Chemical and physical properties of short rotation tree species

The European Union’s growth strategy (Europe 2020) requires reductions in greenhouse gas (GHG) emissions and increases in both renewable energy sources and energy efficiency. Short rotation forestry (SRF) has achieved greater awareness due to these targets. Short rotations (1–12 years), rapid growth and the ability to coppice are typical for SRF. Salix, Populus, Alnus and Betula have smaller GHG emissions of biomass production than annual agricultural plant species, since management and harvesting are not needed every year. Physicochemical properties of these species must be known when their utilisation is planned and optimised. Seven tree species were studied: three willows (Salix myrsinifolia, Salix schwerinii and Klara), one aspen (Populus tremula), one alder (Alnus glutinosa) and two birches (Betula pendula and Betula pubescens). One stem wood (S) sample and one stem wood and bark (SB) sample of each tree were investigated. Furthermore, seven surface soil samples and four incineration ash samples (two S. myrsinifolia and two S. schwerinii) were also studied. Heating values, densities, ash contents as well as carbon, hydrogen and nitrogen contents of all short rotation biomass samples were usually quite typical for the corresponding tree species. Additional observations included the accumulation of cadmium in willow and aspen samples, small chloride content values, and higher ash- and element contents in SB samples than in the corresponding S samples. Nutrient content of ash was usually higher in the S sample, contradictory to biomass samples, and finally the cadmium content of the ash samples was very high.     

Wet oxidation lumped kinetic model for wastewater organic burden biodegradability prediction

In many cases, treatment of wastewaters requires a combination of processes that very often includes biological treatment. Wet oxidation (WO) in combination with biotreatment has been successfully used for the treatment of refractory wastes. Therefore, information about the biodegradability of wastewater solutes and particulates after wet oxidation is very important. The present work proposes a model that can describe the oxidation process via organic concentration characteristics such as chemical oxygen demand (COD), biochemical oxygen demand (BOD), and immediately available BOD (IA BOD) and so can allow the prediction of biodegradability (i.e., BOD/COD ratio). The reaction mechanism includes the destruction of nonbiodegradable substances bytwo pathways: oxidation to carbon dioxide and water and oxidation to larger biodegradable compounds with their further degradation to smaller ones measured via IA BOD. The destruction of small biodegradable compounds to end products is also included in the model. The experiments were performed at different temperatures (170-200 degrees C) and partial oxygen pressures (0.5-1.5 MPa) in a batch stainless steel high-pressure autoclave. The model of concentrated thermomechanical pulp circulation water was selected for the experiments. The proposed model correlates with the experimental data well and it is compared with other WO models in the literature.     

Characterization of Process Conditions in Industrial Stainless Steelmaking Electric Arc Furnace Using Optical Emission Spectrum Measurements

Emission spectroscopy is a potential method for gaining information on electric arc furnace (EAF) process conditions. Previous studies published in literature on industrial EAF emission spectra have focused on a smaller scales and DC arc furnaces. In this study emission spectrum measurements were conducted for 140t AC stainless steelmaking EAF at Outokumpu Stainless Oy, Tornio Works, Finland. Four basic types of emission spectra were obtained during the EAF process cycle. The first one is obscured by scrap steel, the second is dominated by thermal radiation of the slag, the third is dominated by alkali peaks and sodium D-lines and the fourth is characterized by multiple atomic emission peaks. The atomic emission peaks were identified by comparing them to the NIST database for atomic emission lines and previous laboratory measurements on EAF slag emission spectra. The comparison shows that the optic emission of an arc is dominated by slag components. Plasma conditions were analyzed by deriving plasma temperature from optical emissions of Ca I lines. The analysis suggests that accurate information on plasma conditions can be gained from outer plasma having a plasma temperature below 7000 K (6727 °C).     

Moth‐eye antireflection coating fabricated by nanoimprint lithography on 1 eV dilute nitride solar cell

We report on the performance of biomimicked antireflection coating applied to dilute nitride solar cell. The coating consists of nanostructures replicating the moth‐eye geometry and has been fabricated by nanoimprint lithography directly within the window layer covering the dilute nitride absorbing junction. The mean reflectivity within the spectral range of 320–1800 nm remains under 5% for incident angles up to 45°. The effect of the coating on the cell performance was assessed by measuring the current–voltage characteristics under simulated solar illumination. A clear performance increase was identified when comparing a solar cell with the moth‐eye coating with a solar cell having a standard SiN_x/SiO₂ coating. Copyright © 2012 John Wiley & Sons, Ltd.     

Performance analysis of power generating sludge combustion plant and comparison against other sludge treatment technologies

Expectations on wastewater sludge treatment and recovery of its energy and material contents are increasing because of the tightening legislation and the obligation to reduce environmental impacts of sludge disposal. The objective of this study was to analyze the performance of a heat and power generating sludge combustion plant from technical and economical viewpoints and to compare the studied concept to optional sludge treatment technologies. The plant performance was modeled for sewage sludge produced by approximately 200,000 inhabitants. Two plant sizes below 1000 kWe range were investigated, the smaller plant using sludge as the only fuel and the larger plant with wood chips as the additional fuel. The plants were compared with heat-only plants of similar size. The payback periods for heat-only plants are typically shorter than with the cogenerating plants because the changes in plant investment affect stronger the economy than do the revenues from selling electricity. The gate fee of sludge treatment has the strongest effect on the payback period. The selection of the plant concept (cogeneration, heat only or pure electricity generation) is, however, affected more by the local demand of heat and electricity than pure economy. The selection of the optimal technology for sludge treatment is a complicated task. The studied concept can be the optimal choice, for example, if there is no cement kiln or co-combustion possibility near the source of sludge, if there is no land enhancement demand for the digested sludge, or if the energy surplus from combustion compared to anaerobic digestion is considered more valuable than nutrient recovery possibility from digestion. If the new technology concept is found competitive, it still has to meet the challenge of acceptability from the business, social and cultural points of view.     

Role of Bose enhancement in photoassociation

Abstract

We discuss the role of Bose enhancement of the dipole matrix element in photoassociation, using stimulated Raman adiabatic passage as an example. In a non-degenerate gas the time scale for coherent optical transients tends to infinity in the thermodynamic limit, whereas Bose enhancement keeps this time scale finite in a condensate. Coherent transients are therefore absent in photoassociation of a thermal non-degenerate gas, but are feasible if the gas is a condensate.     

Improving integrity of on-line grammage measurement with traceable basic calibration

The automatic control of grammage (basis weight) in paper and board production is based upon on-line grammage measurement. Furthermore, the automatic control of other quality variables such as moisture, ash content and coat weight, may rely on the grammage measurement. The integrity of Kr-85 based on-line grammage measurement systems was studied, by performing basic calibrations with traceably calibrated plastic reference standards. The calibrations were performed according to the EN ISO/IEC 17025 standard, which is a requirement for calibration laboratories. The observed relative measurement errors were 3.3% in the first time calibrations at the 95% confidence level. With the traceable basic calibration method, however, these errors can be reduced to under 0.5%, thus improving the integrity of on-line grammage measurements. Also a standardised algorithm, based on the experience from the performed calibrations, is proposed to ease the adjustment of the different grammage measurement systems. The calibration technique can basically be applied to all β-radiation based grammage measurements.     

A method to measure the fusion strength between expanded polystyrene (EPS) beads

Cellular polystyrene (EPS) is the most commonly used cellular thermoplast whose main applications are insulation and packages. One of its new applications is core material in building elements, and this poses higher requirements for strength. This is particularly evident in self-supporting roof elements. This study presents a method for determining the fusion strength between beads in cellular polystyrene and the dependence of this strength on processing. This method has also enabled us to determine the adhesion of cellular polystyrene beads to other materials, such as glass fibre, and it allows measurement of the fusion strength between EPS beads without the influence of porosity. Fusion strength was found to have a characteristic behaviour. It has an absolute upper limit, and fusion forces approximate this limit asymptotically as heating time is prolonged (this increase is dependent on the energy content of the steam).     

On the time response determination of condensation particle counters

Condensation particle counter (CPC) technology has continued to evolve, with the introduction of several new instruments over the last several years. An important aspect in the characterization of these instruments is the measurement of their time response. Yet there is no standardly accepted approach for this measurement. Here we evaluate different classically used methods for determining CPC time response, and present the potential pitfalls associated with these approaches. Further, we introduce a new simple definition for the term response time, ?, which is based on the first-order systems response, while providing a practical definition by corresponding to ～95% change in concentration. We also present results for various commonly used CPCs, and for the Airmodus A11 nano Condensation Nucleus Counter (nCNC) system, the TSI 3777+3772 Nano Enhancer system, and Aerosol Dynamics Inc.'s (ADI) new versatile water condensation particle counter.

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