Preparation of gold nanoparticles (GNP) aqueous suspensions by a new method involving Tiron

A new method is proposed to produce gold nanoparticles (GNP) by in situ reduction of a gold salt dissolved in water. The reducing agent used is Tiron instead of the citrate anion most often mentioned in literature. The influence of various parameters has been investigated, such as the content of Tiron with respect to that of the precursor of gold HAuCl₄, or the initial pH of the solution after mixing of reactants. It is shown that Tiron also exerts a positive influence as a dispersant, which impedes agglomeration of gold nanoparticles. The typical average size of GNP synthesized in the present work is close to 7 nm.     

Atmospheric corrosion of reference metals in Antarctic sites

This paper presents the results obtained at three Antarctic test sites participating in the “Ibero-American Map of Atmospheric Corrosiveness” (MICAT), a project on atmospheric corrosion carried out during the period 1988–1994 at some 70 sites distributed across 12 countries of the Latin-American region, Spain and Portugal. The three Antarctic sites are located near the coastline.The singular climatic characteristics of Antarctic regions are related with the purity of the air, the absence of rainfall and the formation of ice on the metallic surface during an important part of the exposure time. However, electrochemical activity is possible below ice layers. This situation affects the structure and morphology of corrosion product films and the resulting corrosion rates of metallic surfaces.     

Modeling and Analysis of a Long Thin Conducting Stripline

A long thin conducting stripline embedded in a dielectric and centered between two large conducting plates, i.e., the stripline environment, is considered. The stripline is modeled as infinitely long, infinitely thin, and perfectly conducting by first considering a stripline of finite length, thickness, and conductivity in a dielectric layer. Starting from Maxwell's equations and assuming that the current on the stripline is a propagating wave in length direction, asymptotic expressions for the fields inside and in the neighbourhood of the stripline are deduced. These expressions are used to model the stripline in the stripline environment, which leads to a boundary-value problem for the electric potential. This problem is solved by two different approaches, leading to integral equations for the current and for an auxiliary function describing the electric potential. A relation between the current and the auxiliary function is deduced, which is used to obtain asymptotic expressions for current and impedance. Results are compared with a numerical solution of the integral equation for the current and with results in literature.     

Strategies to improve the performance of very low bit rate speech coders and application to a variable rate 1.2 kb/s codec

This paper presents several strategies to improve the performance of very low bit rate speech coders and describes a speech codec that incorporates these strategies and operates at an average bit rate of 1.2 kb/s. The encoding algorithm is based on several improvements in a mixed multiband excitation (MMBE) linear predictive coding (LPC) structure. A switched-predictive vector quantiser technique that outperforms previously reported schemes is adopted to encode the LSF parameters. Spectral and sound specific low rate models are used in order to achieve high quality speech at low rates. An MMBE approach with three sub-bands is employed to encode voiced frames, while fricatives and stops modelling and synthesis techniques are used for unvoiced frames. This strategy is shown to provide good quality synthesised speech, at a bit rate of only 0.4 kb/s for unvoiced frames. To reduce coding noise and improve decoded speech, spectral envelope restoration combined with noise reduction (SERNR) postfilter is used. The contributions of the techniques described in this paper are separately assessed and then combined in the design of a low bit rate codec that is evaluated against the North American Mixed Excitation Linear Prediction (MELP) coder. The performance assessment is carried out in terms of the spectral distortion of LSF quantisation, mean opinion score (MOS), A/B comparison tests and the ITU-T P.862 perceptual evaluation of speech quality (PESQ) standard. Assessment results show that the improved methods for LSF quantisation, sound specific modelling and synthesis and the new postfiltering approach can significantly outperform previously reported techniques. Further results also indicate that a system combining the proposed improvements and operating at 1.2 kb/s, is comparable (slightly outperforming) a MELP coder operating at 2.4 kb/s. For tandem connection situations, the proposed system is clearly superior to the MELP coder.     

Linear demosaicing inspired by the human visual system.

There is an analogy between single-chip color cameras and the human visual system in that these two systems acquire only one limited wavelength sensitivity band per spatial location. We have exploited this analogy, defining a model that characterizes a one-color per spatial position image as a coding into luminance and chrominance of the corresponding three colors per spatial position image. Luminance is defined with full spatial resolution while chrominance contains subsampled opponent colors. Moreover, luminance and chrominance follow a particular arrangement in the Fourier domain, allowing for demosaicing by spatial frequency filtering. This model shows that visual artifacts after demosaicing are due to aliasing between luminance and chrominance and could be solved using a preprocessing filter. This approach also gives new insights for the representation of single-color per spatial location images and enables formal and controllable procedures to design demosaicing algorithms that perform well compared to concurrent approaches, as demonstrated by experiments.     

Application du recuit simulé à la synthèse d’antennes en réseau constituées d’éléments annulaires imprimés

This publication consists of an analysis and a synthesis by the amplitude law of linear and planar ring printed antennas array. The analysis of the structure is based on the modified cavity model which allows taking into account the fringing fields effects. The synthesis problem is solved by the simulated annealing method based on a random process research controlled by temperature parameter. The feeding network amplitude permitting to produce an optimal radiation pattern is then given. Various synthesis results for linear and planar arrays are presented.     

An integrated system to remote monitor and control anaerobic wastewater treatment plants through the internet.

The TELEMAC project brings new methodologies from the Information and Science Technologies field to the world of water treatment. TELEMAC offers an advanced remote management system which adapts to most of the anaerobic wastewater treatment plants that do not benefit from a local expert in wastewater treatment. The TELEMAC system takes advantage of new sensors to better monitor the process dynamics and to run automatic controllers that stabilise the treatment plant, meet the depollution requirements and provide a biogas quality suitable for cogeneration. If the automatic system detects a failure which cannot be solved automatically or locally by a technician, then an expert from the TELEMAC Control Centre is contacted via the internet and manages the problem.     

Fluorescence and IR characterization of epoxy cured with aliphatic amines

Cure reactions of the stoichiometric mixtures of diglycidyl ether of bisphenol A (DGEBA) and two very low molecular weight aliphatic polyether diamines (PED) were studied by using fluorescence and mid- and near-IR spectroscopic techniques. As the cure proceeded, the primary amine groups in PED are converted to the secondary and the tertiary amines. Near-IR spectral analysis was used to calculate the concentration of the three amine groups as a function of cure time. The decrease in the fluorescence intensity of DGEBA at about 307 nm was observed due to more effective quenching of the tertiary amine groups in PED, in comparison to the primary and the secondary amine groups. A large decrease in fluorescence intensity at 75 and 95 °C cure was observed. The amount of all the amine species was estimated from NIR spectra to shed light on the cure kinetics of PPO (polypropylene oxide) in comparison with PEO (polyethylene oxide) epoxy, as well as to explain their fluorescence behavior.The fluorescence intensity changes were correlated to the extent of epoxy reaction obtained by mid- and near-IR spectroscopy.