Purification of 2-mercaptobenzothiazole by solvent extraction

−Purification of 2-mercaptobenzothiazole (91.9% purity) by solvent extraction was studied. The extraction of impurities present in crude 2-MBT (e.g. benzothiazole, sulfides and sulfur containing compounds) was carried out at temperatures between 70-180°C using various solvents and their mixtures of different polarity. The highest purity of 2-MBT, above 99% was obtained using nitrobenzene, toluene and ethanol, even at a concentration of 2-MBT above 50 wt%. Increasing temperature and decreasing concentration of the raw material have a positive influence on the purification process. A comparable efficiency of purification was observed also with mixed solvents, (toluene with ethanol, acetone and aniline) possessing the same polarities. A correlation between the polarity indexes (PI) of mixed solvents and experimentally obtained purity of 2-MBT was found. The highest purity of 2-MBT provides extraction of the raw material with mixed solvents having PI 3.8-4.4.     

Synthesis and properties of chitosan-modified poly(vinyl butyrate)

Modification of chitosan by grafting of vinyl butyrate was carried out in homogeneous phase using potassium persulfate as redox initator and 1.5% acetic acid as solvent. The percent grafting and grafting efficiency were analysed and the high grafting efficiency up to 94% was observed. The effects of reaction variables such as monomer concentration, initiator concentration, temperature and reaction time were investigated. It was observed that the solubility of chitosan was markedly reduced after grafting with vinyl butyrate. The grafted product is insoluble in common organic solvents as well in dilute organic and inorganic acids. Characterization of the graft copolymers were carried out by using Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC) and Scanning Electron Microscopy (SEM) technics. Characteristic signal of carbonyl group was observed at 1,731 cm⁻¹ which belongs to the poly vinyl butyrate segments in the graft copolymer. The melting transition of the chitosan main chain in the copolymer shifted to 124°C from its original value 101°C. In addition to these, we have also studied topology of the graft copolymer and the SEM micrograph showed continuous homogenous matrix which means there is no phase separation.     

融合多头自注意力的问答社区专家推荐算法

专家推荐是在线问答社区的研究热点之一,但现有的算法大多关注用户的静态兴趣和问题信息的匹配,忽视了对用户的动态兴趣表征信息的有效捕捉,从而导致推荐的准确度不足。针对上述问题,提出了融合多头自注意力的问答社区专家推荐算法。首先,构造由卷积神经网络和注意力机制组成的问题编码器,来处理目标问题和用户历史回答问题,提取对应的问题表征;其次,将用户历史回答问题序列当作时间序列,利用多头自注意力机制学习序列中所蕴涵的动态兴趣表征,结合用户的静态兴趣表征,获取用户的综合兴趣表征;最后,将目标问题表征和用户综合表征进行相似性计算产生推荐结果。利用来自知乎问答社区的真实数据进行了不同参数配置及不同算法的对比实验,实验结果表明该算法性能要明显优于目前较流行的深度学习专家推荐算法。     

支持O2O的时空众包激励技术研究

在这个流行元素日新月异的时代,消费者的口味越来越难以把控,商家的判别标准将极大决定店铺的业绩水平.文章介绍了时空众包的概念,研究在商城背景下,利用时空众包思想设计一种能持续有效执行的机制来提高O2O模式的资源利用率问题.     

新工科背景下信息安全专业建设和人才培养模式探索

针对新工科背景下信息安全专业创新型人才需求,对本校网络与信息安全专业建设和人才培养模式进行探索,从能力培养体系、课程体系、实践教学体系、教学模式、考核体系等方面进行改革,制定符合本校特色的专业培养方案,并阐述人才培养模式实践过程中教学、实践、科研方面取得的初步成效.     

智慧农业综合信息服务系统的设计与开发

针对目前市场上大多数农业信息服务平台功能单一的缺点,设计了一款集专家在线答疑、智能识别病虫害、农业知识学习、农友社交服务于一体的系统,旨在帮助农户解决生产过程中的难题,推动农业生产发展.该系统采用前后端分离开发技术,后端使用Spring、SpringMVC、MyBatis框架搭建,前端使用Vue、Ajax技术开发,并采取SIFT算法实现图像匹配.使用结果表明,该软件功能全面,操作简便,能够满足农户基本需求.     

核动力装置BDS系统仿真与事故分析

蒸汽发生器排污系统(BDS)对核动力装置起着关键性作用,不仅影响蒸汽发生器的换热效率,还关系到汽轮机安全.但是通过近几年核动力装置现场工作人员统计,BDS是一个故障发生概率较大的系统.所以现以BDS为研究对象,通过COSINE程序对该系统进行仿真建模,在验证稳态工况基础上,选择事故概率较高的热交换器泄露事故作为瞬态研究目标,分析事故下系统的热工水力现象,以及给出相应的事故解决方案,并对该事故方案进行优化分析,对动力装置操作的分析具有一定的指导意义.     

油气井钻进钻铤进动特性仿真研究

油气井钻进破岩过程发生于地下几千米,难以获取井底钻具组合的运动状态.井底钻具组合与岩石的相互作用产生多种形式的振动及振动的耦合.为进一步研究破岩引发钻进中振动的产生机理,建立了井底钻具组合钻铤段非线性动力学模型,通过数值仿真,分析了破岩过程中转速、钻井液、井底钻具组合偏心距、摩擦等对钻铤段旋转进动的影响.数值研究表明,系统参数的变化导致井底钻具组合进动轨迹的多样性和不可预测性;井底钻具组合受到外力作用,导致钻铤进动出现混沌;钻进过程中钻铤与井壁间会发生周期性碰摩现象,为研究钻进引发钻柱黏滑振动提供新的研究思路.     

软件检验中的六性要求探讨

针对大型复杂软件可靠性低、重大任务运行过程中出现软件故障的问题,从软件的全生命周期角度研究软件可靠性设计方法;从软件可靠性检验、软件维修性检验、软件保障性检验、软件测试性检验、软件安全性检验和软件环境适应性检验等方面探讨软件六性检验方法.针对软件可靠性检验,从软件失效、功能剖面、失效模式和影响度分析、可靠性定义、可靠性模型选择和指标分配,涵盖了软件需求、概要设计、详细设计及测试设计等不同阶段,最后以实例进行验证.     

高性能MCU的FPGA原型验证系统研究与平台实现

本文研究并实现了一种基于Cortex-A7核的高性能MCU在FPGA原型阶段的验证平台。该设计研究可以针对高性能MCU芯片或其FPGA原型验证阶段的软硬件验证环境快速搭建,通过交互式、软硬件协同的方式对MCU芯片各个模块功能进行实时、可靠的功能验证。高效的FPGA原型验证可以提高MCU研发速度、缩短验证时间、提高验证效率、及时发现芯片设计的缺陷、缩短芯片研发周期。