The effects of Ni and Li doping on the performance of lithium manganese oxide material for lithium secondary batteries

Layered Li_0.7[M_1/6Mn_5/6]O₂ (M=Li, Ni) was synthesized using a sol-gel method. P2-Na_0.7[M_1/6Mn_5/6]O₂ precursor was first synthesized by a sol-gel method, and then O2-Li_0.7[M_1/6Mn_5/6]O₂ was prepared by an ion exchange of Li for Na in P2-Na_0.7[M_1/6Mn_5/6]O₂ precursor. From charge/discharge curves, it was seen that Li_0.7[Li_1/6Mn_5/6]O₂ has two plateaus similar to those observed from a spinel structure, but Li_0.7[Ni_1/6Mn_5/6]O₂ holds a single plateau as observed from a typical layered structure. It was considered that Li_0.7[Li_1/6Mn_5/6]O₂ undergoes a phase transformation from layered to spinel structure during the charge/discharge cycle, but Li_0.7[Ni_1/6Mn_5/6]O₂ maintains O2-layered structure after the cycles. Li_0.7[Ni_1/6Mn_5/6]O₂ was higher in discharge capacity and retention rate than Li_0.7[Li_1/6Mn_5/6]O₂.     

Advanced underfill for high thermal reliability

The key to the success of flip‐chip technology lies in the availability of sucessful underfill materials. However, the reliability of flip‐chip technology using current underfill materials is generally found to be lower than that of conventional wire‐bond connection packaging materials such as epoxy molding compound (EMC) because of the high coefficients of thermal expansion (CTE) and moisture absorption of cured underfill material. In this study desbimide (DBMI), which has a low melting point (about 80°C), was used in the underfill materials as a cohardener. As a result, DBMI‐added underfill can show excellent thermal reliability, which is due to the superior properties of the CTE, the elastic modulus, and water resistance. When the properties of a 2 wt % DBMI‐added underfill were compared with those of a typical underfill (epoxy/anhydride), the CTE value was reduced to less than one‐half at the solder reflow temperature (about 200°C), the elastic modulus was reduced to less than one‐half in the temperature region below the glass‐transition temperature, and the water resistance was improved twofold. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 2617–2624, 2002     

A study of roll‐printing technology for TFT‐LCD fabrication

Abstract— Recently, potential breakthrough technologies for low‐cost processing of TFT‐LCDs and new process developments for flexible‐display fabrication have been widely studied. A roll‐printing process using etch‐resist material as a replacement for photolithographic patterning was investigated. The characterization of the properties of patterns formed in roll printing, a method to fabricate cliché plates for fine patterns, and the design of a new formulation for resist printing ink is reported. The pattern position accuracy, which is one of the most important issues for the successful application of printing processes in display manufacturing was studied and how it can be improved by optimizing the blanket roll structure is explained. New design rules for the layout of the thin‐film‐transistor array was derived to improve the compatibility of roll printing. As a result, a prototype 15‐in.‐XGA TFT‐LCD panel was fabricated by using printing processes to replace all the photolithographic patterning steps conventionally used.     

Design of an auditory guidance system for the blind with signal transformation from stereo ultrasonic to binaural audio

We have designed an auditory guidance system for the blind using ultrasonic-to-audio signal transformation. We first investigated the system requirements, and designed a simple but useful portable guidance system for the blind. The system derives visual information using multiple ultrasonic sensors, and transforms it to binaural auditory information using a suitable technique. The user can recognize the position of obstacles and the surrounding environment. The system is composed of two parts. One is a glasses-type system, and the other is a cane-type system with guide wheels. The former functions as an environment sensor, and the latter functions as a clear-path indicator. Wide-beam-angle ultrasonic sensors are used to detect bojects over a broader range. The system is designed as a battery-supplied portable model. Our design is focused on low power consumption, small size, light weight, and easy manipulation.     

用响应面法进行压缩机环状管*的设计优化

从结构振动和结构噪声的角度来看,压缩机的环状管是电冰箱中最重要的部件。压缩机内部机体产生的振动能量通过环状管传到壳体和外界,因此压缩机环状管的设计非常重要。但是,由于环状管几何形状的复杂性和运动的非线性,分析和设计环状管十分困难,往往不得不用统计法和试验法进行系统设计。对于类似环状管这样的复杂系统,响应面法(RSM)是常用的建模技术。用有限元模型和简单的试验模型代替环状管的实际模型作为环状管优化的起点。建立RS模型以后,用Sensitivity-based优化法进行优化。采用动态最小二乘法(MLSM)减少逼近误差。     

Improved electrochemical performance of a cyclic ultracapacitor using slurry electrodes under various flow conditions

A cyclic ultracapacitor is a promising energy storage device that can be used for grid energy storage. The cyclic ultracapacitor combines the advantages of both ultracapacitors and flow batteries, enabling rapid charging and large‐scale energy use. To improve the electrochemical performance under the flow condition, it is necessary to find a more electrical active material and design a flow cell that minimizes the resistance. In this study, we investigate the effects of changing the ratio of the active material in a slurry electrode under various operating conditions. Slurry electrodes were prepared with different ratios of active material and conductive additive but with a fixed electrolyte amount. Voltage–time curves of both a single and a stack‐flow cell in the constant‐current mode were obtained to analyze the relationship between the active materials ratio and the cell performance. Having more adsorption sites according to the active material amount is more important than increasing the electric conductivity by the conductive additive amount with regard to cell performance capabilities in a low resistance condition such as a non‐flow mode. However, higher electrical conductivity on a slurry electrode is more beneficial to improve the electrochemical performance in the stack‐flow mode, which has harsh resistance levels. Copyright © 2017 John Wiley & Sons, Ltd.     

Minimum-energy cornering trajectory planning with self-rotation for three-wheeled omni-directional mobile robots

A minimum-energy cornering trajectory planning with self-rotation algorithm is investigated for three-wheeled omni-directional mobile robots (TOMRs). First, an generalized minimum-energy point-to-point trajectory planning algorithm is studied, which is obtained using Pontryagin’s minimum principle, a practical cost function as the energy drawn from the batteries to motors, and the accurate TOMR dynamic model including actuator dynamics and the Coriolis force. By analyzing the co-state equation, the minimum-energy rotational velocity trajectory is presented in analytic form. Also a novel algorithm for the minimum-energy translational velocity trajectory is investigated. Second, the minimum-energy cornering trajectory planning algorithm with self-rotation is developed. Simulation results show that the minimum-energy cornering trajectory can save energy up to 15.20%compared with the conventional control using trapezoidal velocity profiles, and up to 3.96 % compared with the loss-minimization control using the armature loss as the cost function. Also a resolved-acceleration controller is implemented to show an actual performance.

     

Optimization of molten carbonate fuel cell (MCFC) and homogeneous charge compression ignition (HCCI) engine hybrid system for distributed power generation

In a previous study, a new hybrid system of molten carbonate fuel cell (MCFC) and homogeneous charge compression ignition (HCCI) engine was developed, where the HCCI engine replaces the catalytic burner and produces additional power by using the left-over heating values from the fuel cell stack. In the present study, to reduce the additional cost and footprint of the engine system in a hybrid configuration, the possibility of engine downsizing is investigated by using two strategies, i.e. the use of a turbocharger and the use of high geometric compression ratio for the engine design, both of which are to increase the density of the intake charge and thus the volumetric efficiency of the engine. Combining these two strategies, we suggest a new engine design with ∼60% of displacement volume of the original engine. In addition, operating strategies are developed to run the new hybrid system under part load conditions. It is successfully demonstrated that the system can operate down to 65% of the power level of the design point, while the system efficiency remains almost unchanged near 63%.     

Investigation of organic n-type field-effect transistor performance on the polymeric gate dielectrics

We report a copper hexadecafluorophthalocyanine (F₁₆CuPc) based n-type organic field-effect transistor (OFET) with polymeric gate dielectrics with different physical/electrical properties. The gate dielectrics are four types of cross-linked poly(4-vinylphenol) and newly prepared poly(4-phenoxy methyl styrene) and those are characterized based on surface tension, leakage current and capacitance. The performance of F₁₆CuPc OFETs with those gate dielectrics was compared. We found that the composition of the gate dielectrics and the interfacial interaction of F₁₆CuPc with the gate dielectric play a decisive role in the performance of OFETs. The effect of physical/electrical properties, composition and processing condition of the gate dielectrics on the device performance was investigated.