PP/PA6/APP/OMMT复合材料的湿热老化性能研究

采用熔融挤出插层制备聚丙烯(PP)/尼龙6(PA6)/聚磷酸铵(APP)/有机蒙脱土(OMMT)阻燃复合材料,研究温度80℃、湿度93.1%的湿热老化条件对复合材料性能的影响.结果表明,随着湿热老化时间的延长,复合材料的表面形貌变得很差,产生大量的粗糙白斑.当OMMT含量较低时,复合材料的拉伸强度随湿热老化时间的延长先上升后下降.而当OMMT含量较高时,复合材料的拉伸强度随着湿热老化时间的延长而下降.弯曲强度的变化规律与拉伸强度相似.缺口冲击强度则随着老化时间的延长而提高.引起复合材料破坏的主要原因并非是湿热老化反应导致的分子链断裂,而是复合材料内积聚的水泡和水分子渗入到各相界面引起界面粘结强度下降导致的结果.     

高性能全数字电压型逆变器三相独立控制技术

介绍了全数字电压型逆变器的三相独立控制技术，解决了其中两个关键问题：一是对称三相给定信号的生成；二是每相逆变器输出电压波形的跟随。实验结果证明了该控制方案能使逆变器在不平衡负载下保持三相输出电压波形的对称性。     

一起GIS接地故障原因分析

GIS设备全封闭结构导致故障检查相对复杂,如何快速准确判断出GIS故障形成原因,缩短停电时间,一直是现场技术人员十分关心的问题。笔者介绍了一例由于安装工艺引起的SF6气体绝缘开关设备(GIS)接地故障。文中通过详实的试验与现场调查,分析故障产生原因,同时对GIS缺陷早期发现与交接试验提出了建议。     

Unsupervised adaptation of electroencephalogram signal processing based on fuzzy C‐means algorithm

This paper studies an unsupervised approach for online adaptation of electroencephalogram (EEG) based brain–computer interface (BCI). The approach is based on the fuzzy C‐means (FCM) algorithm. It can be used to improve the adaptability of BCIs to the change in brain states by online updating the linear discriminant analysis classifier. In order to evaluate the performance of the proposed approach, we applied it to a set of simulation data and compared with other unsupervised adaptation algorithms. The results show that the FCM‐based algorithm can achieve a desirable capability in adapting to changes and discovering class information from unlabeled data. The algorithm has also been tested by the real EEG data recorded in experiments in our laboratory and the data from other sources (set IIb of the BCI Competition IV). The results of real data are consistent with that of simulation data. Copyright © 2011 John Wiley & Sons, Ltd.     

四分暗通道均值比较法的双角度偏振图像去雾

雾天环境下拍摄图像时,雾、霾等介质导致图像模糊、对比度低、色彩暗淡.结合大气散射模型与偏振光原理,实现了利用斯托克斯参数获取亮度最大和亮度最小的双角度偏振图像,并通过新提出的四分图像暗通道均值比较法,准确估计出场景中无穷远处大气光强值,最终将有雾图像恢复到无雾图像.所提方法在薄雾和浓雾环境下均取得了较好的实验结果,在两...     

DSTBC experimental research on UV communication system

Diversity gain can be obtained by applying the space–time block code (STBC) technology to ultraviolet (UV) communication. However, some STBCs, for example, the Alamouti code, quite depend on the acquisition of UV channel state information (CSI) because the accuracy of the obtained CSI influences the quality of the received signal and finally influences the system performance. Yet it is not easy to precisely obtain CSI, and this will affect the validity of some STBC decoding. To solve this problem, this paper tends to study the application of differential space–time block code (DSTBC) technology in the UV communication system. The validity with the exact diversity gain is verified with simulation and experimental results. The processes of the transmitters and receivers in \(2\times 2\) DSTBC are analyzed, and the different UV system performances in different communication situations are acquired. The algorithm complexity of DSTBC is compared with that of Alamouti code. The conclusion then is that the advantage of the DSTBC scheme with no requirement of obtaining real-time CSI is found in the fast time-varying and quick decaying UV channel.     

In Situ Deformation Topology of COFs with Shortened Channels and High Redox Properties for Li–S Batteries

Covalent organic frameworks (COFs) with various topologies are typically synthesized by selecting and designing connecting units with rich shapes. However, this process is time-consuming and labour-intensive. Besides, the tight stacking of COFs layers greatly restrict their structural advantages. It is crucial to effectively exploit the high porosity and active sites of COFs by topological design. Herein, for the first time, inducing in situ topological changes in sub-chemometric COFs by adding graphene oxide (GO) without replacing the monomer, is proposed. Surprisingly, GO can slow down the intermolecular stacking and induce rearrangement of COFs nanosheets. The channels of D- [4+3] COFs are significantly altered while the stacking of periodically expanded framework is weakened. This not only maximizes the exposure of pore area and polar groups, but also shortens the channels and increases the redox activity, which enables high loading while enhancing host-guest interactions. This topological transformation to exhibit the structural features of COFs for efficient application is an innovative molecular design strategy.     

低于1×10-6/℃的低压CMOS带隙基准电流源

提出了一种新颖的CMOS带隙基准电流源的二阶曲率补偿技术,通过增加一个运算跨导放大器(OTA),使带隙基准参考电路的电流特性与理论分析相符合,实现低温度系数(TC)的参考电流。该电路采用SMIC0.13μm标准CMOS工艺,可在1.2 V的电源电压下工作,有效面积为0.045 mm2。仿真结果表明,在-40～85℃温度范围内参考电流的温度系数为0.5×10-6/℃;当电源电压为1.1 V时,电路依然可以正常工作,电源电压调整率为1 mV/V。     

等离子体目标宽频电磁散射特性的快速分析

针对等离子体宽频电磁散射特性分析的复杂性,提出了一种基于最佳一致逼近理论的宽频分析算法。该方法以获得切比雪夫级数逼近为基础,并转化为梅利逼近,使得计算精度大为改善。相比于传统的泰勒-帕德模式,其具有低内存、高精度、有效计算带宽大等优势,尤其在分析等离子体这种色散介质的宽频特性时,避免了复杂高阶阻抗矩阵导数的计算。通过不同实例的数值仿真分析,说明该方法可以作为一种分析等离子体目标宽频特性的有效工具。     

Ionic Liquid Analogs of AlCl3 with Urea Derivatives as Electrolytes for Aluminum Batteries

The ionic liquid analog, formed through the mixture of urea and AlCl₃, has previously shown to serve as a low‐cost electrolyte for an aluminum‐graphite battery, while maintaining good performance and achieving high Coulombic efficiency. Undesirable are the relatively high viscosity and low conductivity of this electrolyte, when compared to chloroaluminate ionic liquids with organic cations. In this work, the fundamental changes to the electrolyte resulting from using derivatives of urea (N‐methyl urea and N‐ethyl urea), again mixed with AlCl₃, are examined. These electrolytes are shown to have significantly lower viscosities (η = 45, 67, and 133 cP when using N‐ethyl urea, N‐methyl urea, and urea, respectively, at 25 °C). The associated batteries exhibit higher intrinsic discharge voltages (2.04 and 2.08 V for N‐methyl urea and N‐ethyl urea electrolytes, respectively, vs 1.95 V for urea system@100 mA g^?1 specific current for ≈5 mg cm^?2 loading), due to changes in concentrations of ionic species. Aluminum deposition is directly observed to primarily occur through reduction of Al₂Cl₇^? when AlCl₃ is present in excess, in contrast to previously suggested cationic Al‐containing species, via operando Raman spectroscopy performed during cyclic voltammetry.