Synthesis and characterization of CdS nanocrystals embedded on solid electrolyte films

In this article nano‐sized CdS crystal embedded in a PEO matrix was successfully prepared by a complex transformation method that is universal for preparing nanosized compounds containing transition metals. The size of embedded CdS particles was in the nanoscale from 2 to 10 nm determined by X‐ray diffusion. The nanosized CdS displayed the expected blue shift of the onset absorbance in the UV spectrum. The amount of blue shift depends upon the dipping time of the PEO–cadmium complex film in a sodium sulfide solution as well as its concentration. The most effective means for adjusting the size of CdS nanocrystals is to change the ratio of the oxygen along with the PEO chain to the cadmium ion in the complex film. The alkali salt in the film would contribute to the conductivity of the composite film. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 1263–1268, 2002; DOI 10.1002/app.10459     

Kinetics of Thermal Dehydroxylation and Carbonation of Magnesium Hydroxide

The kinetics of simultaneous dehydroxylation and carbonation of precipitated Mg(OH)₂ were studied using isothermal and nonisothermal thermogravimetric analyses. Specimens were analyzed using X-ray diffraction, transmission electron microscopy, and through measurements of the volume of carbon dioxide evolved in a subsequent reaction with hydrochloric acid. From 275° to 475°C, the kinetics of isothermal dehydroxylation in helium were best fit to a contracting-sphere model, yielding an activation energy of 146 kJ/mol, which was greater than values reported in the literature for isothermal dehydroxylation under vacuum (53–126 kJ/mol). The carbonation kinetics were complicated by the fact that dehydroxylation occurred simultaneously. The overall kinetics also could be fit to a contracting-sphere model, yielding a net activation energy of 304 kJ/mol. The most rapid carbonation kinetics occurred near 375°C. At this temperature, Mg(OH)₂ underwent rapid dehydroxylation and subsequent phase transformation, whereas thermodynamics favored the formation of carbonate. During carbonation, MgCO₃ precipitated on the surface of disrupted Mg(OH)₂ crystals acting as a kinetic barrier to both the outward diffusion of H₂O and the inward diffusion of CO₂.     

基于阿里云的电动汽车充电站数据网关

随着电动汽车技术的发展,电动汽车决策研究中的数据来源成为一大难题,针对充电决策研究难以直接获取电动汽车充电站日 负荷曲线问题,设计并实现了一种用于电动汽车充电站的数据网关.设备以STM32F407主控系统以及EMW3080通信模块为核心,通过RS485总线接入电动汽车充电站现场总线监听总线的Modbus RTU数据包获取现场数据,并通过MQTT协议将充电桩运行数据上传到云平台,用户能够通过Web端数据显示界面查看各充电站相关运行数据,为电动汽车充电预约配对算法提供了一个可靠数据获取途径.     

Compression based clustering technique for enhancing accuracy in web scale videos

Multimedia Tools and Applications - Detection and clustering of commercial advertisements plays an important role in multimedia indexing also in the creation of personalized user content. In...     

基于功效特征的专利聚类方法

当前专利是按照领域划分的,而基于功效特征可以实现跨领域的专利聚类,这在企业创新设计中具有重要意义,而精确提取专利功效特征和快速获得最优聚类结果是其中的关键任务。为此提出一种信息实体语义增强表示（ERNIE）和卷积神经网络（CNN）相结合的功效特征联合提取（FEI-Joint）模型来提取专利文献的功效特征,并且改进自组织神经网络（SOM）算法,从而提出具有早期拒绝策略与类合并思想的自组织神经网络（ERCM-SOM）来实现基于功效特征的专利聚类。对FEI-Joint模型与TF-IDF、狄利克雷分布（LDA）、CNN在特征提取后的聚类效果上进行比较和分析,结果表明其F-measure值比其他模型有明显提高。ERCM-SOM算法与K-Means算法、SOM算法相比,在F-measure值提高的同时,其时间较SOM算法有明显缩短。对比使用专利分类号（IPC）的专利分类,采用基于功效特征的聚类方法可实现跨领域的专利聚类效果,为设计者借鉴其他领域的设计方法奠定了基础。     

基于OGC标准的水利一张图关键技术解析

为解决水利空间数据共享困难的问题,江苏省基于开放地理信息标准,采用去中心化技术路线,构建水利一张图。利用OGC(开放地理空间信息联盟)提供空间数据交换和服务互操作协议,具体接口可以在业务领域定制化实现,提出以OWS(OGC网络服务)融合异构空间数据,实现地图局部更新和统一风格展示;通过URI定位属性并与Solr搜索引擎结合,扩展WFS实现基于语义的空间信息查询;基于服务链和工作流整合水利空间功能;结合LDAP协议实现CSW服务,构建跨部门、级别、业务的细粒度空间信息目录;通过服务负载均衡,实现云端GIS等方案。从技术上实现水利一张图平台框架,可满足水利空间信息公共服务的功能、性能需求,并为基于水利一张图整合全省水利信息资源,提供理论参考和技术借鉴。     

翼缘纵向变厚度工型截面梁变形性能试验

为研究翼缘纵向变厚度工型截面简支梁的变形性能,对2根翼缘纵向变厚度工型截面梁与2根等厚度梁进行静力加载对比试验,同时采用有限元软件ANSYS进行数值模拟.变厚度梁翼缘材料为Q345GJC等级纵向变厚度钢板,加载方式包括单点加载和两点加载.试验结果表明:试件均发生明显的板件局部屈曲;采用翼缘纵向变厚度工型截面简支梁,不仅可以在保证承载力的情况下大大减少用钢量,而且可以获得更大的强度储备;也可以达到密实截面的变形要求,满足塑性设计要求.有限元结果与试验结果吻合良好.该试验结果可为翼缘纵向变厚度工型截面钢梁的塑性变形设计提供依据.     

DPT-75井试压过程套管挤毁事故分析

剖析典型案例井DPT-75井套管挤毁事故的全过程,指出最易诱发事故的诸多因素,提出合理化的建议。在此基础上,制定了科学的气田试压流程规范,实现了试压的节点控制,现场再未发生此类事故。     

加工中心部件故障相关度评估

为实现加工中心系统部件间故障相关度评估,采用相关故障机理分析与图论相结合建立系统部件故障传递有向图的方法,将系统部件相关度评估转化为复杂网络节点重要度计算,进而由邻接矩阵及其转置变换并结合pagerank算法,实现加工中心系统部件故障相关度求解.计算结果表明:故障相关度的大小与部件间故障关联关系成正比,存在故障相关的部件的故障相关度大于不存在故障相关的部件的故障相关度.若部件被影响度大,影响度小,说明该部件是故障表象部件;反之,影响度大而被影响度小的是故障源部件.提出的方法有助于故障诊断与维护.     

微小型涡喷发动机向心涡轮的流动仿真

为了详细研究微型向心涡轮的内部流动特性,对一台自研微型涡轮发动机的涡轮进行了气动设计和全三维粘性数值模拟仿真,验证了叶片型线设计方案的可行性,得到模拟计算结果（落压比为1.91,总压绝热效率0.73,出口气流马赫数为1.2,流量13.8g/s）。研究了微型涡轮设计工况下内部的气流状态,对微尺寸下涡轮内部的流动特性及各种流动损失产生的特点及原因进行分析总结。结果表明：导向叶流道内的流动损失主要为由气体粘性引起的叶型损失;动叶流道中流动损失主要为气体在动叶前缘产生冲击形成的滞止损失与边界层损失,动叶出口叶片尾缘处形成的尾迹涡流损失。