Friction stir processing strategies to develop a surface composite layer on AA6061-T6

Friction stir processing (FSP) has been used to produce metal matrix composites by incorporating reinforcement particles in an AA6061-T6 matrix. Two types of particles (Al₂O₃ and SiC) were tested. Powder was placed into a mechanized square section groove on a plate surface and then sealed before FSP. This study investigates the effect of several strategies for reinforcement (number and direction of FSP passes) on the wear resistance behavior of friction stir-processed Al-SiC/Al₂O₃ composites. The distribution and size of the particles in the friction stir-processed zone were studied by optical and scanning electron microscopy. Ball-on-disk test was performed on both base material and surface metal matrix composites (SMMCs), and both friction coefficient and specific wear rate (SWR) were correlated with particle distribution and metallurgical effects on the metallic matrix. For all strategies and for both types of reinforcing particles used in this study, the friction coefficient decreases with respect to the base material. Moreover, the SWR is reduced for the conditions of one single FSP pass and two passes with opposite directions, when SiC are used. However, this positive effect has not been detected with Al₂O₃. Wear mechanisms in base metal and in SMMCs are compared and discussed in detail.     

Dendrite-free lithium electrode cycling via controlled nucleation in low LiPF6 concentration electrolytes

The transition from 3D to 2D lithium deposition can be achieved with low Li-ion concentrations by forming a multitude of lithium nuclei on the lithium surface prior to the deposition using a nucleation pulse followed by pulsed galvanostatic deposition. Under these conditions, homogeneous lithium metal deposition is favored by the diffusion-controlled mass transfer to the nuclei-enriched surface.

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High‐Strength Nanotwinned Al Alloys with 9R Phase

Light‐weight aluminum (Al) alloys have widespread applications. However, most Al alloys have inherently low mechanical strength. Nanotwins can induce high strength and ductility in metallic materials. Yet, introducing high‐density growth twins into Al remains difficult due to its ultrahigh stacking‐fault energy. In this study, it is shown that incorporating merely several atomic percent of Fe solutes into Al enables the formation of nanotwinned (nt) columnar grains with high‐density 9R phase in Al(Fe) solid solutions. The nt Al–Fe alloy coatings reach a maximum hardness of ≈5.5 GPa, one of the strongest binary Al alloys ever created. In situ uniaxial compressions show that the nt Al–Fe alloys populated with 9R phase have flow stress exceeding 1.5 GPa, comparable to high‐strength steels. Molecular dynamics simulations reveal that high strength and hardening ability of Al–Fe alloys arise mainly from the high‐density 9R phase and nanoscale grain sizes.     

Poly(amidoamine)-alginate hydrogels: directing the behavior of mesenchymal stem cells with charged hydrogel surfaces

The surface charge of a biomaterial represents a promising tool to direct cellular behavior, which is crucial for therapeutic approaches in regenerative medicine. To expand the understanding of how the material surface charge affects protein adsorption and mesenchymal stem cell behavior, differently charged surfaces with zeta potentials spanning from ?25?mV to +15?mV were fabricated by the conjugation of poly(amidoamine) to alginate-based hydrogels. We showed that the increase of the biomaterials surface charge resulted in enhanced quantities of biologically available, surface-attached proteins. Since different surface charges were equalized after protein adsorption, mesenchymal stem cells interacted rather with diverse protein compositions instead of different surface features. Besides an enhanced cell attachment to increasingly positively charged surfaces, the cell spreading area and the expression of adhesion-related genes integrin α5 and tensin 1 were found to be increased after adhesion. Moreover, first results indicate a potential impact of the surface charge on mesenchymal stem cell differentiation towards bone and fat cells. The improved understanding of surface charge-related cell behavior has significant impact on the design of biomedical devices and artificial organs.

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When it rains,it pours: Peripartum cardiomyopathy with features of left‐ventricular noncompaction in a hemodialysis patient

Pregnancy and associated pre‐eclampsia carry a high maternal risk in hemodialysis patients, yet no guidelines on how to monitor these patients' cardiovascular function exist. A 34‐year‐old hemodialysis patient presented with peripartum cardiomyopathy after a late second trimester miscarriage. On cardiac magnetic resonance imaging, diagnostic features of left ventricular noncompaction were apparent. Yet, histological and gene panel analyses remained negative. Upon stringent dry weight control and pharmacological heart failure therapy, the pathological changes showed complete regression. As pregnant hemodialysis patients have an excessively increased risk for pre‐eclampsia‐related cardiac disease, thorough screening appears valuable in these patients.     

Atomistic simulation of fracture in TiAl

Atomistic simulations of fracture in L1₀ TiAl were carried out using embedded atom method (EAM) interatomic potentials and molecular statics. We studied the behavior of semi-infinite cracks under mode I loading in different orientations of the crack front and plane. For the orientation, we observed dislocation emission involving the formation of superlattice intrinsic stacking fault (SISF). For the [001](110) orientation, we observed the emission of ordinary 1/2[110] edge dislocations that were highly mobile and had a compact core. We found that cracks with [001](100) orientation cleaved near the Griffith value of loading in a purely brittle manner. Similar behavior was observed for cracks with orientation. This article is based on a presentation made in the symposium “Fundamentals of Gamma Titanium Aluminides”, presented at the TMS Annual Meeting, February 10–12, 1997, Orlando, Florida, under the auspices of the ASM/MSD Flow & Fracture and Phase Transformations Committees.     

Atomistic simulation of fracture in TiAl

Atomistic simulations of fracture in L1₀ TiA1 were carried out using embedded atom method (EAM) interatomic potentials and molecular statics. We studied the behavior of semi-infinite cracks under mode I loading in different orientations of the crack front and plane. For the (111) orientation, we observed dislocation emission involving the formation of superlattice intrinsic stacking fault (SISF). For the [001](110) orientation, we observed the emission of ordinary 1/2[110] edge dislocations that were highly mobile and had a compact core. We found that cracks with [001](100) orientation cleaved near the Griffith value of loading in a purely brittle manner. Similar behavior was observed for cracks with (100) orientation. This article is based on a presentation made in the symposium “Fundamentals of Gamma Titanium Aluminides,” presented at the TMS Annual Meeting, February 10–12, 1997, Orlando, Florida, under the auspices of the ASM/MSD Flow & Fracture and Phase Transformations Committees.     

Two-Grid Mixed Finite-Element Approximations to the Navier–Stokes Equations Based on a Newton-Type Step

A two-grid scheme to approximate the evolutionary Navier–Stokes equations is introduced and analyzed. A standard mixed finite element approximation is first obtained over a coarse mesh of size H at any positive time \(T>0\). Then, the approximation is postprocessed by means of solving a steady problem based on one step of a Newton iteration over a finer mesh of size \(h<H\). The method increases the rate of convergence of the standard Galerkin method in one unit in terms of H and equals the rate of convergence of the standard Galerkin method over the fine mesh h. However, the computational cost is essentially the cost of approaching the Navier–Stokes equations with the plain Galerkin method over the coarse mesh of size H since the cost of solving one single steady problem is negligible compared with the cost of computing the Galerkin approximation over the full time interval (0, T]. For the analysis we take into account the loss of regularity at initial time of the solution of the Navier–Stokes equations in the absence of nonlocal compatibility conditions. Some numerical experiments are shown.     

Identifikation von potenziellen Leitprozessen in Einzugsgebieten

For hazard zoning or planning of control measures the identification of the hydrogeomorphic key process is an important step to determine the recurrent design event. The present methodology for the identification of potential hydrogeomorphic key processes is a practicable tool for experts assessing homogeneous sections of running waters (torrents, mountain streams and low-lying rivers) by means of certain parameters. Filling in the developed matrix from your desk and reviewing the results with field surveys on site, the potential key process is rapidly identified for each homogeneous area, as the evaluation of 12 sample streams in Carinthia shows. Further on this method is a useful tool concerning sediment management concepts according to the National Watercourse Development Plan or financial supporting of control measures at stakeholder waters at the field of competence of the Austrian Flood Control Management.