四川盆地剑阁地区须家河组致密砾岩储层裂缝特征及对天然气产能的影响

天然裂缝是致密砾岩储层重要的储集空间和主要的渗流通道,影响致密天然气的成藏、富集及单井产能。利用地表相似露头、岩心、薄片、测井和生产资料,在研究四川盆地剑阁地区须家河组致密砾岩储层天然裂缝类型和发育特征的基础上,分析并阐明了天然裂缝对天然气产能的影响。四川盆地剑阁地区须家河组致密砾岩储层发育穿砾缝、砾内缝和砾缘缝,从地质成因上,穿砾缝为构造裂缝,砾内缝包括构造、构造-成岩和母岩裂缝,砾缘缝为构造-成岩裂缝。其中穿砾缝的面密度、孔隙度和渗透率最大,其次为砾内缝,砾缘缝相对较小,穿砾缝对致密砾岩储层贡献更大,更有利于天然气富集高产。裂缝发育程度与产气量呈正相关,裂缝密度越大,产气量越高。在近东西(EW)向至NWW-SEE向现今地应力作用下,不同方向裂缝对天然气产能的贡献存在差异,其中近EW向裂缝地下开度相对较大,连通性好,对天然气产能贡献最大;其次为近NS和NW-SE向裂缝, NE-SW向裂缝对天然气产能的贡献较小。     

Synthesis of boron-doped double-walled carbon nanotubes by the catalytic decomposition of tetrahydrofuran and triisopropyl borate

Boron-doped double-walled carbon nanotubes (DWCNTs) were produced by the catalytic decomposition of tetrahydrofuran and triisopropyl borate over a Fe–Mo/MgO catalyst at 900 °C. The synthesized B-doped DWCNTs had average outer and inner diameters in the range of 1.6–2.4 nm and 0.8–1.6 nm within the bundle, respectively. They had a larger interlayer spacing in the range of 0.36–0.39 nm, than did undoped DWCNTs. The B-C bonding evident from the B 1s signals in the X-ray photoelectron spectroscopy results indicated that highly coordinated boron atoms replaced the carbon atoms within the graphene sheet. As the triisopropyl borate concentration was increased from 0 to 2.5 M, the substituted boron concentration increased from 0.8 to 3.1 at.%. The results demonstrate that the substituted boron concentration in the hexagonal carbon lattices can be easily controlled by regulating the triisopropyl borate concentration.     

PID Control of Planar Nonlinear Uncertain Systems in the Presence of Actuator Saturation

This paper investigates PID control design for a class of planar nonlinear uncertain systems in the presence of actuator saturation.Based on the bounds on the growth rates of the nonlinear uncertain function in the system model,the system is placed in a linear differential inclusion.Each vertex system of the linear differential inclusion is a linear system subject to actuator saturation.By placing the saturated PID control into a convex hull formed by the PID controller and an auxiliary linear feedback law,we establish conditions under which an ellipsoid is contractively invariant and hence is an estimate of the domain of attraction of the equilibrium point of the closed-loop system.The equilibrium point corresponds to the desired set point for the system output.Thus,the location of the equilibrium point and the size of the domain of attraction determine,respectively,the set point that the output can achieve and the range of initial conditions from which this set point can be reached.Based on these conditions,the feasible set points can be determined and the design of the PID control law that stabilizes the nonlinear uncertain system at a feasible set point with a large domain of attraction can then be formulated and solved as a constrained optimization problem with constraints in the form of linear matrix inequalities(LMIs).Application of the proposed design to a magnetic suspension system illustrates the design process and the performance of the resulting PID control law.     

基于ANSYS的PE-HD实壁管性能与尺寸的关系

采用ANSYS逆向模拟分析高密度聚乙烯(PE-HD)实壁管的环刚度测试过程,研究了管材环刚度为6.3时其规格尺寸如直径和壁厚与原材料性能之间的关系,并分析了标准YD/T 841.2-2008的合理性。结果表明,材料的泊松比对管材最大变形量影响较小;材料的弯曲弹性模量越大,管材最大变形量越小;管材环刚度达到6.3时所需要的原材料弯曲弹性模量值与其径厚比成正比直线关系;标准YD/T 841.2-2008中关于某些壁厚的规定存在不合理性,即按照标准中规定的某些壁厚尺寸,生产PE-HD实壁管所用原材料无法达到环刚度为6.3时所需要的弯曲弹性模量值。     

固体碱催化法合成壬基酚甲醛树脂的工艺研究

本文研究了以壬基酚和甲醛为原料,固体碱为催化剂,合成壬基酚醛树脂的新工艺。对酚醛比、催化剂用量、反应时间、反应温度四个影响因素进行了正交优化实验,确定了优化合成工艺,得到了黏度为20000 mPa·s左右的壬基酚醛树脂,该工艺稳定可靠。     

席夫碱化合物及其复配体系对碳钢缓蚀性能的研究

采用极化曲线、交流阻抗法对比研究了3-甲基-4-胺基缩肉桂醛-5-巯基-1,2,4-三氮唑席夫碱(MACHMT)与其原料的复配体系肉桂醛(CA)、3-甲基-4-氨基-5-巯基-1,2,4-均三唑(简称MACMT)对Q235碳钢在25℃下、0.5mol/L盐酸介质中的缓蚀性能,并探讨了这两种缓蚀剂的缓蚀机理。实验表明,肉桂醛与3-甲基-4-氨基-5-巯基-1,2,4-均三唑的复配体系对Q235碳钢的整体缓蚀性和稳定性均高于相同浓度席夫碱化合物MACHMT。     

天然气净化厂硫磺回收及尾气处理过程有机硫的产生与控制措施

天然气净化厂硫磺回收及尾气处理装置尾气中有机硫含量对SO_2减排有重要影响。研究表明,硫磺回收装置的燃烧炉、催化反应器及尾气处理装置的加氢水解反应器中均会生成有机硫。对此,可通过减少酸气中烃类含量、提高燃烧炉温度、选择合适催化剂类型以及保持较高的加氢水解反应温度等措施,有效降低有机硫的生成量。同时,对于过程中生成的有机硫,应优化催化剂组合方式,在各级反应器中叠加水解,并保持加氢水解单元的高效转化,将进入灼烧炉的有机硫含量降至最低,从而实现生产装置尾气排放达标。     

Rational design on photoelectrodes and devices to boost photoelectrochemical performance of solar-driven water splitting: a mini review

As an eco-friendly, efficient, and low-cost technique, photoelectrochemical water splitting has attracted growing interest in the production of clean and sustainable hydrogen by the conversion of abundant solar energy. In the photoelectrochemical system, the photoelectrode plays a vital role in absorbing the energy of sunlight to trigger the water splitting process and the overall efficiency depends largely on the integration and design of photoelectrochemical devices. In recent years, the optimization of photoelectrodes and photoelectrochemical devices to achieve highly efficient hydrogen production has been extensively investigated. In this paper, a concise review of recent advances in the modification of nanostructured photoelectrodes and the design of photoelectrochemical devices is presented. Meanwhile, the general principles of structural and morphological factors in altering the photoelectrochemical performance of photoelectrodes are discussed. Furthermore, the performance indicators and first principles to describe the behaviors of charge carriers are analyzed, which will be of profound guiding significance to increasing the overall efficiency of the photoelectrochemical water splitting system. Finally, current challenges and prospects for an in-depth understanding of reaction mechanisms using advanced characterization technologies and potential strategies for developing novel photoelectrodes and advanced photoelectrochemical water splitting devices are demonstrated.     

A Novel Body-tied Silicon-On-Insulator(SOI) n-channel Metal-Oxide-Semiconductor Field-Effect Transistor with Grounded Body Electrode

A novel body-tied silicon-on-insulator(SOI) n-channel metal-oxide-semiconductor field-effect transistor with grounded body electrode named GBSOI nMOSFET has been developed by wafer bonding and etch-back technology. It has no floating body effect such as kink phenomena on the drain current curves, single-transistor latch and drain current overshoot inherent in a normal SOI device with floating body. We have characterized the interface trap density, kink phenomena on the drain current (I_DS-V_DS) curves, substrate resistance effect on the I_DS-V_DS curves, subthreshold current characteristics and single transistor latch of these transistors. We have confirmed that the GBSOI structure is suitable for high-speed and low-voltage VLSI circuits.     

Exploring cell tower data dumps for supervised learning-based point-of-interest prediction (industrial paper)

Exploring massive mobile data for location-based services becomes one of the key challenges in mobile data mining. In this paper, we investigate a problem of finding a correlation between the collective behavior of mobile users and the distribution of points of interest (POIs) in a city. Specifically, we use large-scale cell tower data dumps collected from cell towers and POIs extracted from a popular social network service, Weibo. Our objective is to make use of the data from these two different types of sources to build a model for predicting the POI densities of different regions in the covered area. An application domain that may benefit from our research is a business recommendation application, where a prediction result can be used as a recommendation for opening a new store/branch. The crux of our contribution is the method of representing the collective behavior of mobile users as a histogram of connection counts over a period of time in each region. This representation ultimately enables us to apply a supervised learning algorithm to our problem in order to train a POI prediction model using the POI data set as the ground truth. We studied 12 state-of-the-art classification and regression algorithms; experimental results demonstrate the feasibility and effectiveness of the proposed method.