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21.
Assessment of contaminant releases during utilization of used oils is essential for the determination of environmental acceptability. These paper reports the results of the study examining a toxic metal leachability from used engine oil and sludge samples employing leaching test (TCLP). The leaching test indicated that lead in oil samples exceeded 5-ppm concentration level what qualified them as a toxic waste. The samples of contaminated sludge were found to contain high concentration of total lead, barium and chromium, but the leaching test showed concentration below regulatory limit. The total content of benzene, ethylbenzene, toluene, and xylenes (BETX), and naphthalene in used oil and sludge samples was also determined and was found not to be a significant factor to contamination. 相似文献
22.
The Nelder-Mead simplex method is an optimization routine that works well with irregular objective functions. For a function of $n$ parameters, it compares the objective function at the $n+1$ vertices of a simplex and updates the worst vertex through simplex search steps. However, a standard serial implementation can be prohibitively expensive for optimizations over a large number of parameters. We describe an implementation of the Nelder-Mead method in parallel using a distributed memory. For $p$ processors, each processor is assigned $(n+1)/p$ vertices at each iteration. Each processor then updates its worst local vertices, communicates the results, and a new simplex is formed with the vertices from all processors. We also describe how the algorithm can be implemented with only two MPI commands. In simulations, our implementation exhibits large speedups and is scalable to large problem sizes. 相似文献
23.
Direct Ink-Jet Printing of Vertical Walls 总被引:1,自引:0,他引:1
Xinglong Zhao Julian R. G. Evans Mohan J. Edirisinghe Jin-Hua Song 《Journal of the American Ceramic Society》2002,85(8):2113-2115
Direct jet printing can assemble ceramic powder into a three dimensional shape by firing droplets of ink through a nozzle to build a multiple layered structure. As with stereolithography and selective laser sintering, the surface texture is expected to witness the layered assembly. The ability to create vertical walls by direct ink-jet printing was explored using a test piece based on a maze. The structure and topography are discussed in terms of droplet spreading and drying. 相似文献
24.
Julian Chojnowski Slawomir Rubinsztajn Witold Fortuniak Jan Kurjata 《Journal of Inorganic and Organometallic Polymers and Materials》2007,17(1):173-187
Summary Reactions of hexamethylcyclotrisiloxane, D3, with 1,1,3,3-tetramethyldisiloxane, HMMH, 1,1,1,3,3-pentamethyldisiloxane, HMM, phenyldimethylsilane and phenylmethylsilane catalyzed by tris(pentafluorophenyl)borane were studied. These reactions lead
to ring opening of D3 by the SiH reactant producing open chain oligomers with hydrosilane functionality at one or both chain ends. The reactivity
of the hydrosilanes toward D3 decreases in the series: PhMeSiH2 > HMMH > PhMe2SiH > HMM. Competitive self-oligomerization of HMMH and HMM also occurs. Primary products of these processes are able to enter into reactions with the SiH and D3 reactants; some also undergo cyclization. Thus, consecutive and competitive processes lead to a series of various oligohomologues.
Gas chromatography in conjunction with chemical ionization mass spectroscopy permitted identification of structure and determination
of the basic directions of these oligomerization processes. Polysiloxanes of higher molecular weight may be also formed in
some of these systems. The reactions, which occur in the systems studied, are rationalized on the basis of the mechanism involving
the hydride transfer from silicon to trivalent boron. This includes the transient formation of tertiary trisilyloxonium borate
which decomposes by the hydride transfer to one of the silicon atoms of the trisilyloxonium center.
Footnote: This paper is dedicated to Professor Ian Manners in recognition of his significant contributions to the field of
organometallic polymers. 相似文献
25.
The effects of log-normal pore size distributions on the rejection of uncharged solutes and NaCl at hypothetical nanofiltration membranes have been assessed theoretically. The importance of pore radius-dependent properties such as solvent viscosity and dielectric constant is increased by the introduction of a pore size distribution in calculations. However, the effect of porewise variation in viscosity is less apparent when considered at a defined applied pressure rather than at a defined flux, showing a further advantage of basing theoretical analysis of nanofiltration in terms of applied pressure.Truncated pore size distributions gave better agreement than full distributions with experimental rejection data for a Desal-DK nanofiltration membrane. Such truncation is in agreement with the findings of atomic force microscopy (AFM). Analysis of uncharged solute rejection data alone could not give useful information about membrane pore size distribution. Neither could such a distribution be obtained quantitatively directly from AFM images. However, use of the shape of the distribution obtained by AFM in conjunction with experimental rejection data for an uncharged solute allows calculation of corrected distributions. Importantly, incorporation of such a corrected pore size distribution in calculations of NaCl rejection gave better agreement with experimental data, compared to calculations assuming uniform pores, at high pressure, the region of industrial interest. 相似文献
26.
Julian Chojnowski 《Journal of Inorganic and Organometallic Polymers》1991,1(3):299-323
Some basic aspects of the kinetics and mechanisms of anionic and cationic ring-opening polymerization of cyclic siloxanes are discussed in connection with their use in polymer synthesis. The emphasis is put on the polymerization of strained ring monomers, such as cyclic trisiloxanes, since these provide the possibility of tailoring the polymer structure. Much attention is devoted to association phenomena and to oligomer formation processes.This review is from the Second International Topical Workshop, Advances in Silicon-Based Polymer Science. 相似文献
27.
Maktuba Mohid Julian F. Miller Simon L. Harding Gunnar Tufte Mark K. Massey Michael C. Petty 《Soft Computing - A Fusion of Foundations, Methodologies and Applications》2016,20(8):3007-3022
Evolution-in-materio uses evolutionary algorithms to exploit properties of materials to solve computational problems without requiring a detailed understanding of such properties. We show that using a purpose-built hardware platform called Mecobo, it is possible to solve computational problems by evolving voltages and signals applied to an electrode array covered with a carbon nanotube–polymer composite. We demonstrate for the first time that this methodology can be applied to function optimization and also to the tone discriminator problem (TDP). For function optimization, we evaluate the approach on a suite of optimization benchmarks and obtain results that in some cases come very close to the global optimum or are comparable with those obtained using well-known software-based evolutionary approach. We also obtain good results in comparison with prior work on the tone discriminator problem. In the case of the TDP we also investigated the relative merits of different mixtures of materials and organizations of electrode array. 相似文献
28.
Julian J McAuley Tibério S Caetano Marconi S Barbosa 《IEEE transactions on pattern analysis and machine intelligence》2008,30(11):2047-2054
A recent paper \cite{CaeCaeSchBar06} proposed a provably optimal, polynomial time method for performing near-isometric point pattern matching by means of exact probabilistic inference in a chordal graphical model. Its fundamental result is that the chordal graph in question is shown to be \emph{globally rigid}, implying that exact inference provides the \emph{same} matching solution as exact inference in a complete graphical model. This implies that the algorithm is optimal when there is no noise in the point patterns. In this paper, we present a new graph which is also globally rigid but has an advantage over the graph proposed in \cite{CaeCaeSchBar06}: its maximal clique size is smaller, rendering inference significantly more efficient. However, this graph is not chordal and thus standard Junction Tree algorithms cannot be directly applied. Nevertheless, we show that loopy belief propagation in such a graph converges to the optimal solution. This allows us to retain the optimality guarantee in the noiseless case, while substantially reducing both memory requirements and processing time. Our experimental results show that the accuracy of the proposed solution is indistinguishable from that of \cite{CaeCaeSchBar06} when there is noise in the point patterns. 相似文献
29.
James Alfred Walker Katharina Völk Stephen L. Smith Julian Francis Miller 《Genetic Programming and Evolvable Machines》2009,10(4):417-445
Parallel and distributed methods for evolutionary algorithms have concentrated on maintaining multiple populations of genotypes,
where each genotype in a population encodes a potential solution to the problem. In this paper, we investigate the parallelisation
of the genotype itself into a collection of independent chromosomes which can be evaluated in parallel. We call this multi-chromosomal evolution
(MCE). We test this approach using Cartesian Genetic Programming and apply MCE to a series of digital circuit design problems
to compare the efficacy of MCE with a conventional single chromosome approach (SCE). MCE can be readily used for many digital
circuits because they have multiple outputs. In MCE, an independent chromosome is assigned to each output. When we compare
MCE with SCE we find that MCE allows us to evolve solutions much faster. In addition, in some cases we were able to evolve
solutions with MCE that we unable to with SCE. In a case-study, we investigate how MCE can be applied to to a single objective
problem in the domain of image classification, namely, the classification of breast X-rays for cancer. To apply MCE to this
problem, we identify regions of interest (RoI) from the mammograms, divide the RoI into a collection of sub-images and use
a chromosome to classify each sub-image. This problem allows us to evaluate various evolutionary mutation operators which
can pairwise swap chromosomes either randomly or topographically or reuse chromosomes in place of other chromosomes. 相似文献
30.
In this paper we present a novel methodology based on non-parametric deformable prototype templates for reconstructing the
outline of a shape from a degraded image. Our method is versatile and fast and has the potential to provide an automatic procedure
for classifying pathologies. We test our approach on synthetic and real data from a variety of medical and biological applications.
In these studies it is important to reconstruct accurately the shape of the object under investigation from very noisy data.
Here we assume that we have some prior knowledge about the object outline represented by a prototype shape. Our procedure
deforms this shape by means of non-affine transformations and the contour is reconstructed by minimizing a newly developed
objective function that depends on the transformation parameters. We introduce an iterative template deformation procedure
in which the scale of the deformation decreases as the algorithm proceeds. We compare our results with those from a Gaussian
Mixture Model segmentation and two state-of-the-art Level Set methods. This comparison shows that the proposed procedure performs
consistently well on both real and simulated data. As a by-product we develop a new filter that recovers the connectivity
of a shape.
Francesco de Pasquale received his Ph.D. in Applied Statistics from the University of Plymouth, United Kingdom in 2004 discussing a thesis on Bayesian and Template based methods for image analysis. Since his degree in Physics obtained at the University of Rome ‘La Sapienza’in 1999 his work has been focused on developing models and methods for Magnetic Resonance Imaging, in particular image registration, classification and segmentation in a Bayesian framework. After being appointed a 2-year contract as a Lecturer at the University of Plymouth from 2003 to 2004 he is now a post-Doc researcher at the ITAB, Institute for Advanced Biomedical Technologies, University of Chieti, Italy and he works on the analysis of fMRI and MEG data. Julian Stander was born in Plymouth, UK in 1964. He received a BA in Mathematics with first class honours from University of Oxford in 1987, a Diploma in Mathematical Statistics with distinction from University of Cambridge in 1988, and a PhD from University of Bath in 1992. He has been a lecturer at the School of Mathematics and Statistics, University of Plymouth, since 1993, and was promoted to Reader in 2006. His fields of interest are: applications of statistics including image analysis, spatial modelling and disclosure limitation. He has published over 20 refereed journal articles. 相似文献
Francesco de PasqualeEmail: |
Francesco de Pasquale received his Ph.D. in Applied Statistics from the University of Plymouth, United Kingdom in 2004 discussing a thesis on Bayesian and Template based methods for image analysis. Since his degree in Physics obtained at the University of Rome ‘La Sapienza’in 1999 his work has been focused on developing models and methods for Magnetic Resonance Imaging, in particular image registration, classification and segmentation in a Bayesian framework. After being appointed a 2-year contract as a Lecturer at the University of Plymouth from 2003 to 2004 he is now a post-Doc researcher at the ITAB, Institute for Advanced Biomedical Technologies, University of Chieti, Italy and he works on the analysis of fMRI and MEG data. Julian Stander was born in Plymouth, UK in 1964. He received a BA in Mathematics with first class honours from University of Oxford in 1987, a Diploma in Mathematical Statistics with distinction from University of Cambridge in 1988, and a PhD from University of Bath in 1992. He has been a lecturer at the School of Mathematics and Statistics, University of Plymouth, since 1993, and was promoted to Reader in 2006. His fields of interest are: applications of statistics including image analysis, spatial modelling and disclosure limitation. He has published over 20 refereed journal articles. 相似文献