Correlations between optical properties, microstructure, and processing conditions of Aluminum nitride thin films fabricated by pulsed laser deposition

Aluminum nitride (AlN) films were deposited using pulsed laser deposition (PLD) onto sapphire (0001) substrates with varying processing conditions (temperature, pressure, and laser fluence). We have studied the dependence of optical properties, structural properties and their correlations for these AlN films. The optical transmission spectra of the produced films were measured, and a numerical procedure was applied to accurately determine the optical constants for films of non-uniform thickness. The microstructure and texture of the films were studied using various X-ray diffraction techniques. The real part of the refractive index was found to not vary significantly with processing parameters, but absorption was found to be strongly dependent on the deposition temperature and the nitrogen pressure in the deposition chamber. We report that low optical absorption, textured polycrystalline AlN films can be produced by PLD on sapphire substrates at both low and high laser fluence using a background nitrogen pressure of 6.0 × 10^− 2 Pa (4.5 × 10^− 4 Torr) of 99.9% purity.     

TD‐CFIE Formulation for Transient Electromagnetic Scattering from 3‐D Dielectric Objects

In this paper, we present a time domain combined field integral equation formulation (TD‐CFIE) to analyze the transient electromagnetic response from dielectric objects. The solution method is based on the method of moments which involves separate spatial and temporal testing procedures. A set of the RWG functions is used for spatial expansion of the equivalent electric and magnetic current densities, and a combination of RWG and its orthogonal component is used for spatial testing. The time domain unknowns are approximated by a set of orthonormal basis functions derived from the Laguerre polynomials. These basis functions are also used for temporal testing. Use of this temporal expansion function characterizing the time variable makes it possible to handle the time derivative terms in the integral equation and decouples the space‐time continuum in an analytic fashion. Numerical results computed by the proposed formulation are compared with the solutions of the frequency domain combined field integral equation.     

Development of stress-modified fracture strain for ductile failure of API X65 steel

The present paper proposes ductile failure criteria in terms of true fracture strain (the equivalent strain to fracture) as a function of the stress triaxiality (defined by the ratio of the hydrostatic stress to the equivalent stress) for the API X65 steel. To determine the stress-modified fracture strain, smooth and notched tensile bars with four different notch radii are tested, from which true fracture strains are determined as a function of the notch radius. Then detailed elastic–plastic, large strain finite element analyses are performed to estimate variations of stress triaxiality in the tensile bars, which leads to true fracture strains as a function of the stress triaxiality, by combining them with experimental results. Two different failure criteria are proposed, one based on local stress and strain information at the site where failure initiation is likely to take place, and the other based on averaged stress and strain information over the ligament where ductile fracture is expected. As a case study, ligament failures of API X65 pipes with a gouge are predicted and compared with experimental data.     

Stabilizing receding horizon H ∞ control for linear discrete time-varying systems

In this paper, we simply derive matrix inequality conditions on the terminal weighting matrices for linear discrete time-varying systems that guarantee non-increasing and non-decreasing monotonicities of the saddle-point value of a dynamic game. We show that the derived terminal inequality conditions ensure the closed-loop stability of the receding horizon H X control (RHHC). The stabilizing RHHC guarantees the H X norm bound of the closed-loop system. The derived terminal inequality conditions include most well-known existing terminal conditions for the closed-loop stability as special cases. The condition on the state weighting matrix is weakened so as to include even the zero matrix. The results for time-invariant systems are obtained correspondingly from those in the time-varying case.     

Development of a Shape‐Memory Tube to Prevent Vascular Stenosis

Inserting a graft into vessels with different diameters frequently causes severe damage to the host vessels. Poor flow patency is an unresolved issue in grafts, particularly those with diameters less than 6 mm, because of vessel occlusion caused by disturbed blood flow following fast clotting. Herein, successful patency in the deployment of an ≈2 mm diameter graft into a porcine vessel is reported. A new library of property‐tunable shape‐memory polymers that prevent vessel damage by expanding the graft diameter circumferentially upon implantation is presented. The polymers undergo seven consecutive cycles of strain energy‐preserved shape programming. Moreover, the new graft tube, which features a diffuser shape, minimizes disturbed flow formation and prevents thrombosis because its surface is coated with nitric‐oxide‐releasing peptides. Improved patency in a porcine vessel for 18 d is demonstrated while occlusive vascular remodeling occurs. These insights will help advance vascular graft design.     

Significantly Enhanced Photoluminescence of Doped Polymer‐Metal Hybrid Nanotubes

We report on the significantly enhanced photoluminescence (PL) of hybrid double‐layered nanotubes (HDLNTs) consisting of poly(3‐methylthiophene) (P3MT) nanotubes with various doping levels enveloped by an inorganic, nickel (Ni) metal nanotube. From laser confocal microscopy PL experiments on a single strand of the doped‐P3MT nanotubes and of their HDLNTs, the PL peak intensity of the HDLNT systems increased remarkably up to ～350 times as the doping level of the P3MT nanotubes of the HDLNTs increased, which was confirmed by measurements of the quantum yield. In a comparison of the normalized ultraviolet and visible absorption spectra of the doped‐P3MT nanotubes and their HDLNTs, new absorption peaks corresponding to surface‐plasmon (SP) energy were created at 563 and 615 nm after the nanoscale Ni metal coating onto the P3MT nanotubes, and their intensity increased on increasing the doping level of the P3MT nanotube. The doping‐induced bipolaron peaks of the HDLNTs of doped‐P3MT/Ni were relatively reduced, compared with those of the doped‐P3MT nanotubes before the Ni coating, due to the charge‐transfer effect in the SP‐resonance (SPR) coupling. Both energy‐transfer and charge‐transfer effects due to SP resonance contributed to the very‐large enhancement of the PL efficiency of the doped‐P3MT‐based HDLNTs.     

Detection of Methomyl,a Carbamate Insecticide,in Food Matrices Using Terahertz Time-Domain Spectroscopy

The aim of this study was to investigate the feasibility of detecting methomyl, a carbamate insecticide, in food matrices (wheat and rice flours) using terahertz time-domain spectroscopy (THz-TDS). In the frequency range 0.1–3 THz, the characteristic THz absorption peaks of methomyl at room temperature were detected at 1 (33.4 cm^?1), 1.64 (54.7 cm^?1), and 1.89 (63.0 cm^?1)?THz. For detailed spectral analysis, the vibrational frequency and intensity of methomyl were calculated using solid-state density functional theory to mimic molecular interactions in the solid state. Qualitatively, the simulated spectrum was in good agreement with the experimental spectrum. Analysis of the individual absorption modes revealed that all of the features in the THz spectrum of methomyl were mainly generated from intermolecular vibrations. The peak appearing at 1 THz (33.4 cm^?1) was then selected and tested for its suitability as a fingerprint for detecting methomyl in food matrices. Its absorbance was dose-dependently distinguishable from that of wheat and rice flours. The calibration curve of methomyl had a regression coefficient of >0.974 and a detection limit of <3.74 %. Accuracy and precision expressed as recovery and relative standard deviation in interday repeatability were in the ranges 78.0–96.5 and 2.83–4.98 %, respectively. Our results suggest that THz-TDS can be used for the rapid detection of methomyl in foods, but its sensitivity needs to be improved.     

Flooding limited CHF in a vertical 3 × 3 rod bundle with non-uniform axial heat flux

KAERI has performed an experimental study on the critical heat flux (CHF) under zero flow conditions with a non-uniformly heated 3 × 3 rod bundle. Experimental conditions are in the range of a system pressure from 0.50 to 14.96 MPa and inlet water subcooling enthalpies from 68 to 352 kJ/kg. The test section used in the present experiments consisted of a vertical flow channel, upper and lower plenums, and a non-uniformly heated 3 × 3 rod bundle. The experimental results show that the CHFs in low-pressure conditions are somewhat scattered within a narrow range. As the system pressure increases, however, the CHFs show a good parametric trend. The CHFs occur in the upper region of the heated section, but the locations of the detected CHFs move gradually in a downward direction with the increase of the system pressure. Even though the effects of the inlet water subcooling enthalpies and system pressure of the flooding CHF are relatively smaller than those of the flow boiling CHF, the CHF increases by increasing the inlet water subcooling enthalpies. Several existing correlations for the countercurrent flooding CHF based on Wallis's flooding correlation and Kutateladze's criterion for the onset of flooding are compared with the CHF data obtained in the present experiments to examine the applicability of the correlations.     

Selecting linear algebra kernel composition using response time prediction

Numerical linear algebra libraries provide many kernels that can be composed to perform complex computations. For a given computation, there is typically a large number of functionally equivalent kernel compositions. Some of these compositions achieve better response times than others for particular data and when executed on a particular computer architecture. Previous research provides methods to enumerate (a subset of) these kernel compositions. In this work, we study the problem of determining the composition that yields the lowest response time. Our approach is based on a response time prediction for each candidate combination. While this prediction could in principle be obtained using analytical and/or empirical performance models, developing accurate such models is known to be challenging. Instead, we define a feature space that captures salient properties of kernel combinations and predict response time using supervised machine learning. We experiment with a standard set of machine learning algorithms and identify an effective algorithm for our kernel composition selection problem. Using this algorithm, our approach widely outperforms the strategy that would consist in always using the simplest kernel composition and is often close to the fastest kernel compositions among those evaluated. We quantify the potential benefit of our approach if it were to be implemented as part of an interactive computational tool. We find that although the potential benefit is substantial, a limiting factor is the kernel composition enumeration overhead. Copyright © 2014 John Wiley & Sons, Ltd.     

Microstructure,Tensile and Fatigue Properties of Al–5 wt.%Mg Alloy Manufactured by Twin Roll Strip Casting

This study investigated the microstructure, tensile and fatigue properties of Al–5 wt.%Mg alloy manufactured by twin roll strip casting. Strips cast as a fabricated (F) specimen and a specimen heat treated (O) at 400 °C/5 h were produced and compared. In the F specimen, microstructural observation discovered clustered precipitates in the center area, while in the O specimen precipitates were relatively more evenly distributed. Al, Al₆(Mn, Fe), Mg₂Al₃ and Mg₂Si phases were observed. However, most of the Mg₂Al₃ phase in the heat-treated O specimen was dissolved. A room temperature tensile test measured yield strength of 177.7 MPa, ultimate tensile strength of 286.1 MPa and elongation of 11.1% in the F specimen and 167.7 MPa (YS), 301.5 MPa (UTS) and 24.6% (EL) in the O specimen. A high cycle fatigue test measured a fatigue limit of 145 MPa in the F specimen and 165 MPa in the O specimen, and the O specimen achieved greater fatigue properties in all fatigue stress conditions. The tensile and fatigue fracture surfaces of the above-mentioned specimens were observed, and this study attempted to investigate the tensile and fatigue deformation behavior of strip cast Al–5 wt.%Mg based on the findings.