FTIR investigation of ethylene coordination and polymerization on reduced Cr/SiO2 catalyst

FTIR spectroscopy was applied to study the initial steps of ethylene polymerization on reduced chromia-silica (0.5 wt% Cr/SiO₂). To decrease the speed of the reaction small doses of gas were introduced to the catalyst in each run and C₂D₄ was used to confirm band assignments. At the initial steps of the reaction only ethylene molecules coordinated to probably Cr _A ²⁺ cations were observed. The concentration of such complexes was estimated to be about 50% of the total amount of Cr atoms in the sample. The FTIR spectrum of the polymer formed at the initial doses of C₂H₄ (when [C₂H₄] [Cr]) was found to be slightly different from that formed after excess ethylene was introduced onto the catalyst ([C₂H₄] > [Cr]).     

Goodwin House, a place for healing

The following report is excerpted from a senior thesis project prepared by Kirstin Shank. For her thesis, Shank produced an exceptionally thorough and thoughtful proposal for a home for people living with AIDS and HIV. The specifics of her plan may not be easily translated for all such centers, but her holistic approach to designing a therapeutic environment can indeed serve as a models for designers across the country grappling with similar challenges.     

Synthesis of ceramic membranes

Non-supported -alumina films are prepared from a boehmite colloidal suspension. After calcination at 600°C, the microstructure is characterized by a mean pore diameter of 3 nm, a porosity of 50% and a tortuosity of 5.5. The structure is formed by card packed, plate-shaped particles, giving rise to slit-shaped pores. Supported -alumina films, made by a slipcasting process using the same boehmite precursor, have a similar structure as the non-supported films. The slipcasting process is very sensitive to support characteristics and frequently yields defect films. Polyvinylalcohol (PVA) (molecular weight 72000 g mol^–1) is added to the boehmite precursor (0.25 gg^–1 film) to improve this process. This addition results in a less critical and better controllable drying and calcining procedure. The addition of PVA is necessary to slipcast defect free -alumina films on supports with pore diameters of 0.4 m or smaller and on multi-layer supports. It has no significant effect on the resultant microstructure of the -alumina film, provided all PVA is removed by appropriate thermal treatment. The slipcasting rate is slower, resulting in thinner films of 3–5 m at identical slipcasting times.     

Synthesis of metal nitrides and carbide powders by a spark discharge method in liquid media

Metal nitrides and carbides powders were synthesized by the spark discharge method in liquid ammonia at 100 °C and 11 kV of the spark discharge voltage and in n-heptane at 25 °C and 7.5 kV using the pellets of aluminum, titanium, iron and chromium as the starting material. The main products were AlN, TiN_0.51, -Fe, -Cr₂N in liquid ammonia, and Al₄C₃, TiC, -Fe, Fe₂C and Cr₇C₃ in n-heptane. The agglomerated particle size decreased with increasing melting point of the metal used as the starting material.     

Use of AgInTe2 for optoelectronic switching at higher frequencies

A possible application of AgInTe₂ for optoelectronic switching is reported. Alternating and direct current (a.c. and d.c.) response of the material has been studied over a wide frequency range (5 Hz to 1 MHz) through measurements of conductance, capacitance and photocurrent at different temperature and illumination levels. The switching/recovery time has been analysed in terms of time constant and found to be of the order of microseconds for this material. Higher frequencies of operation (>40 kHz) are preferable because, at such frequencies, becomes almost independent of illumination level and temperature. Furthermore, the switching speed can be conveniently controlled with d.c. bias applied across the sample. Elliott's CBH model has been satisfactorily used to explain the switching behaviour for AgInTe₂.     

Aspects of modeling the frequency response of a two-port waveguide-coupled SAW resonator-filter

Coupling-of-modes-in-time and coupling-of-modes-in-space analyses are applied to the modeling of a two-port two-pole waveguide-coupled SAW resonator filter. Modeling is applied to a lumped equivalent circuit and a distributed circuit. While the accuracy of the coupling estimation dictates the exact mode-splitting and bandwidth, the ensuing computations can give a good representation of the amplitude and phase response, including the effect of degenerate transverse modes.     

On evolution of open dynamical systems: Some algebraic methods

Open dynamical systems which are governed by a finite number of ordinary differential equations with controls (time-dependent control parameters) constitute a large and important class of models for practical purposes. In the last few years, there has been considerable interest and progress in algebraic methods for solving the equations of the form (*) $$\dot x\left( t \right) = L_0 x\left( t \right) + \sum\limits_{j = 1}^r {u\left( t \right)L_i x\left( t \right)} ,$$ i.e. bilinear models. In this paper, intended as an expository introduction to the main results of system-theoretic approach to the modelling of open systems, a new “polynomial” representation of solutions to (*) is discussed.     

Comparison of hydrogeologic parameters evaluated by deep well testing programs to assess nuclear waste repository feasibility

Hydrogeologic parameters evaluated for rocks investigated in deep well testing projects for nuclear waste repository feasibility are transmissivity, hydraulic conductivity and storativity. Such studies have been carried out in rock formations of different geologic types, origins and ages for nuclear waste management agencies in North America and Europe. From transient pressure testing, an assessment of static pressure in selected fracture zones was measured from which a profile with depth was developed using modelling techniques. As well, temperatures of formation fluids and hence thermal gradients have also been provided. Hydrogeologic parameters are commonly used in risk analysis for repositories with respect to the possible escape of contaminants and worst case scenarios. The parameters are related to the rate of possible radionuclide migration into the biosphere. The techniques of the investigation and analysis methods of this work have been fully described in the literature. This paper is the first to date, however, to compare results from testing in differen geologic environments. High transmissivity zones have been observed in the upper few hundred metres of granite formations. Below that depth, the rock is more competent and discrete zones of higher permeability occur less frequently. Our studies show, however, that in these rocks, zones of high hydraulic conductivity do not always correspond to zones of high fracture frequency. Most formation pressure profiles have a vertical gradient of about 10 kPa/m. In discrete zones, deviations from this trend can occur due to vertical inhomogeneity in the rock. Thermal gradients vary considerably from one investigation site to another. For example, in the Canadian Shield, gradients are of the order of 1.0 degree C per 100 m, whereas in similar rock types in Europe, the gradient is up to 4.0 degrees C per 100 m.