Hierarchical nanostructure generated by decorating SiO(x) nanowires with CoPt nanoparticles

Silicon oxide nanowires were decorated with magnetically hard 3-5?nm-sized CoPt nanoparticles using a simple physical deposition system without any pretreatment of the nanowire surface. High curvature of the nanowire surface together with the weak metal-substrate interaction helped to maintain discrete particle morphology with spherical shapes during deposition. The weak interaction also allowed the preferential nucleation of the deposited film on the pre-existing particles so that the film deposition can be repeated in order to increase the particle size without significantly altering the particle morphology. We expect that this method can be easily extended to create other metal nanoparticle-decorated nanowires.     

Strain control and spontaneous phase ordering in vertical nanocomposite heteroepitaxial thin films

Two-phase, vertical nanocomposite heteroepitaxial films hold great promise for (multi)functional device applications. In order to achieve practical devices, a number of hurdles need to be overcome, including the creation of ordered structures (and their formation on a large scale), achieving different combinations of materials and control of strain coupling between the phases. Here we demonstrate major advances on all these fronts: remarkable spontaneously ordered structures were produced in newly predicted compositions, vertical strain was proven to dominate the strain state in films above 20 nm thickness and strain manipulation was demonstrated by selection of phases with the appropriate elastic moduli. The work opens up a new avenue for strain control in relatively thick films and also promises new forms of ordered nanostructures for multifunctional applications.     

Analyzing longitudinal data with multilevel models: An example with individuals living with lower extremity intra-articular fractures.

Objective: The use and quality of longitudinal research designs has increased over the past 2 decades, and new approaches for analyzing longitudinal data, including multilevel modeling (MLM) and latent growth modeling (LGM), have been developed. The purpose of this article is to demonstrate the use of MLM and its advantages in analyzing longitudinal data. Research Method: Data from a sample of individuals with intra-articular fractures of the lower extremity from the University of Alabama at Birmingham's Injury Control Research Center are analyzed using both SAS PROC MIXED and SPSS MIXED. Results: The authors begin their presentation with a discussion of data preparation for MLM analyses. The authors then provide example analyses of different growth models, including a simple linear growth model and a model with a time-invariant covariate, with interpretation for all the parameters in the models. Implications: More complicated growth models with different between- and within-individual covariance structures and nonlinear models are discussed. Finally, information related to MLM analysis, such as online resources, is provided at the end of the article. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Understanding Origin of Voltage Hysteresis in Conversion Reaction for Na Rechargeable Batteries: The Case of Cobalt Oxides

Conversion reaction electrodes offer a high specific capacity in rechargeable batteries by utilizing wider valence states of transition metals than conventional intercalation‐based electrodes and have thus been intensively studied in recent years as potential electrode materials for high‐energy‐density rechargeable batteries. However, several issues related to conversion reactions remain poorly understood, including the polarization or hysteresis during charge/discharge processes. Herein, Co₃O₄ in Na cells is taken as an example to understand the aforementioned properties. The large hysteresis in charge/discharge profiles is revealed to be due to different electrochemical reaction paths associated with respective charge and discharge processes, which is attributed to the mobility gap among inter‐diffusing species in a metal oxide compound during de/sodiation. Furthermore, a Co₃O₄–graphene nanoplatelet hybrid material is demonstrated to be a promising anode for Na rechargeable batteries, delivering a capacity of 756 mAh g^?1 with a good reversibility and an energy density of 96 Wh kg^?1 (based on the total electrode weight) when combined with a recently reported Na₄Fe₃(PO₄)₂(P₂O₇) cathode.     

Remote‐Controllable Molecular Knob in the Mesomorphic Helical Superstructures

A programed light‐responsive chiral liquid crystal (LC) containing four photochromic azobenzene moieties covalently connected to a central bicyclic chiral core (abbreviated as AZ₄ICD) is newly designed, precisely synthesized, and efficiently applied as a remote‐controllable molecular knob for the optically tunable thin film. First of all, phase evolutions and ordered structures of AZ₄ICD are systematically investigated by a combination of thermal, microscopic, scattering, and simulation techniques. Wide‐angle X‐ray diffractions of oriented AZ₄ICD samples indicate that the AZ₄ICD molecule itself basically forms layer structures: one is a low‐ordered chiral smectic A LC phase (SmA*) with 5.61 nm layer periodicity at high temperatures, and two highly ordered smectic crystal (SmCr₁ and SmCr₂) phases are subsequently formed at lower temperatures with the anticlinically tilted molecular packing structures. The helical superstructures of chiral nematic LC phase (N*) can be spontaneously constructed by doping AZ₄ICD chiral agents into the achiral nematic molecules. Due to the bent conformational geometry of AZ₄ICD, the thermal window of blue LC phase (BP) is expanded by stabilizing the double twisted cylindrical building blocks. Remote‐controllable phase transformations in the mesomorphic helical superstructures are demonstrated by tuning the wavelength of light.     

Utilization of the Antiferromagnetic IrMn Electrode in Spin Thermoelectric Devices and Their Beneficial Hybrid for Thermopiles

The thermoelectric effect in various magnetic systems, in which electric voltage is generated by a spin current, has attracted much interest owing to its potential applications in energy harvesting, but its power generation capability has to be improved further for actual applications. In this study, the first instance of the formation of a spin thermopile via a simplified and straightforward method which utilizes two distinct characteristics of antiferromagnetic IrMn is reported: the inverse spin Hall effect and the exchange bias. The former allows the IrMn efficiently to convert the thermally induced spin current into a measurable voltage, and the latter can be used to control the spin direction of adjacent ferromagnetic materials. It is observed that a thermoelectric signal is successfully amplified in spin thermopiles with exchange‐biased IrMn/CoFeB structures, where an alternating magnetic alignment is formed using the IrMn thickness dependence of the exchange bias. The scalable signal on a number of thermopiles allowing a large‐area application paves the way toward the development of practical spin thermoelectric devices. A detailed model analysis is also provided for a quantitative understanding of the thermoelectric voltages, which consist of the spin Seebeck and anomalous Nernst contributions.