Cause and effect in the weathering of plastics

In most instances, the study of the weatherability of plastics follows empirical schemes that show little correlation with the actual effects of outdoor exposure. A more reliable analysis must be based on a knowledge of the factors in the weather which affect plastic properties and of the modes of interaction between these factors and the plastic material. It is shown that both the factors of the weather and the kinetics of polymer degradation may be expressed in a quantitative manner suitable for analytical treatment. Furthermore, it is shown that the analytical approach yields predictions which are in qualitative agreement with the results of actual outdoor exposure. Finally, some new techniques are proposed for more reliable predictions of long-term outdoor weatherability on the basis of laboratory studies.     

RO,MSF and VTE/VC Desalination: A comparative evaluation

For sea water conversion in single-purpose plants, reverse osmosis (RO) is shown to be more economical than multistage flash (MSF) desalination over a wide range of unit size and fuel cost. Attention is focussed on vertical tube evaporation/vapor compression (VTE/VC) a self-contained, low-energy consuming thermal process which is potentially competitive with RO.     

Capillary viscometry: A complete analysis including pressure and viscous heating effects

Capillary viscometers have been used extensively, because of their simplicity and reliability, to measure the viscosity of fluids over a wide range of shear rates. However, in capillary flow, the shear rate is not uniform throughout the capillary, a pressure gradient is established in the direction of flow, and the temperature of the fluid is nonuniform due to viscous dissipation. In the present work, a general, simple and practical method is proposed for correcting for the effects of pressure variation and viscous dissipation in determining the viscosity of polymer melts at high pressures. The method essentially involves the estimation of temperature, pressure, shear rate, and shear stress under a variety of experimental conditions at a predetermined point in the capillary. As such, it may be considered as a generalized extension of the classical Rabinowitsch-Mooney method for estimating true viscosity in capillary flow.     

Obtaining silicide free spacers by optimizing sputter etch for deep submicron CMOS processes

In this paper, we have shown that the sputter etch before cobalt deposition during the silicide processing of a deep submicron CMOS device fabrication needs to be optimized in order to eliminate a detrimental origin of gate (G) to source (S)/drain (D) bridging. It is known that Co cannot reduce even a thin layer of native oxide. Therefore, it is necessary to ensure that Co is deposited on a very clean Si surface. To ensure this, an in-situ sputter etch is commonly conducted before Co deposition. It is observed that this sputter etch process can sputter Si from the S/D area and deposit them on the sidewall spacer (SWS). This sputtered Si in turn will react with deposited Co and form silicide. The worst case leakage currents from poly-Si to composite for long (10 m) and narrow (0.18 micron) poly lines are shown to be on the order of milliampere. Transmission electron microscope (TEM) micrographs included show the existence of cobalt silicide layers (/spl sim/8 nm thick) over sidewall spacer. The silicide thickness on the sidewall spacer is correlated with resistance value calculated from current and voltage (I-V) measurements. The need for optimizing the sputter etch recipe has been validated by TEM and I-V measurements.     

Demand assignment for light-route TDMA

With the fluctuating inter-nodal traffic levels that characterize light-route networks, demand assignment (DA) provides the means of increasing the system's effective capacity. This paper focuses on the application of DA in light-route TDMA, and proposes a control architecture that is well-suited to service of heterogeneous traffic. The major advantage of the proposed architecture is its benefit from both the efficient resource management typical of centralized schemes, and the shorter response times of distributed schemes. The impact of the assignment algorithm on the grade of service to heterogeneous populations, and the difficulty in quantifying this impact are also addressed. Results from analytical and simulation models illustrating resource utilization are presented.     

Multisensor-based monitoring of weld deposition and plate distortion for various torch angles in pulsed MIG welding

Manufacturing companies often fail to maintain good weld quality due to poor arc stability and distortion after welding. Weld quality can be improved by reducing the transverse shrinkage and the angular distortion in butt welding. The welding deposition efficiency is also an important economic factor. In this work, various pulse voltage parameters have been varied along with welding torch angle in pulsed metal inert gas (P-MIG) welding. The experimental results revealed that the peak voltage is the dominant pulse voltage parameter. Various sensors were also used to monitor arc current, arc voltage, arc sound, and also weld temperature. A strong relationship between arc sound (as well as arc power) and transverse distortion (as well as metal deposition) was found to exist in P-MIG welding. The frequency domain features of welding arc sound were also extracted and correlated to the process characteristics.     

Network coding-based protection of many-to-one wireless flows

This paper addresses the problem of survivability of many-to-one flows in wireless networks, such as wireless mesh networks (WMNs) and wireless sensor networks (WSNs). Traditional protection schemes are either resource-hungry like the (1+1) protection scheme, or introduce a delay and interrupt the network operation like the (1 : N) protection scheme. In this paper, we present a network coding-based protection technique that overcomes the deficiencies of the traditional schemes. We derive and prove the necessary and sufficient conditions for our solution on a restricted network topology. Then we relax these connectivity requirements and show how to generalize the sufficient and necessary conditions to work with any other topology. We also show how to perform deterministic coding with {0,1} coefficients to achieve linear independence. Moreover, we discuss some of the practical considerations related to our approach. Specifically, we show how to adapt our solution when the network has a limited min-cut; we therefore define a more general problem that takes this constraint into account, which prove to be NP-complete. Furthermore, we discuss the decoding process at the sink, and show how to make use of our solution in the upstream communication (from sink to sources). We also study the effect of the proposed scheme on network performance. Finally, we consider the implementation of our approach when all network nodes have single transceivers, and we solve the problem through a greedy algorithm that constructs a feasible schedule for the transmissions from the sources.     

Tunable Injection Barrier in Organic Resistive Switches Based on Phase‐Separated Ferroelectric–Semiconductor Blends

Organic non‐volatile resistive bistable diodes based on phase‐separated blends of ferroelectric and semiconducting polymers are fabricated. The polarization field of the ferroelectric modulates the injection barrier at the semiconductor–electrode contact and, hence, the resistance of the comprising diodes. Comparison between the on‐ and off‐current of the switching diodes, with the current measured for semiconductor‐only diodes reveals that the switching occurs between bulk‐limited, i.e., space‐charge‐limited, and injection‐limited current transport. By deliberately varying the HOMO energy of the semiconductor and the work‐function of the metal electrode, it is demonstrated that injection barriers up to 1.6 eV can be surmounted by the ferroelectric polarization yielding on/off current modulations of more than five orders of magnitude. The exponential dependence of the current modulation with a slope of 0.25 eV/decade is rationalized by the magnitude of the injection barrier.     

An L9 orthogonal design methodology to study the impact of operating parameters on particulate emission and related characteristics during pulse-jet filtration process

This study embodies experimental characterization of emitted particulate and filtration performance under varied situation in a pulse-jet cleaning process. Tests were conducted under simulated condition in a filtration apparatus consisting four bags. The effect of four different factors such as fabric punch density, baffle plate height, air to cloth ratio and cycle time have been investigated on the key parameters; emission, pressure drop along with PM_2.5 and average particle diameter of emitted particulate matter in a pulse-jet filtration process. Experimental investigation based on L₉-orthogonal design shows that emission is reduced with the increases in punch density and pulse cycle time; but it increases up to a certain extent with the increase in air to cloth ratio. However baffle plate height has no effect on the emission. On the other hand pressure drop across the tube sheet increases with the material consolidation, air to cloth ratio and pulse cycle time; but the above parameter first decrease with the increase in baffle plate height. PM_2.5 (based on the number distribution) is found to be mainly affected by the baffle plate height and cycle time; as it first increases and then decrease with the increase in baffle plate height but it shows reverse trend with the increase in cycle time. Average particle diameter based on number volume is found to be mainly affected by the baffle plate height and cycle time. With the increase in time of filtration, both emission and pressure drop tend to increase without affecting PM_2.5 and average particle diameter based on number volume.