Efficient Resource Allocation and Paving the Way Towards Highly Efficient IMT-Advanced Systems

Recently, new network topologies including relays and meshed networks have emerged as a key technology receiving a lot of attention due to the increasing need for additional resources such as spectrum, and required high data-rates specified by the International Mobile Telecommunication-Advanced (IMT-Advanced) systems (Report ITU-R M.1645, Framework and overall objectives of the future development of IMT-2000 and systems beyond IMT-2000). These systems are designed to provide diverse services sustaining low to high mobility applications and yielding a significant improvement in terms of Quality-of-Service (QoS). In this paper, we identify and describe the novel network topologies that will be able to accommodate the high data rates demanded within the spectrum scarcity paradigm. By efficiently integrating mesh networks and flexible resource sharing, the overall network efficiency is shown to increase. In addition, direct terminal-to-terminal (T2T) communication both with and without the use of relays is presented, where terminals communicate without the use of base stations (BSs) as it is done in conventional systems. The results show significant gains in terms of throughput, average frame delays and power consumption compared to conventional networks. Finally, open issues and potential challenges are addressed.

Simultaneous oxidation of nitrogen oxides and sulfur dioxide with ozone and hydrogen peroxide

The use of ozone and hydrogen peroxide for the simultaneous oxidation of nitrogen and sulfur oxides was studied in experiments carried out in a stirred cell. It was found that in a gas mixture, containing both nitrogen and sulfur oxides, only the nitrogen oxides are oxidized by ozone. Contrary to earlier results, sulfur dioxide does not disturb the oxidation of nitrogen oxides under dry conditions. The consumption of ozone in the oxidation of nitric oxide was slightly below the stoichiometric level because the ozone was introduced into the reactor in the oxygen flow. When the molar ratio between ozone and nitric oxide was more than 0.4, some of the nitric oxide was oxidized to higher oxides of nitrogen, the final product being a solid mixture of N₂O₅ and (NO)₂S₂O₇. Some nitrosyl sulfuric acid was formed in the aqueous solution of hydrogen peroxide in addition to sulfuric acid under wet conditions. Some white solid was found on the walls of the reactor. This solid is said it the literature to consist of H₂SO₄, HNOSO₄ and (NO)₂S₂O₇.     

Influence of erroneous learning samples on adaptation in on-line handwriting recognition

We have considered problems involved in the self-supervised learning process of an on-line handwriting recognition system. Our system is able to recognize isolated characters by comparing them to prototype characters with a method based on the Dynamic Time Warping algorithm. The recognition system is adapted by adding new prototypes, inactivating confusing or erroneous ones, and reshaping existing prototypes with a method based on the Learning Vector Quantization. We have analyzed the sources of erroneous learning samples and studied the influence of such samples on the performance of the recognizer via simulations. In these simulations, two adaptation strategies combined with four methods for inactivating prototypes were applied. The results of the simulations showed that the adaptation strategies are able to improve the system's recognition rate and the prototype inactivation methods do reduce the harmful effects of erroneous learning samples.     

Solid-State Reactions between Cu(Ni) Alloys and Sn

Solid-state interfacial reactions between Sn and Cu(Ni) alloys have been investigated at the temperature of 125°C. The following results were obtained. Firstly, the addition of 0.1 at.% Ni to Cu decreased the total thickness of the intermetallic compound (IMC) layer to about half of that observed in the␣binary Cu/Sn diffusion couple; the Ni addition decreased especially the thickness of Cu₃Sn. Secondly, the addition of 1 to 2.5 at.% Ni to Cu further decreased the thickness of Cu₃Sn, increased that of Cu₆Sn₅ (compared to that in the binary Cu/Sn couple) and produced significant amount of voids at the Cu/Cu₃Sn interface. Thirdly, the addition of 5 at.% Ni to Cu increased the total thickness of the IMC layer to about two times that observed in the binary Cu/Sn diffusion couple and made the Cu₃Sn disappear. Fourthly, in contrast to the previous case, the addition of 10 at.% Ni to Cu decreased the total IMC (Cu₆Sn₅) thickness again close to that of the Cu/Sn couple. With this Ni content no voids were detected. The results are rationalized with the help of␣the thermodynamics of the Sn-Cu-Ni system as well as with kinetic considerations.     

Encapsulated Cobalt Oxide on Carbon Nanotube Support as Catalyst for Selective Continuous Hydrogenation of the Showcase Substrate 1‐Iodo‐4‐nitrobenzene

A carbon nanotube supported catalyst containing cobalt/cobalt oxide (Co/Co₃O₄) nanoparticles encapsulated within a shell of nitrogen‐doped graphene layers (Co₃O₄/NGr@CNT) was prepared. It shows excellent chemoselectivity in the hydrogenation of 1‐iodo‐4‐nitrobenzene, which contains an iodine substituent highly sensitive against hydrodehalogenation. In contrast to traditional activated charcoal‐supported catalysts such as Pt‐V/C or the closely related Vulcan carbon black supported Co₃O₄/NGr@C, the advantageous morphological properties of the CNT support allow for the application of the new Co₃O₄/NGr@CNT as a fixed bed catalyst in a continuous flow reactor. Under optimized conditions, no dehalogenation side products could be detected. This remarkable selectivity in combination with its mechanical stability under operation conditions render Co₃O₄/NGr@CNT a catalyst particularly relevant for application in continuous processes based on a packed bed reactor.

     

Effects of chlorine and sulphur on particle formation in wood combustion performed in a laboratory scale reactor

Fine particle formation in wood combustion was studied in a laboratory scale laminar flow reactor at various flue gas chlorine and sulphur concentrations. Aerosol samples were quenched at around 850 °C using a porous tube diluter. Fine particle number concentrations, mass concentrations, size distributions and chemical compositions were measured. In addition, flue gas composition, including SO₂ and HCl, was monitored. Experimental results were interpreted by thermodynamic equilibrium calculations.Addition of HCl clearly raised fine particle mass concentration (PM1.0) which was because of increased release of ash-forming material to fine particles. Especially the release of K, Na, Zn and Cd to fine particles increased. These species form chlorides which apparently increases their volatilization from the fuel. When a sufficient amount of SO₂ was supplied in a chlorine rich combustion (S/Cl molar ratio from 4.7 to 7.5), most of the HCl stayed in the gas phase, release of ash-forming elements decreased and also fine particle concentrations dropped significantly. The sulphation of alkali metals is suggested to play a key role in the observed decrease in the fine particle concentration. It seems that the formation of sulphates leads to alkali metal retention in the coarse particle fraction.     

X-ray absorption study of rare earth ions in Sr2MgSi2O7:Eu,R persistent luminescence materials

The valence of the europium dopant and selected rare earth co-dopants (Ce³⁺, Dy³⁺, and Yb³⁺) in the Sr₂MgSi₂O₇:Eu²⁺,R³⁺ persistent luminescence materials were studied by room temperature XANES measurements. The results indicated the co-existence of both divalent and trivalent europium in all the studied materials. The relative amount of Eu³⁺ was observed to increase upon increasing exposure to X-rays, as expected by the persistent luminescence mechanism. This suggests a simultaneous filling of oxygen vacancies initially created by the reducing preparation conditions. For the Dy and Yb co-dopants, only trivalent species were observed. On the other hand, traces of tetravalent cerium were present in the Eu,Ce co-doped materials.     

Distinguishing fuel and lubricating oil combustion products in diesel engine exhaust particles

The main sources of particulate emissions from engines are fuel and lubricating oil. In this study, particles emitted by a medium speed diesel engine for locomotive use were characterized chemically by using a soot particle aerosol mass spectrometer (SP-AMS). Additionally, positive matrix factorization (PMF) was applied to the SP-AMS data for the separation of fuel from lubricating oil and/or oil additives in diesel engine emissions. The mass spectra of refractory species, i.e., metals and rBC, were included in the PMF input matrix in addition to organics in order to utilize the benefit of the SP-AMS to measure non-refractory and refractory species. In general, particulate matter emitted by the diesel engine was dominated by organics (51%) followed by refractory black carbon (rBC; 48%), trace metals and inorganic species (1%). Regarding the sources of particles, PMF indicated four factors for particle mass of which two were related to lubricating oil-like aerosol (LOA1, 29% and LOA2, 24%) and two others to diesel-like fuel aerosol (DFA1, 35% and DFA2, 12%). The main difference between LOA1 and LOA2 was the presence of soot in LOA1 and metals in LOA2 factors. DFA factors represented burned (DFA1) and unburned fuel (DFA2). The results from the PMF analysis were completed with particle size distributions, volatility measurements and particle morphology analyses.

Copyright © 2019 American Association for Aerosol Research     

Technology beats algorithms (in exact string matching)

More than 120 algorithms have been developed for exact string matching within the last 40 years. We show by experiments that the naïve algorithm exploiting SIMD instructions of modern CPUs (with symbols compared in a special order) is the fastest one for patterns of length up to about 50 symbols and extremely good for longer patterns and small alphabets. The algorithm compares 16 or 32 characters in parallel by applying SSE2 or AVX2 instructions, respectively. Moreover, it uses loop peeling to further speed up the searching phase. We tried several orders for comparisons of pattern symbols, and the increasing order of their probabilities in the text was the best.     

Power boiler fuel augmentation with a biomass fired atmospheric circulating fluid-bed gasifier

The successful experience in developing the advanced Foster Wheeler atmospheric circulating fluidized-bed (ACFB) combustion system subsequently led to the development of the ACFB gasification (ACFBG) Technology in the early 1980s. The driving force for the development work was the dramatic increase in oil price during this period. The primary advantage of the ACFBG technology is that it enables the substitution of expensive fuels (e.g. oil or gas) with cheaper solid fuels. Prior to this Lahti project, Foster Wheeler had supplied four waste wood fired commercial scale ACFBGs in the mid-1980s to the pulp and paper industry with capacities from 17 to 35 MW_th based on fuel input. These units are still in successful operation today. Lahden Lämpövoima Oy (LLOy) is a Finnish power company producing power and district heat for the City of Lahti. The company is jointly owned by the city of Lahti and by Fortum Oy, the largest utility power company in Finland. LLOy operates the Kymijärvi Power Plant located nearby the city of Lahti in Southern Finland. To keep the energy prices as low as possible, Plant personnel are continuously looking for the most economical fuel sources, and simultaneously, trying to improve the environmental aspects of the energy production. Currently, about 300 GW h/a of different types of biofuels and refuse fuels are available in the Lahti area. On an annual basis, the available amount of biofuels and refuse fuels is enough to substitute for about 15% of the fuels burned in the main boiler, equaling up to 30% of the coal typically used. The aim of the LLOy Kymijärvi Power Plant gasification project is a commercial scale demonstration of direct gasification of wet biofuel and the use of hot, raw and very low calorific gas directly in the existing coal fired boiler. The gasification of biofuels and co-combustion of gases in the existing coal-fired boiler offers many advantages such as: recycling of CO₂, decreased SO₂ and NO_x emissions, efficient way to utilize biofuels and recycled refuse fuels, low investment and operation costs, and utilization of the existing power plant capacity. Furthermore, only small modifications were required in the boiler and process upsets in the gasifier do not shut down the power plant. The first two years of operation (1998 and 1999) have been excellent with good availability for the gasifier and its related components. During 1998 several measurements and tests with different fuel combinations were performed. This paper presents the project in detail as well as the most important results of the first measurements. The EU Thermie program has supported this project.