Epoxy‐montmorillonite clay nanocomposites: Synthesis and characterization

Nanocomposites of epoxy resin with montmorillonite clay were synthesized by swelling of different proportions of the clay in a diglycidyl ether of bisphenol‐A followed by in situ polymerization with aromatic diamine as a curing agent. The montmorillonite was modified with octadecylamine and made organophilic. The organoclay was found to be intercalated easily by incorporation of the epoxy precursor and the clay galleries were simultaneously expanded. However, Na‐montmorillonite clay could not be intercalated during the mixing or through the curing process. Curing temperature was found to provide a balance between the reaction rate of the epoxy precursor and the diffusion rate of the curing agent into the clay galleries. The cure kinetics were studied by differential scanning calorimetry. The exfoliation behavior of the organoclay system was investigated by X‐ray diffraction. Thermogravimetric analysis was used to determine the thermal stability, which was correlated with the ionic exchange between the organic species and the silicate layers. The morphology of the nanocomposites was evaluated by scanning electron microscopy. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 2201–2210, 2004     

A selective reaction of polyhydroxy fullerene with cycloaliphatic epoxy resin in designing ether connected epoxy star utilizing fullerene as a molecular core

A novel ether connected epoxy star like polymer was synthesized by selective reaction of water soluble polyhydroxy fullerene (fullerenol) with a commercial grade cycloaliphatic epoxy resin (CY-230, Ciba Geigy) in heterogeneous medium at ambient alkaline condition using tetrabutylammonium hydroxide as phase transfer catalyst. The reaction went well in such conditions and the hydroxy groups of fullerenol underwent selective nucleophilic addition reaction with polar carbonyl groups of the epoxy resin with the formation of a hemiketal. The progress of the reaction was monitored by FTIR analysis of the product formed. The disappearance of characteristic FTIR bands of fullerenol (at 1593.2, 1381.2, and 1068 cm⁻¹) and the typical carbonyl peak (at 1725 cm⁻¹) of parent epoxy resin and also changes of broad hydroxy peak (at 3431 cm⁻¹) of fullerenol into a sharp peak (at 3396.6 cm⁻¹, indicating reduced hydrophilicity) in the reaction product clearly demonstrated the chemical attachment of the epoxy units to the fullerene core. Multiple epoxy units (about 8-10) were attached to fullerene core. Non-reactivity of fullerenol towards DGEBA epoxy resin (LY 556 Ciba Geigy) in similar conditions further supports our result. The thermal properties of the product were influenced by the presence of fullerenol and exhibits higher thermal stability compared to parent epoxy. A probable reaction mechanism for the reaction has also been discussed.     

Crystallization kinetics of bulk amorphous Se80−xSbxTe20

Crystallization kinetics of the Se_80–x Sb _x Te₂₀ (0x9) alloys have been studied using differential scanning calorimetry. The activation energies for the glass transition and that for crystallization have been determined from the heating rate dependence of the glass transition temperature and the peak crystallization temperature. The results have been analysed using the modified Kissinger's and Matusita's equations for the non-isothermal crystallization of materials. The variation of glass transition temperature with composition suggests that a small amount of Sb ( 4 at %) leads to an increase in the chain length of Se-Te, whereas further increase in Sb atomic per cent increases the number of Se-Te chains in the alloys.     

Development of new encryption system using Brownian motion based diffusion

Multimedia Tools and Applications - A new cryptographic model is proposed incorporating intertwining logistic map based confusion process and two dimensional Brownian Motion based diffusion...     

An overhead and resource contention aware analytical model for overloaded Web servers

A Web server, when overloaded, shows a severe degradation of goodput initially, with the eventual settling of goodput as load increases further. Traditional performance models have failed to capture this behavior. In this paper, we propose an analytical model, which is a two-stage and layered queuing model of the Web server, which is able to reproduce this behavior. We do this by explicitly modelling the overhead processing, the user abandonment and retry behavior, and the contention for resources, for the FIFO and LIFO queuing disciplines. We show that LIFO provides better goodput in most overload situations. We compare our model predictions with experimental results from a test bed and find that our results match well with measurements.     

Architectural space planning using evolutionary computing approaches: a review

This paper presents various applications of evolutionary computing approach for architectural space planning problem. As such the problem of architectural space planning is NP-complete. Finding an optimal solution within a reasonable amount of time for these problems is impossible. However for architectural space planning problem we may not be even looking for an optimal but some feasible solution based on varied parameters. Many different computing approaches for space planning like procedural algorithms, heuristic search based methods, genetic algorithms, fuzzy logic, and artificial neural networks etc. have been developed and are being employed. In recent years evolutionary computation approaches have been applied to a wide variety of applications as it has the advantage of giving reasonably acceptable solution in a reasonable amount of time. There are also hybrid systems such as neural network and fuzzy logic which incorporates the features of evolutionary computing paradigm. The present paper aims to compare the various aspects and merits/demerits of each of these methods developed so far. Sixteen papers have been reviewed and compared on various parameters such as input features, output produced, set of constraints, scope of space coverage-single floor, multi-floor and urban spaces. Recent publications emphasized on energy aspect as well. The paper will help the better understanding of the Evolutionary computing perspective of solving architectural space planning problem. The findings of this paper provide useful insight into current developments and are beneficial for those who look for automating architectural space planning task within given design constraints.     

A new fuzzy decision-making procedure applied to emergency electric power distribution scheduling

In this paper a new fuzzy decision-making procedure is developed. Two levels of weightings, called upper and lower weights, are proposed to calculate the fuzzy weightings of different criteria. The preference table is introduced to calculate the upper and lower weights. Also a new method is developed to determine the expected preference values of different alternatives. These values are used for generating the priority list of alternatives. The procedure is applied for providing an emergency electric power distribution, scheduling time table. The IEEE 14-bus standard system and a 14-bus system with four power plants are considered as case studies. Using fuzzy decision-making procedure, the regions with more priorities are more connected to the distribution net, while the maximum consumption criterion is also reasonably respected.     

Constructing malware normalizers using term rewriting

A malware mutation engine is able to transform a malicious program to create a different version of the program. Such mutation engines are used at distribution sites or in self-propagating malware in order to create variation in the distributed programs. Program normalization is a way to remove variety introduced by mutation engines, and can thus simplify the problem of detecting variant strains. This paper introduces the “normalizer construction problem” (NCP), and formalizes a restricted form of the problem called “NCP=”, which assumes a model of the engine is already known in the form of a term rewriting system. It is shown that even this restricted version of the problem is undecidable. A procedure is provided that can, in certain cases, automatically solve NCP= from the model of the engine. This procedure is analyzed in conjunction with term rewriting theory to create a list of distinct classes of normalizer construction problems. These classes yield a list of possible attack vectors. Three strategies are defined for approximate solutions of NCP=, and an analysis is provided of the risks they entail. A case study using the virus suggests the approximations may be effective in practice for countering mutated malware. R. Mathur is presently at McAfee AVERT Labs.     

Influence of dietary iron deficiency on acute metal intoxication

The frequent difficulties encountered in the diagnosis of pediatric sarcomas, caused by the lack of observable differentiation at the light microscopic level, has led to the routine use of immunohistochemistry in pediatric surgical pathology. To a large degree the advent of this staining technique has led to the correct assessment of many perplexing lesions that previously would have been given inconclusive diagnoses. However, with increased usage and testing, it has become apparent that there are few, if any, "magic bullets" in immunohistochemistry for pediatric pathologists. Thus, it behooves diagnosticians to be careful in the usage of this technique, to be aware of possible discrepancies in its results, and to remember the ancillary nature of its application. The following article will review selected markers commonly used in pediatric surgical pathology, from both previous reports and the author's perspective, and will briefly consider several new phenotypic markers which have potential utility with childhood sarcomas.