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41.
Degradation and mineralization of two agricultural organic pollutants (Diazinon and Imidacloprid as N-heterocyclic aromatics) in aqueous solution by nanophotocatalysis using immobilized titania nanoparticles were investigated. Insecticides, Diazinon and Imidacloprid, are persistent pollutants in agricultural soil and watercourses. A simple and effective method was developed to immobilization of titania nanoparticles. UV-vis, ion chromatography (IC) and chemical oxygen demand (COD) analyses were employed. The effects of operational parameters such as H(2)O(2) and inorganic anions (NO(3)(-), Cl(-) and SO(4)(2-)) were investigated. The mineralization of Diazinon and Imidacloprid was evaluated by monitoring of the formed inorganic anions. The selected pollutants are effectively degraded following first order kinetics model. Results show that the nanophotocatalysis using immobilized titania nanoparticle is an effective method for treatment Diazinon and Imidacloprid from contaminated water. 相似文献
42.
S. M. Mokhtar 《Polymer International》1997,42(3):335-339
The preparation of graft films was carried out by direct radiation-induced graft polymerization of acrylic acid and vinyl acetate comonomer onto heavy-duty poly(ethylene–vinyl acetate) films. The effect of various comonomer compositions on the degree of grafting was investigated. The characterization and some selected properties of the graft copolymers prepared were studied. Thermal stability, mechanical and electrical properties of the films showed great promise for some practical applications. © of SCI. 相似文献
43.
Samia Ayari Dominic Dussault Mathieu Millette Mokhtar Hamdi Monique Lacroix 《International journal of food microbiology》2009,135(1):1-6
This present study was carried out to evaluate the effects of gamma irradiation on the fatty acids (FA) and mureins composition of two different radiotolerant bacteria. Bacillus cereus LSPQ 2872 and Salmonella Typhi ATCC 19430 were used for this study. The bacterial strains were treated with a sublethal radiation dose of 1 kGy to cause a cellular damage. Gas chromatography (GC) and high performance liquid chromatography (HPLC) analysis were performed to demonstrate respectively the modification of the FA composition and the changes in muropeptide profile. Results obtained show, for both bacteria, that this treatment had a significant effect (P ≤ 0.05) on the FA content with an increase of unsaturated FA percentage. Substantial changes were also noticed for the relative percentage and the number of the muropeptides. This study represents one of the few to demonstrate the modifications on bacterial membrane as a cellular response to survive the ionising radiation stress. 相似文献
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46.
A generalization of the linear fractional integral equation u(t)=u0+∂−αAu(t), 1<α<2, which is written as a Volterra matrix-valued equation when applied as a pixel-by-pixel technique is proposed in this paper for image denoising (restoration, smoothing, etc.). Since the fractional integral equation interpolates a linear parabolic equation and a hyperbolic equation, the solution enjoys intermediate properties. The Volterra equation we propose is well-posed for all t>0, and allows us to handle the diffusion by means of a viscosity parameter instead of introducing nonlinearities in the equation as in the Perona-Malik and alike approaches. Several experiments showing the improvements achieved by our approach are provided. 相似文献
47.
Thanks to advances in the computing capabilities and added functionalities of modern mobile devices, creating and consuming digital media on the move has never been so easy and popular. Most of the DTN routing protocols proposed in the literature to enable content sharing have been exploiting users’ mobility patterns, in order to maximise the delivery probability, while minimising the overall network overhead (e.g., number of message replicas in the system, messages’ path length). Common to all these protocols has been the assumption that devices are willing to participate in the content distribution network; however, because of battery constraints, participation cannot be taken for granted, especially if the very same subset of devices are continuously selected as content carriers, simply because of their mobility properties. Indeed, we demonstrate that state-of-the-art DTN routing protocols distribute load in a highly unfair manner, with detrimental effects on delivery once the assumption of unconditional participation is lifted. To overcome this limitation, we propose a load-balancing mechanism whereby nodes maintain local estimates of network workload, and use them to direct traffic towards the least loaded portion of the network. We implement the mechanism on top of a source-based DTN routing protocol, and demonstrate, by means of simulation using a variety of real mobility traces, that high delivery is now achieved without compromising fairness. 相似文献
48.
Javad Saien Farzaneh Moghaddamnia Mokhtar Mishi 《Korean Journal of Chemical Engineering》2013,30(5):1125-1130
The simultaneous influence of NaCl, KCl and KI salts and well known sodium dodecyl sulfate (SDS) surfactant on the interfacial tension (IFT) of conventionally used chemical system of toluene-water was studied. The concentration range of salts was within (0.010 to 0.075) mol/dm3 and of surfactant within (1.7 to 26.0)×10?5 mol/dm3. SDS adsorption on interface is highly intensified in the presence of salts and IFT can reach to 67.1% of its initial value. Accordingly, the role of ions was investigated and the order of salts effectiveness was revealed as KI?KCl>NaCl. The obtained data, with both effects, were nicely reproduced using an equation of state, based on Gibbs adsorption equation and the Langmuir isotherm. Two relevant important adsorption parameters exhibited reasonable variations. Furthermore, the general revealed linear variation of IFT with a previously defined “effective concentration” indicates the strong influence of the surfactant counterions. 相似文献
49.
Preparation of a biopolymer chitosan‐polypropylene imine (CS‐PPI) as a biocompatible adsorbent and its reactive textile dyes removal potential were performed. Chemical specifications of CS‐PPI were determined using Fourier transform infrared, 1H‐NMR, and 13C‐NMR. The surface morphology of the CS‐PPI surface was characterized by scanning electron microscopy. Results confirmed that the linkages between the NH2 groups of PPI dendrimer and carboxylic groups of modified Chitosan were accomplished chemically. Two textile reactive dyes, reactive black 5 (RB5) and reactive red 198 (RR198), were used as model compounds. A response surface methodology was applied to estimate the simple and combined effects of the operating variables, including pH, dye concentration, time contact, and temperature. Under the optimal values of process parameters, the dye removal performance of 97 and 99% was achieved for RB5 and RR198, respectively. Furthermore, the isotherm and kinetic models of dyes adsorption were performed. Adsorption data represented that both examined dye followed the Langmuir isotherm. The adsorption kinetics of both reactive dyes were satisfied by pseudo‐second order equation. Based on this study, CS‐PPI due to having high adsorption capacity (6250 mg/g for RB5 and 5882.35 mg/g for RR198), biocompatibility and ecofriendly properties might be a suitable adsorbent for removal of reactive dyes from colored solutions. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
50.
Mousa Sadeghi-Kiakhani Mokhtar Arami Kamaladin Gharanjig 《Iranian Polymer Journal》2013,22(12):931-940
In this research, chitosan-poly(propylene)imine dendrimer hybrid (CS-PPI) was applied to wool fabrics; and weight gain and antibacterial properties of the grafted wool fabric by CS-PPI were investigated. A response surface methodology employed for optimization of the important factors such as pH, processing time, and CS-PPI and cross-linking agent (CA) concentrations. The physical properties showed sensible changes regardless of weight gain. The maximum weight gain was obtained when the wool fabrics were treated with pH 5, processing time 24 h, CS-PPI 20 %(owf) and CA 5 % over weight of fiber (owf). Scanning electron microscopy analysis showed the presence of foreign particles determinedly fixed to the surface of the wool fabric. Fourier transform infrared spectroscopy and differential scanning colorimetry revealed the grafting of CS-PPI onto wool fabric by forming novel chemical bonds between the wool and CS-PPI molecules. The treated wool fabrics showed broad-spectrum antimicrobial activity against gram-positive and gram-negative bacteria. Antimicrobial activities of the treated wool by CS-PPI at a concentration of 20 % over weight of fiber (owf) demonstrated 100 % bacterial growth inhibition, which was preserved more than 84 % even after being washed in 12 various conditions repeatedly. The grafted wool fabrics have antibacterial potential due to the antibacterial property of CS-PPI molecules. The mechanism of CS-PPI grafting onto wool fabric using CA was proposed. The findings of this study support the potential production of the new environmentally friendly textile fibers. 相似文献