New chemosensors based on thiomacrocycle-containing coumarin-343 fluoroionophor: X-ray structures and previous results on the effect of cation binding on the photophysical properties

Two new emissive chemosensors based on coumarin-343 have been synthesized, and their photophysical studies conducted. L1 contains an aza-thio macrocycle ring as the chelating unit, which has great affinity for soft metal ions, whereas L2 is a parent species without macrocyclic unit. Both compounds were separated by column chromatography and characterized by elemental analysis, ¹H,¹³C NMR, UV–vis and FAB mass spectroscopy. The X-ray structures of L1 and L2 and the supramolecular interactions in the solid state are discussed. Preliminary results on the metal–ion sensing effects of the ligands are presented. Titrations with Ag⁺, Pd²⁺ and Ni²⁺ have been studied by UV–vis absorption and fluorescence spectroscopy.     

Fatty acid composition of selected roes from some marine species

Fifteen roes from different marine fish species available in Spain were analyzed in order to determine their fatty acid (FA) composition, especially the eicosapentaenoic acid (20:5n‐3, EPA) and docosahexaenoic acid (22:6n‐3, DHA) contents. Roes from Atlantic bonito (Sarda sarda), European squid (Loligo vulgaris), cuttlefish (Sepia spp.), lumpfish (Cyclopterus lumpus), European hake (Merluccius merluccius), Atlantic salmon (Salmo salar) and gonads of male Atlantic mackerel (Scomber scombrus) reached EPA + DHA amounts higher than 30% of the total FA, and among them, roes from lumpfish, European hake and salmon provide different FA type ratios that could make them adequate as dietary sources of EPA and DHA.     

Control of C.I. Basic Violet 10 aggregation in aqueous solution by the use of poly(sodium 4-styrenesulfonate)

The aggregation behavior of C.I. Basic Violet 10 in the presence of poly(sodium 4-styrenesulfonate) was modified, as a consequence of short-range interactions. In aqueous acidic media, the cationic dye forms hydrophobic ion pairs with polymeric benzene sulfonate groups which tend to aggregate in H-contacts, this tendency being readily influenced by the relative concentration of the macromolecule with respect to that of the dye. In the case of dilute aqueous dye solutions (≤10^?4 M), for which the probability of dye self-aggregation is small, C.I. Basic Violet 10 self-contacts are forced in the presence of a moderate excess of poly(sodium 4-styrenesulfonate). At dye concentrations >10^?4 M, for which the probability of dye self-aggregation increases, dye-dye contacts are minimized in the presence of a large excess of the polymer. Hence, the luminescence of dye solutions can be tuned insorar as, that of dilute dye solutions is quenched whilst that of concentrated dye solutions can be enhanced. This behavior was not observed for other polyelectrolytes such as poly(sodium vinylsulfonate), or the more hydrophobic poly(sodium 2-(N-acrylamido)-2-methyl-propanesulfonate).     

Fabrication of bronze components by metal injection moulding using powders with different particle characteristics

The aim of this work is to fabricate bronze components by metal injection moulding (MIM) studying the possibility of changing partially or totally the gas atomised powder by water atomised ones that are cheaper than the former. In order to carry out this study, a bronze 90/10 gas atomised spherical powder (usual MIM powder <22 μm) and two water atomised irregular powders (particle size <35 μm and <140 μm) were mixed in different proportions. As received powders and their mixtures were used to fabricate feedstocks and processed by MIM to evaluate the influence of powder particle size and morphology on debinding and sintering stages. Finally, both mechanical properties hardness and maximum flexural stress were determined to characterize the sintered materials. The addition of irregular fine and coarse powders was found to affect the moulding process, although densities and mechanical properties close to values of gas atomised one were obtained after sintering. Therefore, the use of water atomised bronze powders could be a promising way to diminish production costs in this technology.     

Electrochemical and morphological characterization of poly(12-pyrrol-1′-yl dodecanoic acid)

12-Pyrrol-1′-yl dodecanoic acid was prepared and electrochemically polymerized on ITO electrodes by three different methods. The electrochemical and morphological properties of poly(12-pyrrol-1′-yl dodecanoic acid) films were investigated by cyclic voltammetry, galvanostatic charge–discharge curves and AFM, which characteristics varied as function of deposition method. Films deposited by potentiodynamic and galvanostatic methods showed capacitive properties and are promising for application in polymeric capacitors.     

Influence of workpiece hardness on EDM performance

The aim of this research is to show the influence of the hardness of the alloy steel on the material removal rate and on the workpiece surface roughness.The Taguchi methodology was used to study that influence. The result of the verification test for workpiece surface roughness was a strong confirmation. This type of outcome allows the use of the additive model to predict the workpiece surface roughness with an average error of 0.4%.The result of the verification test for material removal rate was a poor confirmation due to an interaction of parameters. This type of outcome does not allow the additive model to predict the material removal rate with accuracy. Therefore, a linear regression model was developed for material removal rate using workpiece hardness and its interactions, among other variables. This model predicts the material removal rate with an average error of 1.06%.These results show that workpiece hardness and its interactions have influence on the material removal rate and on the workpiece surface roughness.     

Experimental evaluation of alkaline treatment as a method for enhancing the enzymatic digestibility of autohydrolysed Acacia dealbata

BACKGROUND: Acacia dealbata wood samples were subjected to hydrothermal processing in aqueous media, yielding a liquid phase (containing xylooligosaccharides) and a solid phase, enriched in cellulose, which was treated with alkaline solutions to obtain solids with improved susceptibility towards enzymatic hydrolysis. The effects of the most influential variables involved in the alkaline processing (sodium hydroxide concentration, temperature and reaction time) on solid yield, solid composition and kinetic parameters involved in the modelling of the enzymatic hydrolysis were assessed using the response surface methodology (RSM). RESULTS: Analysis of the RSM equations allowed selection of operational conditions (temperature = 130 °C, sodium hydroxide concentration = 4.5%, time of alkaline processing = 3 h), leading to selective removal of non‐cellulosic components and to a solid substrate highly susceptible to enzymatic hydrolysis. Operating at an enzyme loading of 20 FPU (filter paper units) g^?1 autohydrolysed, extracted solids (denoted AES) with a liquor to solid ratio of 30 g liquor g^?1 AES, solutions containing 29.7 g glucose L^?1 (corresponding to a yield of 47.3 g glucose per 100 g solids from autohydrolysis) were obtained after 48 h. CONCLUSION: Samples of Acacia dealbata wood were processed by autohydrolysis, sodium hydroxide treatment and enzymatic hydrolysis, yielding xylooligomers and processed solids highly susceptible to the enzymatic hydrolysis. Copyright © 2009 Society of Chemical Industry     

Theoretical considerations on small color differences ascribed to the standard observer made on the basis of individual color‐matching functions

An analytical method to determine how color‐matching functions influence the perception of chromaticity differences is proposed. We show that, as a consequence of the observer metamerism, a metameric color‐match perceived by one observer may appear to be a significant mismatch to a different observer. It is also shown that, on average, the differences between the color‐matchings made by two different observers can be estimated to be in the order of 2 CIELAB units. © 2009 Wiley Periodicals, Inc. Col Res Appl, 34, 194–200, 2009     

Comparison of color gamuts among several types of paper with the same printing technology

In this work, we have studied the relationship among the colorimetric properties of different types of paper, having different finishing and grammage. Their color reproduction capability has also been analyzed by using the same printing technology (inkjet printing). On the one hand, we have plotted CIELAB data under the illuminant D50 into constant lightness and hue‐angle planes to be compared with MacAdam limits and with Pointer's real‐world surface color. On the other hand, we have calculated the volume gamut of the color solid associated to each color paper gamut. Analyzing the results, we have checked that there is not any clear relationship among the colorimetric properties of paper (for instance, CIE whiteness index, etc.) and the color gamut volume associated. However, the colorimetric parameters associated to the printed sample showed a quite good linear correlation between the minimum lightness (or the maximum blackness value) of the printed color chart and the color gamut volume. In particular, the greatest color gamut volume corresponds to the glossy papers taking into account this correlation for inkjet printing. © 2009 Wiley Periodicals, Inc. Col Res Appl, 34, 330–336, 2009     

NETmix®, a new type of static mixer: Modeling,simulation, macromixing,and micromixing characterization

NETmix® is a new technology for static mixing based on a network of chambers connected by channels. The NETmix® model is the basis of a flow simulator coupled with chemical reaction used to characterize macro and micromixing in structured porous media. The chambers are modeled as perfectly mixing zones and the channels as plug flow perfect segregation zones. A segregation parameter is introduced as the ratio between the channels volume and the whole network volume. Different kinetics and reactants injection schemes can be implemented. Results show that the number of rows in the flow direction and the segregation parameter control both macro and micromixing, but the degree of micromixing is also controlled by the reactants injection scheme. The NETmix® model enables the systematic study of micromixing and macromixing for different network structures and reaction schemes, enabling the design of network structures to ensure the desired yield and selectivity. © 2009 American Institute of Chemical Engineers AIChE J, 2009