High current density organic electrosynthesis via metal powders in multiphase systems

A procedure for the high current density (> 0.5 A cm^–2) reduction of organic compounds is described. The reactions employ an emulsion of aqueous zinc chloride (4 M) and the organic substrate and occur via the intermediate formation of zinc powder at the cathode. A high current density and thein situ reaction of the powder ensure that the metal has a high surface area, free of oxidized films: it is therefore very reactive. Two reactions, the dechlorination of 1,2,2-trichloroethane and the reduction of nitrobenzenes, are used as examples.     

Electrosynthesis in systems of two immiscible liquids and a phase transfer catalyst. V. The anodic chlorination of naphthalene

The anodic chlorination of naphthalene in a water/methylene chloride emulsion and using tetrabutylammonium ion as the phase transfer catalyst is demonstrated; in conditions where the aqueous phase is saturated NaCl, the organic yield of 1-chloronaphthalene is 56% and the current yield is 33% after the passage of 2.33 F mol^–1 of naphthalene. It is shown, however, that when the aqueous phase also contains zinc chloride so that the species transferred is [(C₄H₉)₄N⁺]₂ZnCl ₄ ^–– , the yields can be increased to 92% and 49% respectively. The mechanism of these chlorinations is discussed.     

A study of the electrochemical reduction of nitrobenzene to p-aminophenol

The electrochemical reduction of nitrobenzene has been studied in aqueous organic solvents containing sulphuric acid. It is shown that the yield ofp-aminophenol and the maximum current density for the reaction is dependent upon the solvent, the cathode metal, the electrode potential, the concentration of acid and the rate of stirring of the catholyte. The changes of products would not be obvious from theI-E curves but it is possible to find conditions where the yield ofp-aminophenol is > 75% at a current density of 150 mA cm^–2.     

The kinetics of the silver (I)/silver (II) couple at a platinum electrode in perchloric and nitric acids

The kinetics of the silver (I)/silver (II) couple have been studied in 3 M nitric acid and 3 M perchloric acid at a platinum electrode. It has been found that silver (II) can be produced in high current yields in a fast electrode reaction although the conversion of silver (I) to silver (II) is limited by the chemical reaction of silver (II) with water. It has also been shown that silver (I) can successfully be used as a catalyst or current carrier in the anodic oxidation of organic and inorganic substrates.     

On detecting co-resident cloud instances using network flow watermarking techniques

Virtualization is the cornerstone of the developing third-party compute industry, allowing cloud providers to instantiate multiple virtual machines (VMs) on a single set of physical resources. Customers utilize cloud resources alongside unknown and untrusted parties, creating the co-resident threat—unless perfect isolation is provided by the virtual hypervisor, there exists the possibility for unauthorized access to sensitive customer information through the exploitation of covert side channels. This paper presents co-resident watermarking, a traffic analysis attack that allows a malicious co-resident VM to inject a watermark signature into the network flow of a target instance. This watermark can be used to exfiltrate and broadcast co-residency data from the physical machine, compromising isolation without reliance on internal side channels. As a result, our approach is difficult to defend against without costly underutilization of the physical machine. We evaluate co-resident watermarkingunder a large variety of conditions, system loads and hardware configurations, from a local laboratory environment to production cloud environments (Futuregrid and the University of Oregon’s ACISS). We demonstrate the ability to initiate a covert channel of 4 bits per second, and we can confirm co-residency with a target VM instance in $<$ 10 s. We also show that passive load measurement of the target and subsequent behavior profiling is possible with this attack. We go on to consider the detectability of co-resident watermarking, extending our scheme to create a subtler watermarking attack by imitating legitimate cloud customer behavior. Our investigation demonstrates the need for the careful design of hardware to be used in the cloud.     

Effect of Composition on the Electromechanical Properties of (1-x)Pb(Mg1/3Nb2/3)O3−XPbTiO3 Ceramics

Ceramic lead magnesium niobate–lead titanate ((1-x)PMN_-xPT) of different compositions has been prepared by the columbite precursor method. This study discusses compositions ranging from 0.94PMN–0.06PT to 0.60PM–N0.40PT, focusing on two areas of the (1-x)PMN_xPT system: compositions that exhibit electrostrictive behavior, and those that show piezoelectric behavior. In electrostrictive compositions where x is in the range of 0.06–0.20, the dielectric constant and electromechanical coupling factor dependencies on the bias field are evaluated. The optimal electromechanical properties are obtained with the composition 0.82PMN–0.18PT, measured at temperature T = T_m (the temperature of maximum dielectric constant) = 80°C and with a dc bias of 5 kV/cm. X–ray diffractometry is used to show that the (1-x)PMN_-xPT system has a compositionally wide two–phase region and that 0.655PMN–0.345PT is the morphotropic phase boundary (MPB) composition. Electromechanical property evaluation shows that the optimal piezoelectric properties (piezoelectric charge coefficient ( d₃₃ ) value of 720 pC/N, dielectric constant ( K ) value of 5400, and electromechanical planar and thickness coupling coefficient ( k_p and k_t , respectively) values of 62% and 46%, respectively) are obtained at the MPB composition.     

Specificity of Systemically Released Cotton Volatiles as Attractants for Specialist and Generalist Parasitic Wasps

Cotton plants under herbivore attack release volatile semiochemicals that attract natural enemies of the herbivores to the damaged plant. The volatiles released in response to herbivory are not only released from the damaged leaves but from the entire cotton plant. We found that cotton plants that released myrcene, (Z)-3-hexenyl acetate, (E)--ocimene, linalool, (E)-4,8-dimethyl-1,3,7-nonatriene, (E)--farnesene, and (E, E)-4,8,12-trimethyl-1,3,7,11-tridecatetraene systemically from undamaged leaves of caterpillar damaged plants were attractive to the generalist parasitoid Cotesia marginiventris and the specialist parasitoid Microplitis croceipes. Plants from which the caterpillar damaged leaves were removed and that released those compounds systemically were significantly preferred over undamaged control plants in two-choice experiments in a flight tunnel. Artificially damaged cotton plants that released green leafy volatiles and constitutive terpenoids were less attractive for M. croceipes and C. marginiventris. Only C. marginiventris preferred artificially damaged plants over undamaged control plants, whereas M. croceipes showed no preference. The apparent lack of specificity of systemically released compounds in response to different herbivores feeding on the lower leaves is discussed.     

Synthesis and dielectric properties of polystyrene‐clay nanocomposite materials

Polystyrene‐clay nanocomposite (PsCN) materials were synthesized and their properties of crystallinity, thermal behavior, and dielectric characteristics were investigated. A polymerizable cationic surfactant, [2‐(dimethylamino)ethyl]triphenylphonium bromide, was used for the intercalation of montmorillonite (MMT). The organophilic MMT was prepared by Na⁺‐exchanged MMT and ammonium cations of a cationic surfactant in an aqueous medium. Organophilic styrene monomers were intercalated into the interlayer regions of organophilic clay hosts followed by a free‐radical polymerization. Exfoliation to 2 wt % MMT in the polystyrene (PS) matrix was achieved as revealed by X‐ray diffraction (XRD) and transmission electron microscopy (TEM). Thermal properties by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) were also studied. The dielectric properties of PsCNs in the form of film with clay loading from 1.0 to 5.0 wt % were measured under frequencies of 100 Hz–1 MHz at 25–70°C. A decreased dielectric constant and low dielectric loss were observed for PsCN materials. The dielectric response at low frequency that originated from dipole orientation was suppressed due to the intercalation of clay materials. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1368–1373, 2004     

Performance of estimating depth in projection based stereoscopic virtual display

Accurate distance estimation is essential for effective user interaction with objects appearing in the virtual space. Research has shown that the distance estimation in the virtual space is not as accurate as that in the real world. The inaccuracy phenomenon is almost exclusively documented for estimating objects appearing straight ahead of the eye. A collection of the accuracy data for targets located in different angles of view in the visual field may be useful in aiding the design of user‐virtual object interaction. This study collected the object to object distance estimation accuracy for targets displayed stereoscopically. There are five horizontal and two vertical viewing angles and three depths, resulting in a total of 30 locations in the virtual space. The distance estimation for any of the 30 object pairs were performed with or without the aid of spatial cues. Significant factors influencing the accuracy and time of distance estimation were identified. Implications of the finding were discussed with respect to the stereoscopic display environment.     

An introduction to the Information Display Measurement Standard 1, the first display measurement standard from the International Committee for Display Metrology

On June 1, 2012, the Information Display Measurement Standard version 1 was released. This is the first standard from the worldwide standard group, the International Committee for Display Metrology, a standards committee within SID, and it culminates several years worth of development from many contributors at various levels. It has 26 top‐level chapters and a total over 450 sections of all parts, including over 200 measurement sections and 8 appendices that cover 133 topics of display metrology, tutorials, technical discussions, and references. Herein is an overview of the Information Display Measurement Standard version 1, including the structure of the document, tips, tricks, and hidden features, how it is maintained, support material, a breakdown of its contents, and finally, a sampling of four of the over 200 measurements. The standard is available as a free download and can be found on the International Committee for Display Metrology home page — http://www.icdm‐sid.org .