Novel synthesis of interconnected nanocubic PbS thin films by facile aqueous chemical route

In the present investigation, we have successfully synthesized lead sulfide (PbS) thin films by using simple, cost effective and facile aqueous chemical route. The effect of deposition time on optical, structural and morphological properties of PbS thin films were investigated by using UV–Vis–NIR absorption spectroscopy, X-ray diffraction (XRD), photoluminescence, field emission scanning electron microscopy (FESEM), high-resolution-transmission electron microscopy (HRTEM), energy dispersive X-ray spectroscopy (EDS) and X-ray photoelectron spectroscopy (XPS). The optical band gap energy was varied in the range of 0.96–1.56 eV. The XRD patterns revealed the formation of pure cubic crystal structure. FESEM micrographs demonstrated the conversion of morphology from pyramidal to interconnected nanocubic. HRTEM and selected area electron diffraction (SAED) pattern illustrated that nanoparticles are compact, well interconnected and single crystalline in nature. EDS spectrum confirms that deposited PbS thin films are in good stoichiometry.     

Static Dalvik Bytecode Optimization for Android Applications

Since just‐in‐time (JIT) has considerable overhead to detect hot spots and compile them at runtime, using sophisticated optimization techniques for embedded devices means that any resulting performance improvements will be limited. In this paper, we introduce a novel static Dalvik bytecode optimization framework, as a complementary compilation of the Dalvik virtual machine, to improve the performance of Android applications. Our system generates optimized Dalvik bytecodes by using Low Level Virtual Machine (LLVM). A major obstacle in using LLVM for optimizing Dalvik bytecodes is determining how to handle the high‐level language features of the Dalvik bytecode in LLVM IR and how to optimize LLVM IR conforming to the language information of the Dalvik bytecode. To this end, we annotate the high‐level language features of Dalvik bytecode to LLVM IR and successfully optimize Dalvik bytecodes through instruction selection processes. Our experimental results show that our system with JIT improves the performance of Android applications by up to 6.08 times, and surpasses JIT by up to 4.34 times.     

Advanced Concentration Gradient Cathode Material with Two‐Slope for High‐Energy and Safe Lithium Batteries

Li[Ni_0.65Co_0.13Mn_0.22]O₂ cathode with two‐sloped full concentration gradient (TSFCG), maximizing the Ni content in the inner part of the particle and the Mn content near the particle surface, is synthesized via a specially designed batch‐type reactor. The cathode delivers a discharge capacity of 200 mAh g^?1 (4.3 V cutoff) with excellent capacity retention of 88% after 1500 cycles in a full‐cell configuration. Overall electrochemical performance of the TSFCG cathode is benchmarked against conventional cathode (CC) with same composition and commercially available Li[Ni_0.8Co_0.15Al_0.05]O₂ (NCA). The TSFCG cathode exhibits the best cycling stability, rate capability, and thermal stability of the three electrodes. Transmission electron microscopy analysis of the cycled TSFCG, CC, and NCA cathodes shows that the TSFCG electrode maintains both its mechanical and structural integrity whereas the NCA electrode nearly pulverizes due to the strain during cycling.     

Highly sensitive hydrogen detection of catalyst-free ZnO nanorod networks suspended by lithography-assisted growth

We have successfully demonstrated a ZnO nanorod-based 3D nanostructure to show a high sensitivity and very fast response/recovery to hydrogen gas. ZnO nanorods have been synthesized selectively over the pre-defined area at relatively low temperature using a simple self-catalytic solution process assisted by a lithographic method. The conductance of the ZnO nanorod device varies significantly as the concentration of the hydrogen is changed without any additive metal catalyst, revealing a high sensitivity to hydrogen gas. Its superior performance can be explained by the porous structure of its three-dimensional network and the enhanced surface reaction of the hydrogen molecules with the oxygen defects resulting from a high surface-to-volume ratio. It was found that the change of conductance follows a power law depending on the hydrogen concentration. A Langmuir isotherm following an ideal power law and a cross-over behavior of the activation energy with respect to hydrogen concentration were observed. This is a very novel and intriguing phenomenon on nanostructured materials, which suggests competitive surface reactions in ZnO nanorod gas sensors.     

Symbiotic Dynamic Memory Balancing for Virtual Machines in Smart TV Systems

Smart TV is expected to bring cloud services based on virtualization technologies to the home environment with hardware and software support. Although most physical resources can be shared among virtual machines (VMs) using a time sharing approach, allocating the proper amount of memory to VMs is still challenging. In this paper, we propose a novel mechanism to dynamically balance the memory allocation among VMs in virtualized Smart TV systems. In contrast to previous studies, where a virtual machine monitor (VMM) is solely responsible for estimating the working set size, our mechanism is symbiotic. Each VM periodically reports its memory usage pattern to the VMM. The VMM then predicts the future memory demand of each VM and rebalances the memory allocation among the VMs when necessary. Experimental results show that our mechanism improves performance by up to 18.28 times and reduces expensive memory swapping by up to 99.73% with negligible overheads (0.05% on average).     

Transmission of block turbo coded digital audio over FM-SCA

In this paper, an efficient coded scheme for transmitting digital audio over the existing FM channel, by multiplexing it with the baseband FM signal, is described. Transmission of multiplexed signals in the FM baseband called FM-SCA (subsidiary communications authorization) has been previously used for low quality analog content and some low rate digital content. The investigated scheme opens up the possibility of achieving CD quality audio over FM-SCA by enabling high bitrate transmission using MPEG-I layer 3 and MPEG-AAC audio coding for the digital audio. These schemes provide CD quality audio at or below 128 kbps, MPEG-AAC being able to do so at rates as low as 96 kbps. Block turbo codes (BTC), which offer near Shannon's limit performance with relatively low hardware complexity requirements, provide the error protection. Block turbo codes have been shown to be particularly effective for high coding rates. The system uses OFDM in conjunction with 8PSK/16PSK to modulate the digital bitstream and fit it in the 44 kHz (54 to 98 kHz) band available in the FM baseband. Simulation results show an optimal system configuration for digital audio transmission in FM-SCA.     

Granulocytic sarcoma as isolated extramedullary relapse after donor lymphocyte infusion in a patient with CML who relapsed after allogeneic bone marrow transplantation: a case report

Nineteen patients with spina bifida and bilateral dislocation of the hips were studied with a minimal follow-up of 10 years. The average age at review was 21 years (range, 10-31). Ten patients had an upper neurologic level (thoracic to L3), and nine had a low lesion (L4 to sacrum). Three patients had no hip surgery. A closed or open reduction was performed in 12 hips, supplemented by one or more surgical procedures. Of these, 10 remained enlocated, and two had redislocated. In all other hips, several surgical procedures were performed, aimed at improvement of hip-flexion deformity or stability. At follow-up, one patient had occasional pain in one hip, which was dysplastic. Of the 10 patients with a high lesion, only two were walkers, but both had bilateral dislocation of the hips at follow-up. In contrast, all nine patients were walkers, but four of these had bilateral dislocation at follow-up. We found that a level pelvis and good range of motion of the hips are more important for ambulation than is reduction of bilateral hip dislocation.     

Suppression of GHz range power/ground inductive impedance and simultaneous switching noise using embedded film capacitors in multilayer packages and PCBs

We measured and demonstrated the great advantages of embedded film capacitors in reducing power/ground inductive impedance and the suppression of SSN at frequencies up to 3 GHz for high-performance multilayer packages and PCBs. Eight-layer test PCBs were fabricated, and their inductive power/ground network impedances were measured as a function of film thickness, via distribution, and combined use with discrete decoupling capacitors, using a two-port self-impedance measurement method. This successfully demonstrated that the power/ground inductive impedance was reduced from 270 pH to 106 pH simply by using an embedded film capacitor instead of 16 discrete decoupling capacitors.     

Partition characteristics of close-boiling components in a chromatographic column

Partition characteristics of three close-boiling components (dichloromethane, diethylether, and dimethoxymethane) were investigated with dinonylphthaiate-coated Chromosorb A and helium as the carrier. The outlet stream from the Chromatographic column was monitored continuously. Partition coefficients were experimentally determined at various column temperatures for the three components. With the assumption of uniform film thickness, two parameters were estimated by Fourier analysis of the response curves. The Peclet number for particle was expressed in terms of the Reynolds number and the Schmidt number as: $$\frac{1}{{Pe,p}} = \frac{{0.87}}{{\operatorname{Re} \cdot Sc}} + 0.5$$ Intraparticle diffusion coefficient of each component was also determined in the form of the dimensionless group. P_i. The theoretical response curve in time domain was in good agreement with the observed one. From the sensitivity analysis, it is concluded that the liquid film resistance was small and the diffusion in the liquid phase was not a rate-determining step.