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941.
On-body communications around the human torso are considered, using ultra-wideband transmissions. The velocity of the diffracted wave propagating around the body is extracted from frequency- domain spatial correlation analyses. 相似文献
942.
943.
Raymond F. Boyer 《Polymer International》1982,14(4):163-172
Polymers under discussion can be represented by [CH2)nR]p where R is CH2, CF2, O, S or CH = CH; and where n can vary from 0 to ∞. The copolymer, P(ethylene-alt-TFE) is also included. These polymers tend to be highly crystalline with resultant confusion about their Tg and hence their Tg/Tm values and a clarification scheme is proposed in which it is considered that each such polymer has a double glass transition, Tg(L)/f(χc), Tg(U) = F(χc); and a sub-glass T<Tg(L) at 0.75 Tg(L), where F(χc) signifies a function of fractional crystallinity, χc. T<Tg(L) and Tg(L) increase linearly with Tm. The ratio, Tg(L)/Tm, is therefore, not a constant but is close to 0.5. T<Tg(L)/Tg(L) is also not a constant but is close to 0.75. Tg(U) lies within a wedge whose top and bottom sides increase with Tm. The premelting, intracrystalline transition temperature, Tαc, is also a linear function of Tm. It is suggested that the scheme outlined above should help to resolve uncertainties in assigning transition temperatures for unsubstituted polymers. The low Tg/Tm values for these polymers is discussed in terms of their small da/dc ratios and small crosssectional areas per chain. 相似文献
944.
In this study, an analytical model is developed to include the effect of material fracture on the overall behavior of a structure. The continuum damage mechanics approach is used to describe the continuous deterioration of the material stiffness that leads to total failure. The damage evolution is assumed to be anisotropic and the effect of the triaxiality of stress on the fracture criterion is included in the analysis. The above modifications were applied to an existing finite element program which is capable of including both geometric and material nonlinearities in the analysis. The program was used to analyze a welded tubular connection (T-joint). This joint was chosen because fracture was shown experimentally to control its ultimate behavior. Solid finite elements were used to model the chord and the branch in the intersection region, wedge elements were used for the weld profile, and the rest of the geometry was modeled using shell elements. The joint was subjected to an increasing amount of displacement at the far end of the branch. The loading was continued until total failure. During this process, the evolution of the damage and its propagation were monitored. Divergence of the solution was obtained at a failure load of 42.4 kips compared to 44.0 kips obtained experimentally. In addition, the failure mode of the joint predicted by the analysis was identical to that observed experimentally. 相似文献
945.
Abstract. The estimation of the spectral density function of a stationary Gaussian process at the input of an instantaneous nonlinearity is considered when the nonlinearity is known and a finite set of observations of the output process is given. A class of spectral estimates is considered and their quadratic-mean consistency is established; precise asymptotic expressions for their bias and covariance are derived and their asymptotic normality is obtained. 相似文献
946.
T.F. Zabel 《臭氧:科学与工程》1985,7(1):11-30
Only two water works in the UK apply ozone at present as part of their treatment, onefor taste and odor control and theother forcolor removal. Forthetwo applicationus ozone was the most economical option at thetime theplants were installed andozone has been successful for the purpose for which it was designed. 相似文献
947.
V. V. Tcherdyntsev S. D. Kaloshkin A. I. Salimon E. A. Leonova I. A. Tomilin J. Eckert F. Schurack V. D. Rogozin S. P. Pisarev Yu. P. Trykov 《Materials and Manufacturing Processes》2002,17(6):825-841
Al-Cu-Fe alloys were prepared from elemental powders in a high-energy planetary ball mill. A sequence of solid state reactions resulting in quasicrystal (QC) phase formation takes place during heating of the as-milled powder. These reactions were studied by both differential scanning calorimetry and x-ray diffraction methods. Mechanically alloyed powders were consolidated by cold and hot pressing, as well as by explosive compaction. After annealing at sufficiently high temperatures, the consolidated samples are single-phase QC, except the ones consolidated by explosion. The high reactivity of the as-milled alloys causes the appearance of high porosity of the consolidated samples after the annealing. 相似文献
948.
Growth rates of spherulites were measured in poly(p-phenylene sulphide) crystallized from the melt and the quenched glass over the temperature range 100°C–280°C, possibly the most extensive overall range yet reported for any polymer and, as such, most propitious for study of régime III crystallization. For a medium M.wt. polymer, a régime II → III transition was obtained at 208°C using values of transport parameters common to many polymers (, T∞ ? Tg = 30°C) together with experimentally determined values of T0m(315°C) and Tg(92°C). Under these conditions, the régime III/II slope ratio was found to be 2.07 (i.e. only 3.5% higher than predicted by régime theory), and reasonable estimates of surface free energies and of the work of chain folding were obtained. Other choices of the transport terms, including WLF and zero values, did not allow successful kinetic analyses. Although a régime I → II transition is predicted to occur at the high-temperature end of our growth-rate data, we found no experimental evidence for it. For a low M.wt. polymer, our analysis showed that régime III kinetics is obeyed at low temperatures, while at higher ones there is a continuous departure from that behaviour without, however, full attainment of régime II kinetics. 相似文献
949.
Hydrogenation of canola oil in the presence of nickel and the methyl benzoate-chrome carbonyl complex 总被引:1,自引:0,他引:1
L. J. Rubin S. S. Köseoglu L. L. Diosady W. F. Graydon 《Journal of the American Oil Chemists' Society》1986,63(12):1551-1557
Canola oil was hydrogenated using a mixture of homogeneous methyl benzoate-Cr(CO)3 and heterogeneous nickel catalysts. The effect of the methyl benzoate-Cr(CO)3_to-nickel ratio on the activity, specific isomerization index, linoleate and linolenate selectivities, and fatty acid composition
was evaluated, and the results compared with those obtained with commercial nickel catalyst and methyl benzoate-Cr(CO)3 used individually. At higher chromium-to-nickel ratios the activity of nickel was inhibited and the system behaved essentially
like the pure chrome complex, while at low chromium-to-nickel ratios the characteristics of the nickel predominated. In a
short transition zone relatively high reaction rates were obtained with significantly reducedtrans-isomer levels in the product. In a broader sense, it may be possible to combine a homogeneous and heterogeneous catalyst
while retaining the advantages of both. We may thus be able to design catalyst systems for specific applications. 相似文献
950.
A Dielectrophoretic Chip With a 3-D Electric Field Gradient 总被引:1,自引:0,他引:1