Effect of isothermal aging on the imidization of PMR-15

The imidization of polymerizable reactive mixtures, PMR-15 has been performed in a vacuum oven at isothermal aging temperatures ranging from 65 to 200°C for aging periods of 0.5 to 2.5 h. The weight loss of the resin and chemical changes that occurred as a result of aging were monitored gravimetrically and by FT-IR spectroscopy. Differential scanning calorimetry was used to determine the temperature at which imidization took place. Imidization was observed to commence at 65°C after long aging times, t ≥ 2.5 h and at ∼95°C at a shorter time, t ∼0.5 h. At higher aging temperatures of 135 to 165°C, extensive imidization occurred. This was shown by the dramatic increase in imide absorption bands at 1780 and 1380 cm⁻¹. Beyond 165°C, there were no significant changes in the imide absorption bands, suggesting that imidization was nearly complete. The activation energy for isothermal aging was determined from the slope of the log of the rate of weight loss vs 1/T curve to be ∼4.5 kJ/mol and is lower than the average activation energy for imidization ∼43 kJ/mol obtained from the plot of the log of the rate of increase of the imide carbonyl peak absorption at 1780 cm⁻¹ vs 1/T.     

创新可持续性建筑的消防安全设计

<正>引言"侨福芳草地"(Parkview Green)出于创新可持续性的设计构思,设有一个特殊的玻璃金字塔环保罩,内包含了四座高层建筑,使之既不同于普通的大空间建筑,也不同于一般的建筑群,一旦共享空间发生火灾,烟气可能在环保罩下聚集,给消防设计带来巨大挑战。除环保罩外,与其它建筑不同还有,"芳草地"的首层不是位于街面高度,而是在地下二层,在建筑周围区域形成一个露天的两层下沉广场。而其下沉广场的独     

Temburong Bridge,Brunei – Design of two cable stayed bridges

The Temburong Bridge Project is a 30 km long dual two‐lane highway crossing over the Brunei Bay. It will connect the relatively isolated Brunei district of Temburong to the other three Brunei districts. The main objective of the project is to stimulate economic growth in the Temburong region by connecting it to the country's airport and ports. The alignment crosses two navigation channels resulting in the need for two cable stayed bridges – the Brunei Channel Bridge (145 m main span) and the Eastern Channel Bridge (260 m main span). The design of these cable stayed bridges is one of the first applications of the Eurocode to a fully concrete cable stayed bridge. Both cable stayed bridges draw on strong Islamic architectural influences from the region to form a tower shape that is unique and instantly recognisable. Temburong Brücke, Brunei – Entwurf von zwei Schrägkabelbrücken Die Temburong Brücke ist eine 30 km lange Verbindung über die Brunei Bucht mit zwei Richtungsfahrbahnen mit je zwei Fahrstreifen. Sie wird den relativ isolierten Distrikt Temburong mit den anderen drei Distrikten Bruneis verbinden. Hauptanliegen des Projekts ist die Stimulierung von ökonomischem Wachstum in der Temburong Region, indem sie an den Flughafen und Seehafen des Landes angebunden wird. Die Trassierung erfordert die Überquerung zweier Schiffahrtsrouten. Dies wird mit der Anordnung zweier Schrägkabelbrücken ermöglicht, der Brunei Channel Brücke (145 m Hauptspannweite) und der Eastern Channel Brücke (260 m Hauptspannweite). Die Bemessung der beiden Brücken stellt eine der ersten Anwendungen des Eurocode auf Schrägkabelbrücken mit Betonüberbau dar. Optisch sind die beiden Brücken geprägt von der islamischen Architektur der Umgebung, die Pylonform ist ein besonderes Erkennungsmerkmal der Brücken.     

New trends in rock slope stability analyses

 The paper discusses alternative approaches to stability analyses including the traditional deterministic principle, the so-called partial factor principle and the probabilistic approach which assesses the probability of failure rather than the factor of safety. To illustrate the different principles and approaches, stability analyses of road cuts near Trondheim, central Norway, are used as examples. It is concluded that although the traditional deterministic approach has the advantage of being well established and easy to understand, to conform with new standards and guidelines it is likely to be replaced by the partial factor principle. To obtain the best possible basis for evaluation it is useful to include a probabilistic analysis. Received: 5 August 1999 · 28 August 1999     

Micro-fibre and ultra-micro-fibre cloths, their physical characteristics, cleaning effect, abrasion on surfaces, friction, and wear resistance

The properties of 12 micro-fibre cloths and two ultra-micro-fibre cloths were studied and compared with conventional cleaning methods. The cloths made from micro-fibre and ultra-micro-fibre had very good cleaning effect. Scrubbing Plexiglas caused pitting and scratch marks on the Plexiglas surface with the largest damage being caused in dry condition. All the cloths tested were wear resistant. Most of the cloths showed high friction against the surfaces in damp condition. Micro- and ultra-micro-fibre cloths are good alternatives to conventional methods for cleaning interior surfaces. Furthermore, good cleaning results can be achieved without any use of polluting cleaning chemicals.     

The Fast Prefix Coding Algorithm (FPCA) for 3D Pavement Surface Data Compression

The enormous data inflow during three‐dimensional (3D) pavement surface data collection requires an efficient compression system for 3D data. However, with respect to the phase of lossless encoding, the commonly used Huffman Coding is inefficient in terms of speed and memory usage for encoding 3D pavement surfaces. The Fast Prefix Coding Algorithm (FPCA) is proposed in the article as an effective substitute of Huffman Coding at the stage of lossless encoding. It is demonstrated in the article that the FPCA is much faster and more memory efficient than Huffman Coding, while outperforming Shannon–Fano Coding in terms of both redundancy and time efficiency. The FPCA‐based coding approach is a modification of the baseline JPEG algorithm to support 3D pavement data whose dynamic range is more than 12 bits. The presented modifications include algorithms for Quantization, Run‐Length Encoding and Entropy Coding without limiting data depth in terms of dynamic range. Compared with the baseline JPEG approach, the proposed coding system is able to restrict the data loss more successfully and can achieve a significantly higher level of time efficiency and compression ratio (over than 30:1 for most of the evaluated 3D images). With parallel computing techniques, encoding full‐lane width pavement in 3D and at 1 mm resolution with an up‐to‐date desktop computer can be conducted at 150 MPH or even higher speed.     

The HIV-epidemic among drug addicts in Norway

Up to 1996, 368 persons in Norway (population 4.3 million) had been reported as being HIV-infected because of intravenous drug use. 72 of these had developed AIDS and 59 had died from AIDS. HIV-testing is very common among drug users in Norway and new cases are rarely detected at treatment centres or at autopsy. Some 15-30 cases may still be undiagnosed. HIV spread very rapidly among drug users in Norway in 1984 and 1985, by around 100 new cases per year. Since then, the annual incidence has decreased from 30-40 cases in 1986 to 10-15 in 1995. Although the drug users seldom shared syringes even before the advent of the HIV epidemic, we believe that the public rehabilitation programmes, needle exchange programmes and health information have contributed to control HIV in this group. We expect an annual incidence of 10-15 cases the next five years.