Unexpected products of the allyldiethylamine hydroformylation homogeneously catalyzed by rhodium complexes

Attempts to carry out the hydroformylation of allyldiethylamine homogeneously catalyzed by rhodium complexes led to unexpected formation of N,N,N,N-tetraethyl-1,4-diaminobutane and 4-(diethylamino)-1-butanole as final products. The role of the catalyst on the product formation and the reaction mechanism are briefly discussed.     

Direct magnetic problem solved by quaternion analog of 3-D Cauchy-Riemann system

Contents By applying the quaternion variant of the Cauchy integral formula the general solution of the direct magnetic problem is derived. The applicability of the method presented here is shown by investigating and calculating the outer field of a analytically magnetized sphere.

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Die Lösung der direkten Aufgabe der Magnetik mit Hilfe des Quaternionen Analogons des 3-D Cauchy-Riemann Systems

Übersicht Die allgemeine Lösung der direkten Aufgabe der Magnetik wird mit Hilfe der Quaternionenvariante des Cauchy-Integrals abgeleitet. Die Anwendbarkeit der vorgestellten, Methode wird am Beispiel des berechneten äußeren magnetischen Feldes einer analytisch magnetisierten Kugel untersucht.

     

Conversion electron Mössbauer spectroscopy of the surface crystallization of the Fe75Co9B16 amorphous alloy

Using a new design of helium-methane gas-flow detector of conversion electrons for Mössbauer spectroscopy, non-uniform nucleation of the primary -Fe-Co phase on both contact and free surfaces of the Ar(+H₂) annealed amorphous Fe₇₅Co₉B₁₆ alloy was observed in its early crystallization stage. In this state the amount of crystalline phase on the contact ribbon side surpasses that on the free one by a factor of three, whereas no traces of volume crystallization were observed in the transmission spectra. By applying ion implantation to both ribbon surfaces, a slight reduction of the crystalline phase contribution was found. Magnetic domain structure observations were performed in order to evaluate the influence of surface crystallization on magnetic properties.     

On the probability theory on MV algebras

 The paper contains a review of some results concerning probability theory on MV algebras (laws of large numbers, central limit theorem, martingale convergence theorem). Also some algebraic and methodical aspects are discussed.     

Honeymoon with IWBs: A qualitative insight in primary students' views on instruction with interactive whiteboard

The main purpose of this study was to investigate the views of primary students about interactive whiteboard [IWB] use in their classes from attitudinal and pedagogical perspectives. Research was designed as an empirical approach to phenomenology. Data was collected from fifty primary students (fourth to eighth) through focus group interviews. Nvivo 9 qualitative data analysis software was used to analyze data. Results showed that students like instruction with IWB especially for such reasons/capabilities as practical and economical use, better visual presentation, and test-based use. Students were predominantly uncomfortable with the technical problems. They believed that instruction with IWB positively impacted their learning especially because of visualization and contextualization, effective presentation, test-based use, and motivational factors. Finally it was inferred that IWBs were not used to their full potential, and both technical problems and common practices indicated that teachers were still at an initial stage of transmission to instruction with IWB and they needed both technical and pedagogical training.     

The investigation of metastable ζ-hcp phase in the Ag-rich f c c region of Ag-In alloys rapidly quenched from the melt

Stacking faults, which were detected in the Ag-In system, have been examined by transmission electron microscopy and electron diffraction. An enhanced concentration of stacking faults in splat cooled specimens as well as the formation of a metastable hexagonal phase in the f c c region of the alloy was observed. As far as we know this is the first case of the terminal solid solubility being reduced by rapid quenching. Terminal solid solubility is reduced because of the high concentration of structural defects introduced by quenching, e.g. dislocations and stacking faults, which serve as the nuclei for the transformation from the f c c to the h c p structure. Our measurements and calculations show that the stacking fault energy minimum is shifted to lower electron concentrations with respect to the stacking fault energy minimum corresponding to the equilibrium phase boundary for the f c c-h c p transformation. The new metastable phase boundary for this transformation was confirmed by X-ray examinations. We explain this earlier h c p phase appearance in rapid quenched specimens as the consequence of enhanced interaction of the Fermi surface and contracted Brillouin zone. The Brillouin zone contraction we attributed to quenched-in vacancies.     

Observation of a half-quantum-flux periodicity pattern in an rf SQUID with small critical currents

We have found experimentally that rf SQUID's working in a nonhysteretic mode with small critical currents give exactly at resonance and at very low rf bias a triangular pattern with a period equal to half of one elementary quantum of magnetic flux. We discuss a possible explanation of this peculiar result.