注入信号频率对注入式定子接地保护的影响

为研究注入信号频率对发电机注入式接地保护测量灵敏度、测量误差方面和保护注入功率的影响,得到注入式定子接地保护外加注入源频率的最佳选择范围,提升注入式定子接地保护的测量精度.通过MATLAB/SIMULINK模块仿真计算分析说明了采用电流判据的局限性,并得出注入信号的最佳选择范围.结果表明:注入信号的最佳选择范围低频区间为10～30Hz,高频区间为70～80Hz.     

溴酸钾非等温热分解过程及热分解动力学研究

为了解溴酸钾(KBrO3)的热性能,利用差热分析(DTA)研究了KBrO3的非等温热分解过程.采用Kissinger法和Ozawa法计算了KBrO3的热力学参数,并与硝酸铵(NH4NO3)的热稳定性进行了对比.结果发现:KBrO3在400℃附近开始熔化,随后发生放热分解,其热分解是分两个阶段进行的,在升温速率为5℃?min-1时,第一阶段的放热峰温为432.28℃,第二阶段的放热峰温为439.86℃;第一阶段热分解活化能E、焓变???、熵变???及吉布斯自由能???分别为175.17 kJ?mol-1、169.15 kJ?mol-1、-25.32 kJ?K-1?mol-1和187.51 kJ?mol-1;对比KBrO3两阶段热分解的熵变???,发现第二阶段热分解比第一阶段热分解更易发生;KBrO3的热稳定性优于硝酸铵(NH4NO3).     

Screening of Inhibitors Targeting Heat Shock Protein 47 Involved in the Development of Idiopathic Pulmonary Fibrosis

Heat shock protein 47 (HSP47), a collagen-specific molecular chaperone, is causally related to fibrotic diseases, including idiopathic pulmonary fibrosis. The identification of Compounds that interfere with the HSP47-collagen interaction is essential for the development of relevant therapeutics. Herein, we prepared human HSP47 as a soluble fusion protein expressed in E. coli and established an assay system for HSP47 inhibitor screening. We screened a natural and synthetic Compound library established at Nagasaki University. Among 1023 Compounds, 13 exhibited inhibitory activity against human HSP47, of which three inhibited its function in a dose-dependent manner. Epigallocatechin-3-O-gallate, one of these three Compounds, is a typical polyphenol Compound derived from tea leaves. Structurally related Compounds were synthesized and examined for their activity, revealing a hydroxyl group at A-ring position 5 as important for its activity. The present findings provide valuable insight for the development of natural product-derived therapeutics for fibrotic diseases, including idiopathic pulmonary fibrosis.     

一款运动型轿车轮胎的开发与调校

以国内市场运动型新车型开发需求为例,结合运动型车型定位,确定性能开发优先级,选定标准胎;根据性能的目标要求,从轮胎外轮廓,花纹,施工三方面对该款产品进行针对性设计与开发,开发前期对产品进行了两次有限元分析;后期进行了两次轮胎开发与调校,对样胎进行制动性、操控性,NVH,舒适性的实车评价;第一次调校后的产品性能劣势进行分析,对产品方案进行调整与优化。第二次调校后在达成轮胎与车辆匹配目标性能后,对轮胎设计参数进行固化,开始着手批量生产事宜。     

CO2体积分数对燃煤细颗粒物在水汽环境中凝结长大的影响

为研究燃煤烟气中CO₂体积分数对细颗粒物在水汽环境中凝结长大效果的影响,建立了计算模型并搭建了实验平台,分别从理论计算和实验研究两方面探讨了CO₂体积分数对细颗粒物凝结长大效果的影响。结果表明:随着CO₂体积分数升高,混合烟气的热、质扩散系数均降低,生长管内平均过饱和度增加,细颗粒物长大效果明显;管壁温度越高,随着CO₂体积分数的提高,细颗粒物粒径越大。     

间冷循环水系统水质调控措施探讨

近年来,间接空冷系统在我国北方地区的新建燃煤发电厂中得到广泛应用.分析间冷循环水系统水质恶化的原因,列举针对性的水质调控措施,提出先解决间冷循环水系统的腐蚀问题,再进行循环水水质调节处理,并通过综合比选确定合适的水处理系统方案,最后给出相关的解决建议.     

环氧乙烷银催化剂研究现状及技术进展

介绍了环氧乙烷银催化剂技术研究现状,从催化剂载体、制备工艺等方面概述了我国环氧乙烷银催化剂技术研究进展,指出其今后的发展建议.     

考虑应力历史的饱和黏土一维固结渗透试验研究

为研究固结应力比和应力历史对饱和黏土一维固结渗透的影响,利用GDS三轴仪进行了一系列一维固结-渗透联合试验。研究结果表明,在不同固结应力比相同应力历史条件下,正常固结和超固结饱和黏土在一维固结渗透过程中试样的渗透系数和孔隙比均随固结应力比的增大而减小,试样的最终压缩量均随固结应力比的增大而增大。在相同固结应力比不同应力历史条件下,超固结饱和黏土的最终压缩量小于正常固结饱和黏土。将固结应力σ与土层自重应力σcz的差值σdv与试样最终压缩量sf进行拟合,得出应力差值σdv与各固结应力下的最终压缩量sf间呈良好的线性关系。通过研究发现,同时考虑固结应力比和应力历史对饱和黏土一维固结渗透的影响是有必要的,同时在得到土体自重应力后可较为准确地预测土体最终压缩量。     

Functionalized metal–organic frameworks with strong acidity and hydrophobicity as an efficient catalyst for the production of 5-hydroxymethylfurfural

In the dehydration of fructose to 5-hydroxymethyl furfural(HMF), in situ produced water weakens the acid strength of the catalyst and causes the rehydration of HMF, causing unsatisfactory catalytic activity and selectivity. In this work, a class of benzenesulfonic acid-grafted metal–organic frameworks with strong acidity and hydrophobicity is obtained by the direct sulfonation method using 4-chlorobenzenesulfonic acid as sulfonating agent. The resultant MOFs have a specific surface area of greater than 250 m~2·g~(-1), acid density above 1.0 mmol·g~(-1), and water contact angle up to 129°. The hydrophobic MOF-Ph SO_3 H exhibits both higher catalytic activity and selectivity than MOF-SO_3 H in the HMF synthesis due to its better hydrophobicity and olephilicity. Moreover, the catalyst has a high recycled stability. At last, fructose is completely converted, and 98.0% yield of HMF is obtained under 120 °C in a DMSO solvent system. The successful preparation of the hydrophobic acidic MOF provides a novel hydrophobic catalyst for the synthesis of HMF.     

Reactivity study and kinetic evaluation of CuO-based oxygen carriers modified by three different ores in chemical looping with oxygen uncoupling (CLOU) process

In the chemical looping with oxygen uncoupling (CLOU) process,CuO is a promising material due to the high oxygen carrier capacity and exothermic reaction in fuel reactor but limited by the low melting point.The combustion rate of carbon is faster than the decoupling rate of oxygen carrier (OC).Hence,high tem-perature tolerance and rapid oxygen release rate of CuO modified by three different ores were investi-gated in this study.The kinetics analysis of oxygen decoupling with Cu-based oxygen carriers was also evaluated.Results showed that CuO modified by chrysolite had faster oxygen release rate than that of CuO.Limestone showed obvious positive effect on the oxidization process.The selected OCs could keep stable in at least 20 cycles,for about 1200 min.Shrinking core model (SCM) fitted well for the decoupling process in the temperature range of 1123-1223 K.Reduction rate kinetic information may aid in the development of chemical looping with oxygen uncoupling (CLOU) technologies during reactor design and process modeling.Ternary doped copper oxide with chrysolite and limestone could improve the reactivity of CuO in decoupling and coupling process and also improve the high temperature tolerance.