Die Bestimmung von Schwefelanteilen im Stahl unter 10 μg/g

Analytische Möglichkeiten einer neuen Gerätegeneration. Weiterentwicklung des Verfahrens mit synthetischer Eichung bis zur Bestimmungsgrenze 2 μg/g.     

Festlegung der physikalischen Wirkzusammenhänge,Unterprogramm PHYWIZ,beim rechnerunterstützten systematischen Projektieren und Konstruieren

Aufgabe des Unterprogrammes PHYWIZ. Ermittlung physikalischer Funktionen zur Erfüllung der Funktionen der festgelegten logischen Funktionskette. Variante physikalische Funktionen und Mehrfachzuordnungen. Programmstruktur zur Berechnung physikalischer Wirkzusammenhänge. Behandlung der unmittelbar schnittstellenabhängigen Zusammenhänge. Vorgehen bei Überschreitung der Schnittstellenbedingungen. Bearbeitung der physikalischen Wirkzusammenhänge, die keinen Einfluß auf die Schnittstellenbedingungen haben können. Bewertung varianter Funktionsketten und endgültige Festlegung auf eine physikalische Funktionskette.     

Optimierung spektrometrischer Verfahren durch ein Datenverarbeitungssystem

Einsatz von Prozeßrechnern in Laboratorien. Aufbau eines Systems zur Produktionsüberwachung eines Sauerstoffaufblasstahlwerkes. Beschreibung des Rechners und der Programmgestaltung. Ablauf der emissionsspektrometrischen und röntgenfluoreszenzspektrometrischen Roheisen-, Stahl- und Schlackenanalysen. Erste Ergebnisse und Erfahrungen.     

Integral Antireflective Surface Production on Optical Glass

Integral antireflective surfaces with extremely high laser-damage thresholds were prepared on optical glasses by controlled corrosion in neutral solution. Properties of such surfaces are discussed and compared with gradient antireflective surfaces produced on phase-separated borositicate glasses.     

Interaction of thermally induced and mechanical fatigue

The influence of superimposed total strain controlled HCF loadings on TMF life is presented and discussed for several cast Al-Si alloys, the Ni-base superalloy Inconel 617 and the cast iron GJS-700. Except for GJS-700, a threshold of the superimposed HCF loading is observed, below of which TMF life is not significantly affected. The strong decrease of TMF life as soon as the HCF amplitude exceeds this threshold is due to fundamental changes in the crack propagation mechanisms. The paper closes with a brief overview on lifetime prediction methods for TMF and their application in the case of TMF/HCF loadings.     

Kinetik der polykondensation von natriumsulfidhydrat und 1,4-dichlorbenzol zu poly(thio-1,4-phenylen)

The kinetics of the polycondensation of sodium sulfide hydrate and 1,4-dichlorobenzene to poly(thio-1,4-phenylene) in 1-methyl-2-pyrrolidone as solvent was studied in a differential scanning calorimeter at temperatures between 220 and 280°C. This polycondensation shows an autocatalytic behavior and the kinetics can be modelled by a first order reaction up to complete conversion. This is explained by the low solubility of sodium sulfide in l-methyl-2-pyrrolidone. The concentration of sodium sulfide is regarded as being constant during the whole course of the reaction. The autocatalytic effect can be explained by the increase of the condensation rate constant at the beginning of polycondensation due to the higher reactivity of the oligomers compared to the monomers. The number- and the weight-average molecular weight of the products formed during the course of the polycondensation can be modelled by means of stochastic methods. A simple model with only two different rate constants of the condensation process is assumed. The concentration of sodium sulfide in the reactive phase is found to be 2–5% of the value of dichlorobenzene at the beginning of the reaction and remains constant nearly until the end of polycondensation.     

Study of Interatomic Potentials in ZnS—Crystal-GRID Experiments Versus Ab Initio Calculations

Crystal-GRID measurements have been performed with ZnS single crystals. For the first time, an asymmetric Crystal-GRID line shape could be observed. The preliminary data evaluation indicates that the reported lifetime of the 3221 keV level in ³³S is too short. A value of about 60 fs has been found. Due to this “long” lifetime the line shape is much less structured than calculated with the reported lifetime.     

Numerical analysis of ductile failure of undermatched interleaf in tension

Ductile failure of an interleaf tension specimen consisting of a metal interleaf bonded between two elastic substrates, with a crack located in the centre of the metal, is studied by means of detailed finite element (FE) analyses. The rate-independent version of the Gurson model is used. This accounts for ductile failure mechanisms of micro-void nucleation, growth and coalescence within the framework of a finite deformation plasticity theory. Also, the rapid evolution of void density due to coalescence, which leads to ultimate failure, is considered. The effect of the interleaf thickness on failure (crack initiation and limited amount of crack growth) is investigated. The results show that the interleaf thickness affects crack initiation only slightly. For all specimens considered, crack initiation takes place at the crack tip. However, after crack initiation, the interleaf thickness affects stress and strain distributions significantly. Reducing the interleaf thickness significantly increases the load-carrying capacity. Moreover, reducing the interleaf thickness increases the maximum hydrostatic stress in the interleaf, which is no longer developed at the crack tip but at a distance far away from the crack tip. The resulting fracture toughness thus decreases as the interleaf thickness decreases. The shielding of the crack tip due to constrained plasticity is observed at higher load levels for interleaf specimens. This revised version was published online in August 2006 with corrections to the Cover Date.