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131.
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Katja Maihold 《Bautechnik》2007,84(6):396-396
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Robert Wegener Stefan Schulz Torsten Meiners Katja Hadwich Monika Hilker 《Journal of chemical ecology》2001,27(3):499-515
Egg deposition of the elm leaf beetle Xanthogaleruca luteola causes the emission of volatiles from its food plant, Ulmus minor. These volatiles are exploited by the egg parasitoid, Oomyzus gallerucae, to locate its host. In contrast to other tritrophic systems, the release of volatiles is not induced by feeding but by egg deposition. Previous investigations showed that the release is systemic and can be triggered by jasmonic acid. Comparison of headspace analysis revealed similarities in the blend of volatiles emitted following egg deposition and feeding. The mixture consists of more than 40 compounds; most of the substances are terpenoids. Leaves next to those carrying eggs emit fewer compounds. When treated with jasmonic acid, leaves emit a blend that consists almost exclusively of terpenoids. Dichloromethane extracts of leaves treated with jasmonic acid were also investigated. After separation of extracts of jasmonate induced elm leaves on silica, we obtained a fraction of terpenoid hydrocarbons that was attractive to the parasitoids. This indicates that jasmonic acid stimulates the production of terpenoid hydrocarbons that convey information of egg deposition to the parasitoid. 相似文献
135.
Rheological properties of aqueous solutions and hydrogels formed by an amphiphilic star block copolymer, poly(acrylic acid)-block-polystyrene (PAA54-b-PS6)4, were investigated as a function of the polymer concentration (Cp), temperature, and added salt concentration. The water-soluble polymer synthesised by atom transfer radical polymerization (ATRP) was found to form hydrogels at room temperature at polymer concentrations, Cp, over 22 g/L due to the interpolymer hydrophobic association of the PS blocks. Increasing Cp leads to stronger elastic networks at room temperature that show a gel-to-solution transition with increasing temperature. Increase of ionic strength decreases the moduli compared with the pure hydrogel but did not affect the gel-sol transition temperature significantly. Small-angle X-ray experiments showed two distinct scattering correlation peaks for samples above the gelling Cp, which indicates the aggregates formed due to hydrophobic association. Upon heating the intensity of the scattering correlation peaks was found to decrease indicating the loss of the network structure due to thermal motion. 相似文献
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Homoionic Na+, Ca2+, Sr2+, Li+, Cu2+ and Zn2+ samples of the <2 μm fraction of a cis-vacant montmorillonite from Linden (Bavaria) were steam treated at 200°C (≈1.5 MPa), 240°C (≈3.3 MPa) and 300°C (≈8.0 MPa) after dehydroxylation at temperatures up to 630°C. Cation exchange capacity (CEC) measurements, determination of exchangeable cations and X-ray diffraction (XRD), supplemented by thermoanalytical investigations of the evolved water in a thermobalance linked to a mass spectrometer, infrared (IR) and electron spin resonance (ESR) spectroscopy were employed to obtain information about the state of expandability and structural changes of swellable montmorillonite and the sites of interlayer and octahedral cations after heating and rehydroxylation.The XRD pattern of the initial samples showed a well-defined (001) reflection according to the interlayer cation and its hydration state under laboratory atmosphere. After dehydroxylation the pattern exhibited (001) reflections between 9.6 and 9.8 Å, corresponding to a collapsed structure for all samples. The Na+-, Ca2+- and Sr2+-rich montmorillonites regained partial expandability after rehydroxylation at 200°C and full expandability after rehydroxylation at 300°C if the dehydroxylation temperature was less than 630°C. Rehydroxylation at 300°C of the Cu2+- and Zn2+-rich montmorillonites did not cause reexpansion, whereas the Li+-rich samples recovered a partial swellability after rehydroxylation at 240°C and nearly the full swellability after rehydroxylation at 300°C.The Li+-, Cu2+- and Zn2+-rich samples underwent a strong CEC reduction due to migration of the interlayer cations into the 2:1 layer before dehydroxylation started. After rehydroxylation under water steam Cu2+- and Zn2+-rich samples released 16–30 meq/100 g of Mg2+ from the structure, increasing with the steam temperature. Mg2+ release was not observed for the Li+-rich montmorillonite. 相似文献
139.
Several new eco-friendly materials have the potential to replace conventional petroleum-derived materials and monomers. Among them are natural polysaccharides. The use of polysaccharides in polyurethane (PU) synthesis has not yet been studied extensively, even though as multihydroxyl compounds, they can easily serve as crosslinkers in PU synthesis. One naturally occurring (hyper-)branched polymer is amylopectin, a component of starch. In this work, we report the PU synthesis and film-forming capacity using the asymmetric cyclic aliphatic diisocyanate—isophorone diisocyanate (IPDI) with acetylated and pristine partially hydrolyzed amylopectin/white dextrin (AVEDEX W80) as a crosslinker. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47454. 相似文献
140.
Numerous companies working in the field of membrane development, membrane production, and membrane separation engineering were present at ACHEMA 2022. Compared to the last ACHEMA in 2018, there were fewer attending companies and only few new topics since development has been blocked partially by the pandemic situation and the subsequent restrictions of this years. Nevertheless, some new developments have been identified concerning process design as well as ceramic and polymeric systems. 相似文献