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121.
    
A series of (vinylphenyl)pyridine‐based polymer binders, PVPh2Py, PVPh3Py, and PVPh4Py, are designed and synthesized and it is found that mixtures of Liq and the polymers exhibit superior electron injection characteristics as ultrathin (1.6 nm) electron injection layer (EIL) films. They are comparable to those of EILs composed only of Liq. The addition of the polymers does not deteriorate the performance of Liq EILs. Additionally, when the EIL thickness is increased from 1.6 nm to 16 nm, the driving voltages increase and the external quantum efficiencies decrease. The increase in the voltage and decrease in the EQE are suppressed in the device with mixed EILs compared to those observed for the device composed of 100 wt% Liq. Furthermore, the position of the nitrogen in the pyridine ring is considered to influence the electron transport properties of the EILs. The mixing PVPh4Py with Liq improves the driving voltage of the fabricated devices, even with a thick mixed EIL. This reduced dependence of the performance of EILs on their thickness will be advantageous for the coating of large areas using solution processes.  相似文献   
122.
    
Silk is a protein fiber used to weave fabrics and as a biomaterial in medical applications. Recently, genetically modified silks have been produced from transgenic silkworms. In the present study, transgenic silkworms for the mass production of three colors of fluorescent silks, (green, red, and orange) are generated using a vector originating from the fibroin H chain gene and a classical breeding method. The suitability of the recombinant silks for making fabrics is investigated by harvesting large amounts of the cocoons, obtained from rearing over 20 thousand silkworms. The application of low temperature and a weakly alkaline solution for cooking and reeling enables the production of silk fiber without loss of color. The maximum strain tolerated and Young's modulus of the fluorescent silks are similar to those of ordinary silk, although the maximum stress value of the recombinant silk is slightly lower than that of the control. Fabrics with fluorescent color are demonstrated using the recombinant silk, with the color persisting for over two years. The results indicate that large amounts of genetically modified silk can be made by transgenic silkworms, and the silk is applicable as functional silk fiber for making fabrics and for use in medical applications.  相似文献   
123.
  总被引:1,自引:0,他引:1  
In search of an efficient transdermal drug delivery system (TDDS), a polyhydroxyalkanoate (PHA)-based system with a polyamidoamine dendrimer was examined. Tamsulosin was used as the model drug. The dendrimer was found to act as the weak enhancer. By adding the dendrimer, the dendrimer-containing PHA matrix achieved the clinically required amount of tamsulosin permeating through the skin model. This is also the first report of the application of PHA and dendrimer to the TDDS.  相似文献   
124.
In recent studies on two-dimensional supersonic jets, it is reported that the hysteresis phenomenon for the reflection type of shock waves in the jet flow field is occurred under the quasi-steady flow condition and this phenomenon is affected by the transitional pressure ratio between the regular reflection and Mach reflection. However, so far, there are few researches on the hysteresis phenomenon for the transition of shock waves between regular and Mach reflection in over-expanded supersonic jets and the phenomenon has not been investigated satisfactorily. Therefore, the purpose of this study is to clarify the hysteresis phenomena for the reflection type of shock wave in the over-expanded axi-symmetric supersonic jet experimentally, and to discuss the relationship between hysteresis phenomenon and rate of the change of pressure ratio with time. Furthermore, the effect of Mach number at the nozzle exit on hysteresis loop was investigated for two kinds of nozzle.  相似文献   
125.
    
Poly(arylene ether nitrile) (PEN) nanocomposites filled with functionalized graphite nanoplates (GNs) were prepared by a simple solution‐ casting method and then characterized by rheometer and thermogravimetric analysis (TGA). This study investigates how the surface treatment of GNs affects the GN dispersion state. The linear rheological test indicated that the 4‐aminophenoxyphthalonitrile‐grafted GN (GN‐CN) presented better dispersion in PEN matrix than purified GN because the corresponding composite showed the lower rheological percolation threshold, which was further confirmed by scanning electron microscopy and solution experiments. The TGA revealed that the presence of 4‐aminophenoxyphthalonitrile‐grafted GN retarded the depolymerization evidently compared with that of purified GN, showing remarkable increase in the temperatures corresponding to a weight loss of 5 wt % (increased by 21°C) and maximum rate of decomposition (increased by 9°C). Both the dispersion state and the surface functionalization of GN are very important to the thermal stability of PEN matrix. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013  相似文献   
126.
Females of the solitary endoparasitoid Cotesia vestalis respond to a blend of volatile organic compounds (VOCs) released from plants infested with larvae of their host, the diamondback moth (Plutella xylostella), which is an important pest insect of cruciferous plants. We investigated the flight response of female parasitoids to the cruciferous plant Brassica rapa, using two-choice tests under laboratory conditions. The parasitoids were more attracted to plants that had been infested for at least 6 hr by the host larvae compared to intact plants, but they did not distinguish between plants infested for only 3 hr and intact plants. Although parasitoids preferred plants 1 and 2 days after herbivory (formerly infested plants) over intact plants they also preferred plants that had been infested for 24 hr over formerly infested plants. This suggests that parasitoids can distinguish between the VOC profiles of currently and formerly infested plants. We screened for differences in VOC emissions among the treatments and found that levels of benzyl cyanide and dimethyl trisulfide significantly decreased after removal of the host larvae, whereas terpenoids and their related compounds continued to be released at high levels. Benzyl cyanide and dimethyl trisulfide attracted parasitoids in a dose-dependent manner, whereas the other compounds were not attractive. These results suggest that nitrile and sulfide compounds temporarily released from plants under attack by host larvae are potentially more effective attractants for this parasitoid than other VOCs that are continuously released by host-damaged plants.  相似文献   
127.
When predators invade a leaf patch inhabited by herbivores, the herbivores disperse to a neighboring predator-free leaf patch, thus escaping from the predators. However, the neighboring patch might already be used by con- or heterospecific herbivores. We used laboratory bioassays to examine whether perception of odor from con- or heterospecific competitors on a neighbored lima bean leaf patch influences dispersal behavior of the herbivorous mite Tetranychus urticae when attacked by predatory mites Phytoseiulus persimilis. The dispersal rates of T. urticae that perceived odors from leaf patches infested by conspecifics or cowpea aphids (Aphis craccivora) did not differ from the control (the dispersal rate of T. urticae that perceived odor from uninfested leaf patches). By contrast, the dispersal rate of T. urticae was reduced when they perceived odors from leaf patches that were currently or had previously been infested by larvae of the common cutworm (Spodoptera litura). Previous herbivory by S. litura larvae induced resistance in leaf patches to T. urticae as indicated by the reduced number of eggs laid by T. urticae. Our results are discussed with respect to the feeding behavior of the tested competitors of T. urticae and the impact of the plant and arthropod community on the dispersal behavior of these mites.  相似文献   
128.
采用相同工艺制作的横向 PNP晶体管进行了低剂量率辐照实验,研究了不同周长面积比、不同基区有效宽度、不同发射极面积及不同氧化层厚度的双极晶体管的低剂量率辐射损伤增强效应。实验结果表明:通过提高横向 PNP管周长面积比、减小基区有效宽度、增加发射极面积和减薄氧化层厚度,在低剂量率下横向 PNP双极晶体管辐照前后增益降低小于 50%,且辐照后增益大于 100,大幅度提升了横向 PNP管的抗辐射能力。  相似文献   
129.
目的 得到IP防腐涂层的本构模型。方法 通过连续刚度法对涂层表面进行纳米压痕试验,得到硬度和弹性模量,输出载荷-位移曲线。利用量纲分析法的 定理,建立各本构参数之间的无量纲函数,确定涂层的本构模型,最后将本构模型代入有限元模型,模拟纳米压痕试验,对比仿真与试验的载荷-位移曲线,验证本构模型的准确性。结果 涂层的硬度为5.49 GPa,弹性模量为69.31 GPa。有限元仿真时,若特征应变偏小,在加载阶段,曲线随硬化指数减小而下移;在卸载阶段,曲线随硬化指数的增大而左移。特征应变偏大时,载荷-位移曲线表现则相反。经对比试验与有限元仿真得到的载荷-位移曲线,二者较为一致。结论 涂层具有较高的表面硬度,表面抗变形能力较好。特征应变偏小时,载荷-位移曲线变化是因为硬化指数变大,加载阶段塑性功增加,总功也增加;特征应变偏大时的相反趋势是因为计算的屈服强度大幅度下降和特征应力点后移导致的塑性功增加。获得的涂层本构模型具有较高的精度且该方法具有可靠性。  相似文献   
130.
黄海涛  陈曦  查俊吉 《电网技术》2022,44(8):2955-2963

多园区综合能源系统具有能源互济互联、协调合作运行、利益主体多元的重要特征,这对各园区间能量交互与协同管理提出了自主自治、隐私安全等要求。为此就多园区综合能源系统能量交易模式及物理实现架构,提出一种分区自治式能量合作社区及优化调度模式。首先针对能量交易模式,引入能源供需比和讨价还价博弈模型,构建合作社区内部交易及其定价机制,模拟能源供需形势及利益分配对社区内部交易的影响,有效激励园区参与合作;其次针对物理实现架构,构建各园区内综合能源系统模型及园区间输送管网模型,建立多园区系统的联合优化调度模型,应用交替方向乘子法分布式求解架构提出了上、下分层的解算方法,实现合作社区能源交互交易,保证园区交易自主、运行自治、信息隐私;最后算例验证了该合作社区与调度模式能够充分挖掘园区互济效益,实现共享收益公平分配,促进园区可持续合作共赢,提升能源利用效率。

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