Preparation and Characterization of Novel Polyimides from 2,6-bis[1-(p-dimethylaminophenylimino)ethyl] pyridine for the Selective Extraction of some Metals

Summary A group of new polyimides has been prepared by solution condensation of 2,6-bis[1-(p-dimethylaminophenylimino)ethyl] pyridine containing pendant NMe₂ units and various dianhyrides in N-methylpyrrolidone (NMP). The tridentate (N-N′-N) pydim ligands were prepared by Schiff-base condensation of 2,6-diacetylpyridine and 4-dimethylaminoaniline in the presence of formic acid as catalyst. These polymers were investigated for their extraction capabilities for Zn(II), Mn(II), Cu(II), Cd (II) and Ni(II) and at different pH. Under different conditions enhanced selectivity was observed. Up to 98% quantitative recoveries were observed for all metals.     

Acoustic Properties of Amorphous Solids at Very Low Temperatures: The Quest for Interacting Tunneling States

We discuss the strain dependence of the acoustic properties of amorphous metals in both normal and superconducting states, in the temperature range 0.1 mK<T<1 K. A crossover is found when the strain energy is of the order of the effective interaction energy between tunneling systems at the corresponding temperature. Our results provide clear evidence for the interaction between tunneling systems, whose energy is in quantitative agreement with theoretical expectations, and reveal that without the knowledge of the corresponding strain dependences, the measured temperature dependences below ～50 mK of the acoustic properties of disordered solids are rather meaningless.     

A probabilistic model for cleavage fracture with a length scale--parameter estimation and predictions of stationary crack experiments

This study presents a large experimental investigation in the transition temperature region on a modified A508 steel. Tests were carried out on single-edge-notch-bend specimens with three different crack depth over specimen width ratios to capture the strong constraint effect on fracture toughness. Three test temperatures were considered, covering a range of 85 °C. All specimens failed by cleavage fracture prior to ductile tearing. A recently proposed probabilistic model for the cumulative failure by cleavage was applied to the comprehensive sets of experimental data. This modified weakest link model incorporates a length scale, which together with a threshold stress reduce the scatter in predicted toughness distributions as well as introduces a fracture toughness threshold value. Model parameters were estimated by a robust procedure, which is crucial in applications of probabilistic models to real structures. The conformity between predicted and experimental toughness distributions, respectively, were notable at all the test temperatures.     

The Gas-to-Particle Heat Transfer and Hydrodynamics in Spouted Bed Drying of Sawdust

This article presents experimental results for spouted bed drying of sawdust, carried out in a full-scale as well as in a laboratory-scale dryer using air as well as steam as drying media. The aim is to present design parameters for a spouted-bed sawdust dryer that can be used by the industry in designing full-scale dryers. A hydrodynamically stable spouted jet spouted bed was obtained. The heat transfer characteristics of the bed were represented in terms of a volumetric heat transfer coefficient (VHC). When sawdust is dried in a spouted bed, the mean VHC is increasing up to fiber saturation level (20-25% wb) from 40 to 110 W/m³ K. The VHC decreases with the residence time and with an increased static bed height. Gas temperature profiles are also presented for the bottom part of the drying chamber.     

MOBSY: Integration of vision and dialogue in service robots

Abstract. This contribution introduces MOBSY, a fully integrated, autonomous mobile service robot system. It acts as an automatic dialogue-based receptionist for visitors to our institute. MOBSY incorporates many techniques from different research areas into one working stand-alone system. The techniques involved range from computer vision over speech understanding to classical robotics. Along with the two main aspects of vision and speech, we also focus on the integration aspect, both on the methodological and on the technical level. We describe the task and the techniques involved. Finally, we discuss the experiences that we gained with MOBSY during a live performance at our institute.     

High yield formation of carbon nanotubes using a rotating cathode in open air

Carbon nanotubes (CNTs) have been synthesized using the arc discharge method with a rotating graphite disc as the cathode. Arcing was carried out in open air and without the use of catalysts. The current density was maintained constant through out the experiment, while, the rate of rotation of the cathode and atmosphere under which arcing was carried out were changed during experimentation. Characterization of the samples produced indicates that rotation of the cathode has a significant impact on the quality and yield of the process. It is proposed that rotation of the cathode drags plasma formed between two electrodes away from high temperature region. This results in a sudden quenching of the reactive plasma. The time available for nucleation and growth phenomena is significantly reduced and thus leads to the formation of highly graphitic multi walled CNTs (yield 60%) and traces of double walled CNTs.     

Agglomeration and networks in spatial economies

We consider the parallel developments in the economics of agglomeration and the economics of networks. We explore the complementarities between the productivity benefits of agglomeration and those of network linkages, arguing that networks of actors dispersed over space may substitute for agglomerations of actors at a single point.JEL Classification: D20, L14, R30