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排序方式: 共有598条查询结果,搜索用时 15 毫秒
91.
Masato Takeuchi Junichi Deguchi Manabu Hidaka Shiro Sakai Kyoungja Woo Pyuck-Pa Choi Jong-Ku Park Masakazu Anpo 《Applied catalysis. B, Environmental》2009,89(3-4):406-410
The photocatalytic oxidation of gaseous acetaldehyde with O2 on commercial TiO2 nano-particles could be successfully enhanced by a simple mechanical blending with a high-silica mordenite (MOR) zeolite, the surface of which showed high hydrophobic properties. When the TiO2 nano-particles of ca. 5–20 wt% were mixed with the MOR zeolite powders in an agate mortar for only 5 min, the blended TiO2/MOR samples showed higher photocatalytic reactivity as compared to the pure TiO2 nano-particles. Since the high-silica zeolite powders are highly transparent in UV light regions, the incident UV light is effectively irradiated onto the whole part of the TiO2 nano-particles without any loss of light intensity. Furthermore, the siliceous MOR zeolite powders effectively adsorb the gaseous acetaldehyde molecules and supply them onto the surfaces of the blended TiO2 nano-particles, resulting in an enhancement of the photocatalytic reactivity. 相似文献
92.
Pseudomonas aeruginosa as a model microorganism for investigation of chemotactic behaviors in ecosystem 总被引:1,自引:0,他引:1
Kato J Kim HE Takiguchi N Kuroda A Ohtake H 《Journal of Bioscience and Bioengineering》2008,106(1):1-7
Motile bacteria sense changes in the concentration of chemicals in environments and respond in a behavioral manner. This behavioral response is called chemotaxis. Bacterial chemotaxis can be viewed as an important prelude to metabolism, prey-predator relationships, symbiosis, infections, and other ecological interactions in biological communities. Genome analysis reveals that a large number of environmental motile bacteria possess a number of genes involved in chemosensing and chemotatic signal transduction. Pseudomonas aeruginosa has a very complex chemosensory system with more than 20 chemotaxis (che) genes in five distinct clusters and 26 chemoreceptor (methyl-accepting chemotaxis protein [mcp]) genes. Among the 26 MCPs of P. aeruginosa, nine have been identified as MCPs for amino acids, inorganic phosphate, oxygen, ethylene, and volatile chlorinated aliphatic hydrocarbons, whereas 3 MCPs were demonstrated to be involved in biofilm formation and biosynthesis of type IV pilus. Six che genes are essential for chemotactic responses, while genes in Pil-Chp cluster and Wsp cluster are involved in type IV pilus synthesis and twitching motility and biofilm formation, respectively. P. aeruginosa, with its complex chemotaxis system, is a better model microorganism for investigating ecological aspects of chemotaxis in environmental bacteria than Escherichia coli and Salmonella enterica serovar Typhimurium, which possess a relatively simpler chemotaxis system. 相似文献
93.
94.
SiO2 nanoparticles (NPs) surface modified with polyethyleneimine-oleic acid complex (PEI-OA) has successfully prepared in a simple manner as a stabilizer of metal (Ni) fine particles (FPs) as well as a component of Ni/SiO2 composite particles. Starting from SiO2 NPs which were collected through centrifugation of commercial SiO2 colloids, it was found that PEI-OA can effectively adsorbed on collected SiO2 NPs surface during their redispersion process in toluene with the assistance of ultrasonication. The aggregated particle size (Z-average size) in toluene could be successfully reduced to c.a. 100 nm under saturated adsorption of PEI-OA. It was also found that PEI-OA-modified SiO2 NPs can effectively attach to the Ni FPs by a simple mixing process in toluene. The FE-SEM observation confirmed the adsorption of the PEI-OA-modified SiO2 NPs on the Ni FPs without forming severe NP aggregates. Owing to the attachment of the PEI-OA-modified SiO2 NPs with surfaces that are compatible to toluene and α-terpineol, the suspension stability of the Ni/SiO2 composite particles in these solvents drastically improved. The result was confirmed by the effective reduction of the sedimentation velocity of diluted suspensions as well as by the reduction of the viscosity of dense suspensions. 相似文献
95.
Wave conversion materials with high thermal conductivity are necessary for high-power semiconductor lighting. Ceramics have higher thermal conductivity than existing matrices such as resin or glass in which phosphor particles are dispersed. However, the high densification of ceramics generally requires high-temperature sintering, which degrades and alters the phosphor particles. In this study, we aimed to achieve the high densification of MgO ceramics at room temperature. Applying high hydrostatic pressure with water addition improved the sample packing ratio and promoted the formation of Mg(OH)2. As a result, the relative density was ≥95%. Additionally, various nitride phosphor particles (CaAlSiN3:Eu2+, β-SiAlON:Eu2+, and α-SiAlON:Eu2+) were dispersed in the MgO matrix at room temperature without degrading the luminescence property. The thermal conductivity of the obtained sample was about 8 W m?1K?1, 40 times higher than that of the epoxy matrix. 相似文献
96.
Shape-selective properties of octadecyltrichlorosilane-treated H-ZSM-5, abbreviated as H-ZSM-5-C18, have been observed in the hydrolysis of esters having some rings and lactones in toluene-water solvent system. The shape-selectivity for the reaction has been evaluated by the ratio
of the relative rate constants in comparison with the rate constant of methyl acetate. The selectivity became higher with increase in bulkiness of the substrate. Substrates having the minimum diameter larger than 6.5 Å, significantly larger in size than the pore openings of ZSM-5, could not react in this system. 相似文献
97.
Kazuki Yanome Takayuki Kiba Midori Kawamura Yoshio Abe Kyung Ho Kim Junichi Takayama Akihiro Murayama 《Journal of Electronic Materials》2017,46(7):3873-3879
We report the ellipsometric and photoluminescence (PL) properties of Indium zinc oxide (IZO) films, which were grown by radio frequency sputtering under Ar and O2 atmospheres. IZO films grown under an O2 atmosphere (IZO (O2)) showed enhanced PL properties when compared to the films grown under an Ar atmosphere (IZO (Ar)), particularly with respect to the band-edge emission. The enhancement of band-edge emission can be attributed to the reduction in the non-emissive defect states related to oxygen vacancies, which were repaired by sputtering under O2 atmosphere, whereas the PL enhancement in green region is probably due to the formation of the different types of defects under the excess oxygen environment. This was also supported by the results of time-resolved PL measurements, where the band-edge emission of IZO (Ar) showed rapid decay with a 50 ps lifetime, which indicates the dominance of the relaxation pathway to underlying defect states. In contrast, the PL decay profiles of IZO (O2) for band-edge and emissive defect states showed moderate decay with time-constants of 2.3 ns and 5.7 ns, respectively. The exciton relaxation dynamics were sensitive to the presence and its kinds of defect states, which were controlled by the growth conditions. 相似文献
98.
99.
100.
Toshiaki Momose Yoshiya Yamaguchi Takashi Iida Junichi Goto Toshio Nambara 《Lipids》1998,33(1):101-108
The structure-retention correlation of various C24 bile acid isomers was studied by the addition of methyl β-cyclodextrin (Me-β-CD) to mobile phases in reversed-phase high-performance
liquid chromatography (HPLC). The compounds examined include a series of monosubstituted bile acids related to cholanoic acids
differing from one another in the position and configuration of an oxygen-containing function (hydroxyl or oxo group) at the
position C-3, C-6, C-7, or C-12 and the stereochemistry of the A/B-ring fusion (trans 5α-H and cis 5β-H) in the steroid nucleus. The inclusion HPLC with Me-β-CD was also applied to biologically important 4β- and 6-hydroxylated
bile acids substituted by three to four hydroxyl groups in the 5β-steroid nucleus. These bile acid samples were converted
into their fluorescence prelabeled 24-pyrenacyl ester derivatives and chromatographed on a Capcell Pak C18 column eluted with methanol-water mixtures in the presence or absence of 5 mM Me-β-CD. The effects of Me-β-CD on the retentions
of each compound were correlated quantitatively to the decreasing rate of capacity factors and the relative strength of host-guest
inter-actions. On the basis of the retention data, specific and nonspecific hydrogen-bonding interactions between the bile
acids and the Me-β-CD were discussed. 相似文献