Homogeneous cooling of hard ellipsoids

We study the homogeneous cooling of hard, smooth ellipsoids in three dimensions using event driven numerical simulation. The elongation of the particle has a strong effect on the cooling behavior. Weakly elongated ellipsoids display two distinct cooling regimes. For small times, the translational and rotational energy decay at a different rates. Once their ratio reaches a time-independent value (different from equipartition), the overall temperature of the system decays like t ^?2, as predicted by Haff??s law. For more elongated ellipsoids the translational and rotational temperatures rapidly reach a constant ratio near unity. The cooling behavior in the homogeneous state can be predicted from Haff??s law and the equilibrium collision rate.     

Nanoemulsion-based delivery systems for poorly water-soluble bioactive compounds: Influence of formulation parameters on Polymethoxyflavone crystallization

Polymethoxyflavones (PMFs) extracted from citrus peel exhibit potent anti-cancer activity, but are highly hydrophobic molecules with poor solubility in both water and oil at ambient and body temperature, which limits their bioavailability. The possibility of encapsulating PMFs within nanoemulsion-based delivery systems to facilitate their application in nutraceutical and pharmaceutical products was investigated. The influence of oil type (corn oil, MCT, orange oil), emulsifier type (β-lactoglobulin, lyso-lecithin, Tween, and DTAB), and neutral cosolvents (glycerol and ethanol) on the formation and stability of PMF-loaded nanoemulsions was examined. Nanoemulsions (r < 100 nm) could be formed using high pressure homogenization for all emulsifier types, except DTAB. Lipid droplet charge could be altered from highly cationic (DTAB), to near neutral (Tween), to highly anionic (β-lactoglobulin, lyso-lecithin) by varying emulsifier type. PMF crystals formed in all nanoemulsions after preparation, which had a tendency to sediment during storage. The size, morphology, and aggregation of PMF crystals depended on preparation method, emulsifier type, oil type, and cosolvent addition. These results have important implications for the development of delivery systems for bioactive components that have poor oil and water solubility at application temperatures.     

Creation of reduced fat foods: Influence of calcium-induced droplet aggregation on microstructure and rheology of mixed food dispersions

The impact of calcium-induced fat droplet aggregation on the microstructure and physicochemical properties of model mixed colloidal dispersions was investigated. These systems consisted of 2 wt% whey protein-coated fat droplets and 4 wt% modified starch granules heated to induce starch swelling (pH 7). Optical and confocal microscopy showed that the fat droplets were dispersed within the interstitial region between the swollen starch granules. The structural organisation of the fat droplets within these interstitial regions could be modulated by controlling the calcium concentration: (i) at a low calcium concentration the droplets were evenly distributed; (ii) at an intermediate calcium concentration they formed a layer around the starch granules; (iii) at a high calcium concentration they formed a network of aggregated droplets. Paste-like materials were produced when the fat droplets formed a three-dimensional network in the interstitial region. The properties of fat droplet–starch granule suspensions can be modulated by altering the electrostatic interactions to alter microstructure.     

Surfactant Concentration,Antioxidants, and Chelators Influencing Oxidative Stability of Water‐in‐Walnut Oil Emulsions

Effects of surfactant concentration, antioxidants with different polarities, and chelator type on the oxidative stability of water‐in‐stripped walnut oil (W/O) emulsions stabilized by polyglycerol polyricinoleate (PGPR) were evaluated. The formation of primary oxidation products (lipid hydroperoxides) and secondary oxidation products (hexanal) decreased with increasing PGPR concentrations (0.3–1.0 wt% of emulsions). Excess surfactant might solubilize lipid hydroperoxides out of the oil–water interface, resulting in the decreased lipid oxidation rates in W/O emulsions. At concentrations of 10–1000 μM, the polar Trolox demonstrated concentration‐dependent antioxidant activity according to both hydroperoxide and hexanal formation. The antioxidant efficiency of the non‐polar α‐tocopherol was slightly reduced at the higher range of 500–1000 μM based on hydroperoxide formation. Both ethylenediaminetetraacetic acid (EDTA) and deferoxamine (DFO) at concentrations of 5–100 μM reduced the rates of lipid oxidation at varying degrees, indicating that endogenous transition metals may promote lipid oxidation in W/O emulsions. EDTA was a stronger inhibitor of lipid oxidation than DFO. These results suggest that the oxidative stability of W/O emulsions could be improved by the appropriate choice of surfactant concentration, antioxidants, and chelators.     

Charting the Potential of Landscape Urbanism in Dubai

Landscape Urbanism has been, to date, a theory emerging primarily from the Western world. This paper counters the Western focus by exploring the potential of Landscape Urbanism theory in Dubai. In a previous article published by the author, landscape architecture in Dubai has been identified as diverging from the tenets of the various charters of the International Federation of Landscape Architects (IFLA), having apparently scant regard for pressing ecological, social and cultural design issues. Landscape Urbanism in this paper is discussed with respect to its ability to bolster the practice of landscape architecture in Dubai in relation to these issues. The paper argues that a number of key facets of Landscape Urbanism appear difficult to reconcile with the ecological, social and cultural conditions of Dubai. Further to this, it tends to lack the tools by which landscape urbanists in Dubai could link theory with practice.     

有机硅BS94对以脱硫石膏为原料生产的耐水纸面石膏板性能的影响

探讨了不同掺量的有机硅BS94对脱硫石膏吸水率、抗折强度、抗压强度、初凝时间、终凝时间的影响规律,分析了脱硫石膏中杂质对有机硅BS94防水性能的影响。结果表明,有机硅BS94对以脱硫石膏为原料生产的耐水纸面石膏板具有较好的防水性能,可以广泛应用于以脱硫石膏生产耐水纸面石膏板的工艺中,但当脱硫石膏中的F离子含量较高时,防水剂的防水性能会有所下降,因此,应严格控制原料中可溶性F的含量。     

The effect of sodium polymethacrylate on the rheology of the positive paste and performance of the lead-acid battery

Due to its rheological properties, positive lead-acid battery paste can be difficult to spread on lead current collectors accurately and efficiently under industry machinery and setting. Sodium polymethacrylate dispersant was studied as an effective positive paste additive that could lower the yield stress of the paste without affecting paste density and battery performance. Under a four-blade vane rheometer setup, stress growth and oscillatory amplitude strain sweep experiments evaluated the rheological properties of positive paste with the addition of varying amounts of sodium polymethacrylate. Further, the electrochemical effects of sodium polymethacrylate were also evaluated in 2V batteries by testing positive active material utilization and cycle life.