Development of a new advanced process for manufacturing polyacetal resins. Part III. End-capping during polymerization for manufacturing acetal homopolymer and copolymer

Conventionally, acetal homopolymer or copolymer is obtained by the polymerization of formaldehyde or trioxane, following the end-capping using acetic anhydride or unzipping of the unstable polymer end fraction. First, Asahi Chemical developed a new process to obtain an end-capped polymer during polymerization of highly purified formaldehyde using acetic anhydride as the chain-transfer agent. Use of highly purified formaldehyde and endcapping during polymerization using acetic anhydride as a chain-transfer agent or an endcapping agent will provide a simple process for manufacturing acetal homopolymer. The polymerization mechanism was confirmed by infrared spectroscopy analysis and proton NMR analysis of the polymer obtained. Second, for the acetal copolymer, purified trioxane was copolymerized with ethylene oxide in the presence of methylal, which gave an endcapped polymer with high thermal stability. Two new intermediates from the initiation reaction of the copolymerization, 1,3,5,7-tetraoxacyclononane (TOCN) and 1,3,5,7,10-pentaoxacyclododecane (POCD), were isolated and a new initiation mechanism was proposed. © 1993 John Wiley & Sons, Inc.     

The principle and fundamental characteristics of brushless three-phase synchronous induction motor with two stators

Brushless three-phase synchronous motor involving a rotating ac exciter on the same shaft as the motor and with the windings linked through a shaft-mounted rectifier is widely used as medium and large capacity machines. However, the motor needs to fit with damping windings for self-starting outside of the field winding in the rotor and needs to equip discharge resistance with complex electronic device to dispose of electromagnetic force induced in the field winding at starting. Therefore, the rotor structure is very complex, and there are disadvantages, especially for the robust and highly reliable motor that is desired. To solve the problem found in traditional motors, the authors proposed a brushless three-phase synchronous induction motor with two stators and one wound rotor. This problem is solved because the proposed motor is of two-stators structure: the rotor winding operates as a secondary winding of induction motor at starting and as the field winding at synchronous operation. The motor can self-start as a wound-rotor induction motor without external secondary resistance. Therefore, discharge resistance is not necessary; the starting equipment is very simple and the rotor structure is robust. It is possible to start with high torque. In this paper, the basic constitution of the proposed motor and the principles of operation are described in detail. The experimental results at starting and pulling into synchronism are shown for confirming the principles of operation and the experimental and numerical results of the starting characteristics. The load ones and the generating ones are shown and then the practical use of the proposed motor is confirmed.     

Excessive closure of the right eye: a new sign of infarction in the territory of the ipsilateral right middle cerebral artery

In right middle cerebral territory infarction a new sign, excessive closure of the right eye ipsilateral to the lesion and mild closure of the left eye on command, was noted. The excessive ipsilateral eye closure was not observed on spontaneous eye closure.     

A high-speed vector-controlled spindle motor drive with closedtransition between with encoder control and without encoder control

A 40000-r/min vector-controlled induction motor drive is introduced. The vector control of induction motors has been widely accepted in spindle drives of machine tools where they replace conventional DC motors because of the low maintenance requirements. Another important feature of the AC spindle drive is its high-speed capability. The magnetic encoder is most widely used as the speed detector because it is suited for use in an adverse environment. However, the magnetic encoder with high resolution and a high S/N ratio loses the output pulses at extremely high speed. In the drive system introduced, the conventional vector control is used in the low-speed range, and the vector control without the encoder is used in the high-speed range. Close transition between two modes is made without interrupting the operation     

New method for measuring an optical property of a sample treated by FWA

In this article, a new method for measuring a total spectral radiance factor of a FWA‐treated sample illuminated by a specific standard illuminant is introduced. The method replaces an unstable real fluorescent standard by a bi‐spectral luminescent radiance factor data, which works as a virtual fluorescent standard (VFS) by knowing spectral intensity distributions of illuminations applied to the sample. The method utilizes two illuminations I₁ and I₂ whose relative spectral intensity distributions are different from each other and synthesizes a virtual illumination presenting the identical fluorescent spectral radiance factor to that presented by the standard illuminant with the VFS of the specific bi‐spectral luminescent radiance factor by linearly combining I₁ and I₂ with the suitable weighting factors. The applicability of the method is examined in principle by comparing ISO brightness and CIE whiteness index of fluorescent standard paper as a test sample obtained by this new method to the assigned values. © 2007 Wiley Periodicals, Inc. Col Res Appl, 32, 195–200, 2007     

Sub-50-nm physical gate length CMOS technology and beyond usingsteep halo

Sub-50-nm CMOS devices are investigated using steep halo and shallow source/drain extensions. By using a high-ramp-rate spike annealing (HRR-SA) process and high-dose halo, 45-nm CMOS devices are fabricated with drive currents of 650 and 300 μA/μm for an off current of less than 10 nA/μm at 1.2 V with T_ox^inv =2.5 nm. For an off current less than 300 nA/μm, 33-nm pMOSFETs have a high drive current of 400 uA/μm. Short-channel effect and reverse short-channel effect are suppressed simultaneously by using the HRR-SA process to activate a source/drain extension (SDE) after forming a deep source/drain (S/D). This process sequence is defined as a reverse-order S/D (R-S/D) formation. By using this formation, 24-nm nMOSFETs are achieved with a high drive current of 800 μA/μm for an off current of less than 300 μA/μm at 1.2 V. This high drive current might be a result of a steep halo structure reducing the spreading resistance of source/drain extensions     

Surface characterization and catalytic properties of La1−x -Sr x CoO3

The surface chemical states of the perovskite-type compounds, strontium doped lanthanum cobalt oxides (La_1?x Sr _x CoO₃), have been investigated using X-ray photoelectron spectroscopy (XPS). Catalytic oxidations of both methane and CO have also been investigated using flow methods. The chemical composition of the surface of La_1?x Sr _x CoO₃ was very different from that in the bulk, which was measured by X-ray fluorescence spectroscopy (XRFS). The catalytic activity of La_1?x Sr _x CoO₃ increased with an increase in the quantity of cobalt atoms on the surface.     

Cerebral angioplasty in a patient with vascular dementia

A mechanical computerized three-dimensional scanner with a resolution of 1 micron was used to assess loss of enamel caused by orthodontic bonding and debonding. A total of 2646 measurements was performed on six human premolars. The results showed an average loss of enamel of 7.4 microns. The range was between 1 and 52 microns, which may account for discrepancies with earlier studies that measured only a few points per tooth surface.     

Design optimization of tall tubular lead/acid cells based on an analysis of the reaction distribution

In order to estimate the discharge performance of tall lead/acid cells (with tubular positives), changes in current and potential distributions with discharge progress were calculated with a computer on the basis of plate resistance and the current—potential—time relationship between small facing parts of positive and negative plates. The taller the cell, the larger the voltage drop along the plates. Thus, the discharge time became shorter despite a large amount of available active mass remaining in the bottom part of the plates.Various current-collector designs were evaluated, e.g., one with varying resistance at each height; a side conductor placed along the plates and connected to them at the top, centre and bottom, etc. Results revealed an optimum collector design with which the maximum discharge capacity could be obtained. Furthermore, it was shown that the side conductor markedly improved the discharge performance because the active mass near the connecting parts was appreciably used.     

XIII. Yeast sequencing reports. Cloning and sequencing of the NES24 gene of Saccharomyces cerevisiae

We have cloned NES24 using a temperature-sensitive nes24-1 mutant as a host and sequenced a 3162 bp XhoI-EcoRI DNA fragment containing the NES24 gene. Computer analysis revealed that this segment contains a 1806 bp open reading frame which is needed for complementation of the nes24-1 mutation. We found SUP8 in the region upstream of the NES24 gene, placing the NES24 gene on chromosome XIII. A protein homology search indicated that NES24 encodes a new protein. The disruption of the NES24 gene resulted in temperature-sensitive growth. The sequence has been deposited in DDBJ/EmBL/GenBank data bases under Accession Number D15052.