomain in cerebral arteries of CADASIL patients. The potential for NTF2 to reduce vascular proteins and the enhanced preference for it to trans-reduce mutant NOTCH3 implicate a role for protein trans-reduction in cerebrovascular pathological states such as CADASIL.     

Direct vapor phase growth process and robust photoluminescence properties of large area MoS2 layers

There has been growing research interest in the use of molybdenum disulfide in the fields of optoelectronics and energy harvesting devices, by virtue of its indirect-to-direct band gap tunability. However, obtaining large area thin films of MoS2 for future device applications still remains a challenge. In the present study, the amounts of the precursors （S and MOO3） were varied systematically in order to optimize the growth of highly crystalline and large area MoS2 layers by the chemical vapor deposition method. Careful control of the amounts of precursors was found to the key factor in the synthesis of large area highly crystalline flakes. The thickness of the layers was confirmed by Raman spectroscopy and atomic force microscopy. The optical properties and chemical composition were studied by photoluminescence （PL） and X-ray photoelectron spectroscopy. The emergence of strong direct excitonic emissions at 1.82 eV （A-exciton, with a normalized PL intensity of -55 × 10^3） and 1.98 eV （B-exciton, with a normalized PL intensity of -5 × 10^3） of the sample at room temperature clearly indicates the high luminescence quantum efficiency. The mobility of the films was found to be 0.09 cm^2/（V.s） at room temperature. This study provides a method for the controlled synthesis of high-quality two-dimensional （2D） transition metal dichalcogenide materials, useful for applications in nanodevices, optoelectronics and solar energv conversion.