Bistable composite laminates: Effects of laminate composition on cured shape and response to thermal load

This paper develops a finite element (FE) approach using commercial ANSYS V11.0 software to accurately predict the cured shape of bistable composites by including the influence of manufacturing imperfections, such as resin rich areas and ply-thickness variations. Laminate composition was characterised by optical microscopy and their cured shapes measured using a Peak Motus motion analysis system. The FE model accurately predicts observed differences between laminate curvature in the two stable states. Localised reversal of curvature resulting from through-thickness shear stress is also predicted. Structural response to thermal loading was experimentally characterised showing a temperature dependent deflection rate and a residual curvature caused by non-reversible residual stresses. FE-predictions show good agreement with experiment over the range 20–110 °C. The presented data highlights the importance of manufacturing processes and materials selection in the design of thermally stressed multi-stable composite structures.     

UV absorption in solutions and crystals of potassium dihydrogen phosphate

The effects of impurities and growth conditions on the optical quality of potassium dihydrogen phosphate (KDP) crystals were examined. The transmittance of crystals grown under various conditions was measured in the range 200–400 nm for a larger number of impurities than previously. The highest transmittance is afforded by crystals grown from solutions with the stoichiometric composition at 55‡C and a growth rate of 1 mm per day.     

A framework for generating tunable test functions for multimodal optimization

Multimodal function optimization, where the aim is to locate more than one solution, has attracted growing interest especially in the evolutionary computing research community. To evaluate experimentally the strengths and weaknesses of multimodal optimization algorithms, it is important to use test functions representing different characteristics and various levels of difficulty. The available selection of multimodal test problems is, however, rather limited and no general framework exists. This paper describes an attempt to construct a software framework which includes a variety of easily tunable test functions. The aim is to provide a general and easily expandable environment for testing different methods of multimodal optimization. Several function families with different characteristics are included. The framework implements new parameterizable function families for generating desired landscapes. Additionally the framework implements a selection of well known test functions from the literature, which can be rotated and stretched. The software module can easily be imported to any optimization algorithm implementation compatible with the C programming language. As an application example, 8 optimization approaches are compared by their ability to locate several global optima over a set of 16 functions with different properties generated by the proposed module. The effects of function regularity, dimensionality and number of local optima on the performance of different algorithms are studied.     

The Helsinki Office Environment Study: Air Change in Mechanically Ventilated Buildings

Abstract The objective of this study was to assess the magnitude and balance of mechanical ventilation in the rooms of Helsinki metropolitan office buildings with different types of ventilation systems. A random sample of 50 office buildings was selected from the Building Registry. Of these buildings, the 33 that have a mechanical ventilation system were included in this study. Most office buildings in the Helsinki metropolitan area have a ducted supply and exhaust system and hot water radiator heating. Air recirculation is used in about half of the buildings which have a mechanical supply and exhaust system. The average exhaust airflow was 1.2 L/s, m² (SD 0.73) or 17.2 L/s per person (SD 11.6). The variation of the airflows was found to be very high among the buildings, and among the rooms within the buildings. Therefore, even though the ventilation rates on average comply with the Finnish building code, it was found that many people were working in offices with airflows which were either too low or unnecessarily high.     

Two-dimensional multipoles from arbitrary current densities in polygonal domains

A complex analytic multipole decomposition of the magnetic field produced by an arbitrary, continuous current density in a two-dimensional polygonal domain is obtained by series expanding the Green's function of complex magnetic field. The multipole coefficients are given explicitly as functions of the vertex coordinates of the polygon.     

Properties of porous materials of copper and nichrome fibers

Luginy Machine Building Institute. Translated from Metallovedenie i Termicheskaya Obrabotka Metallov, No. 4, pp. 46–48, April, 1992.     

Structural and plasma characterization of the power effect on the chromium thin film deposited by DC magnetron sputtering

The chromium (Cr) films on silicon Si(100) substrate are prepared using DC magnetron sputtering technique at an argon gas pressure of 3 Torr for different applied powers (40—140 W). The chemical composition, the thicknesses and the structural characterization of the deposited Cr films are studied and analyzed using energy dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), and X-ray diffraction (XRD), respectively. Furthermore, the generated plasma parameters, including floating potential, plasma potential, electron density, ion density and electron temperature, have been measured, and the automated Langmuir probe is used for the Cr films deposition. The ion and metal fluxes are also determined. The results show that the Cr film thickness enhances with the higher applied power. The Cr deposited films properties are characterized and correlated with the measured plasma parameters.     

On the syntheses of branched saturated fatty acids

In order to investigate the relation between the structure of mono-branched saturated fatty acids and their physical properties, a three-factor central composite design was constructed. For this purpose sixteen different fatty acids were prepared. The synthetic strategy was to use if possible, a few common starting materials for the preparation of most of the acids. Thus alkylation and hydrolysis of oxazolines were used for the preparation of 2-butylhexanoic acid, 2-methyloctadecanoic acid, 2-hexadecyloctadecanoic acid and 2-pentyloctadecanoic acid. A number of acids were prepared from thiophene derivatives followed by desulfurization with Raney-Nickel alloy under alkaline conditions. Thus, starting from 3-ethylthiophene, 4-ethyl-2-thiophenecarboxylic acid and 4-ethyl-2-methyl-5-thiophenecarboxylic acid were prepared, which upon desulfurization gave the desired 4-methylhexanoic acid. From 3-bromo-2-methylthiophene, 3-ethyl-2-methyl-5-thiophenecarboxylic acid was preparedvia 3-acetyl-2-methylthiophene and 3-ethyl-2-methylthiophene. Desulfurization gave 4-ethylhexanoic acid. Another approach started with 2-acylthiophenes, which were reacted with Grignard reagent to yield the appropriate olefins. By metalation and reaction with carbon dioxide, these were transformed to the corresponding 2-thiophenecarboxylic acids. Upon desulfurization, the desired fatty acids were obtained. In this way 6-propyldecanoic acid, 6-hexyldodecanoic acid, 6-methyldodecanoic acid and 6-pentylpentadecanoic acid were prepared. The remaining four acids were prepared from some of the branched acids described above through Kolbe reactions of dioic acids. Thus 16-methyloctadecanoic acid and 10-methyl-dodecanoic acid were obtained from 4-methylhexanoic acid, 16-ethyloctadecanoic acid from 4-ethylhexanoic acid and 9-pentyloctadecanoic acid from 6-pentylpentadecanoic acid.     

Effects of silane and the lowering of pH on the properties of phenol–formaldehyde resol resins and resin coatings

Phenol–formaldehyde resol resins were modified by the addition of silane (3‐aminopropyltriethoxysilane) and the lowering of pH (formic acid). The effects of the modifications on the properties of the resins during storage were studied through comparison with the parent resins and by viscosity measurements, NMR spectroscopy, ultraviolet–visible spectroscopy, and differential scanning calorimetry. Resin coatings on paper were prepared to determine the influence of discoloration of the resin solution on the color of the cured resin. A decrease in the pH of the NaOH‐catalyzed resin solutions lightened the color of the solutions and corresponding coatings, whereas silane additions made the coatings slightly more yellow. The lowering of pH increased the viscosities and decreased the reactivities of the resin solutions compared with the unmodified reference resins during storage. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1933–1941, 2007