Synthesis of graphene-supported bimetallic nanoparticles for the sunlight photodegradation of Basic Green 5 dye in aqueous medium

Graphene nanosheets-supported Sn-Pt bimetallic nanoparticles (GNs/Sn-Pt) were prepared by precipitation method. The obtained GNs/Sn-Pt was used as a photocatalyst for photodegradation of Basic Green 5 (BG5) in aqueous solution under sunlight. The morphology and photodegradation study was performed by SEM and UV–VIS spectrophotometry, respectively. The SEM image showed the presence of Sn and Pt on GNs, being confirmed by energy dispersive X-ray (EDX) analysis. The photodegradation study of BG5 showed that the dye degradation increases as a function of irradiation time. The degradation of BG5 was found to be pH dependent and maximum degradation was found at higher pH.     

Synthesis of Ferrocene-Based Hyperbranched Polyether and Its Catalytic Performance for Thermal Decomposition of Ammonium Perchlorate

A series of ferrocene-based hyperbranched polyethers (HBPE-Fc) with different ferrocene content were synthesized by esterification of ferrocenecarbonyl chloride and hyperbranched polyether (HBPE). ¹H NMR and FT-IR were used to confirm the structure of HBPE and HBPE-Fc. GPC was used to calculate the molecular weights. The catalytic performance of the synthesized HBPE-Fc for thermal decomposition of ammonium perchlorate (AP) was investigated by TG and DTG techniques. The results showed that HBPE-Fc exhibited good catalytic activity on the thermal decomposition of AP. The influence factors on catalytic performances, such as substitution degree of ferrocene and mass ratio of AP/HBPE-Fc were discussed as well.     

Advances in reduction of NOx and N2O1 emission formation in an oxy-fired fluidized bed boiler

Fossil fuel combustion is one of the major means to meet the mounting global energy demand. However, the increasing NO_x and N₂O emissions arising from fossil fuel combustion process have hazardous effects. Thus, mitigating these gases is vital to attain a sustainable environment. Interestingly, oxy-fuel combustion in fluidized bed for carbon capture and minimized NO_x emissions is strongly sustainable compare to the other approaches. It was assessed that NO_x formation and fuel-N conversion have significant limitation under oxy-fluidized bed compared to air mode and the mechanism of NO_x formation is still deficient and requires further development. In addition, this review paper discussed the potential of primary measure as low emission process with others supplementary techniques for feasible NO_x reduction. The influences of combustion mode, operating parameters, and reduction techniques such as flue gas recirculation, oxygen staging, biomass co-firing, catalyst, influence of fluidized bed design and structure, decoupling combustion and their merges are respectively evaluated. Findings show that significant minimization of NO_x emission can be achieved through combination of primary and secondary reduction techniques.     

Biosynthesis of reusable and recyclable CuO@Magnetite@Hen Bone NCs and its antioxidant and antibacterial activities: a highly stable magnetically nanocatalyst for excellent reduction of organic dyes and adsorption of polycyclic aromatic hydrocarbons

For the first time, through a fast, eco‐friendly and economic method, the aqueous extract of the leaf of Euphorbia corollate was used to the green synthesis of the highly stable CuO@Magnetite@Hen Bone nanocomposites (NCs) as a potent antioxidant and antibacterial agent against Pseudomonas aureus, Staphylococcus aureus, Escherichia coli and Klebsiella pneumoniae pathogenic bacteria. The biosynthesised NCs were identified using the scanning electron microscopy (SEM), energy dispersive X‐ray spectroscopy, elemental mapping, X‐ray diffraction (XRD), Fourier transforms infrared spectroscopy and UV–vis analytical techniques. Also, the radical scavenging activity using (2,2‐diphenyl‐1‐picrylhydrazyl) method was used to evaluate the antioxidant activity of the NCs. The stability of nanocatalyst was monitored using the XRD and SEM analyses after 30 days from its synthesis. Furthermore, its excellent catalytic activity, recycling stability, and high substrate applicability were demonstrated to the adsorption of the polycyclic aromatic hydrocarbons of the light crude oil from Shiwashok oil fields and destruction of methylene blue and methyl orange as harmful organic dyes at ambient temperature using UV–vis spectroscopy. Moreover, the green CuO@Magnetite@Hen Bone NCs were recovered and reused several times without considerable loss of its catalytic activity.Inspec keywords: nanobiotechnology, X‐ray diffraction, infrared spectra, catalysis, crude oil, Fourier transform spectra, ultraviolet spectra, scanning electron microscopy, dyes, catalysts, photochemistry, iron compounds, X‐ray chemical analysis, antibacterial activity, adsorption, visible spectra, microorganisms, organic compounds, reduction (chemical), nanomedicine, toxicology, recycling, chemical industryOther keywords: antioxidant activity, XRD, SEM analyses, recycling stability, polycyclic aromatic hydrocarbons, harmful organic dyes, UV–vis spectroscopy, green CuO@Magnetite@Hen Bone NCs, reusable CuO@Magnetite@Hen Bone NCs, recyclable CuO@Magnetite@Hen Bone NCs, antioxidant activities, antibacterial activities, highly stable magnetically nanocatalyst, eco‐friendly method, economic method, euphorbia corollate, green synthesis, CuO@Magnetite@Hen Bone nanocomposites, antibacterial agent, pseudomonas aureus, staphylococcus aureus, escherichia coli, klebsiella pneumoniae pathogenic bacteria, biosynthesised NCs, X‐ray spectroscopy, X‐ray diffraction, radical scavenging activity, antioxidant agent, 2,2‐diphenyl‐1‐picrylhydrazyl, catalytic activity, organic dye reduction, light crude oil, CuO     

Feedback spreading control laws for semilinear distributed parameter systems

The paper shows, for the first time that a feedback spreading control law for semilinear distributed parameter systems with compact linear operator can be provided by a selection procedure which involves both the dynamics of the system and the property to be spread. In the case of affine dependence upon the control a minimum energy feedback spreading control law will be derived by using a parametrized constrained optimization technique along with some facts of set-valued analysis.     

Scalable Schemes for Call Admission and Handover in Cellular Networks with Multiple Services

The introduction of new service categories withdifferent bandwidth requirements, e.g., data and multimedia, to cellularmobile radio networks makes many of the traditional mechanisms for controlingtraffic unusable orless efficient. The call admission and the handover handling are of the mostsensitive issues in this extension to new services. The performance of allservices includingthe traditional voice and the new services can be dramatically affected ifappropriate schemes are not used. In this paper, we propose call admission andhandover handling schemes for a cellular mobile network that offers twoservice types: voice and data. The data connections are assumed to transmitatdifferent transmission rates that are integer multiples to that of one radiochannel. In the case of congestion, the base station asks the active dataconnections to reduce their transmission rate in order to provide freechannels for the newly arrived request of both service types. This isbasically intended for incoming handover requests. The request will berejected if the transmission rate of the active connections reaches a givenminimum rate. Similar mechanism can also be used for new call arrivals, butsome priority can be given to handovers by setting a higher transmission ratethreshold for the new call rejection. As an extension to the proposedscalability, aqueuing of new calls is also proposed and analyzed. Analytical models werebuilt for the two proposed schemes together with the traditional channelreservation scheme. The effect of different traffic and configurationparameters on the performance measures like the grade of service, blockingprobabilities, and utilization, are studied using the proposed technique.Results show that the proposed schemes provide very good performance and morefairness among the different service types.     

Fast computation of accurate Zernike moments

Zernike polynomials are continuous orthogonal polynomials defined in polar coordinates over a unit disk. Zernike moment’s computation using conventional methods produced two types of errors namely approximation and geometrical. Approximation errors are removed by using exact Zernike moments. Geometrical errors are minimized through a proper mapping of the image. Exact Zernike moments are expressed as a combination of exact radial moments, where exact values of radial moments are computed by mathematical integration of the monomial polynomials over digital image pixels. A fast algorithm is proposed to accelerate the moment’s computations. A comparison with other conventional methods is performed. The obtained results explain the superiority of the proposed method.     

STOPE‐based approach for e‐readiness assessment case studies

The STOPE‐based approach is used here for practical e‐readiness assessment case studies. The approach integrates and evaluates the various e‐readiness assessment issues, over its well‐structured domains: strategy, technology, organization, people, and environment. The case studies considered concern three Saudi organizations: a government organization, a bank, and a private sector company. The results obtained provide e‐readiness indicators that illustrate the strengths and weaknesses of each organization with regard to e‐readiness strategic development issues, information and communication technology (ICT) issues, management and organization issues, people issues, and environment issues within which the organization operates. The work shows how the approach can be practically used, and it also provides practical results that direct the organizations concerned toward enhancing their e‐readiness in response to the current trend of globalizing e‐business. Copyright © 2007 John Wiley & Sons, Ltd.     

Potentiality of daylighting in a maritime desert climate: the Eastern coast of Saudi Arabia

Energy savings from the utilization of daylight will be influenced by the amount of external daylight incident on the external surface of the window plane. Therefore, savings from daylight will vary from a place to another, based on the prevailing sky conditions in the climate concerned. This paper aims to investigate the potentiality of natural light if used a source of internal illuminance in buildings in the Eastern coast of Saudi Arabia. This includes providing information about daylight performance in the area.     

Controllability of buildings: A multi-input multi-output stability assessment method for buildings with slow acting heating systems

The paper describes a methodology to assess the controllability of a building and its servicing systems, such as heating, lighting and ventilation. The knowledge for these methods has been transferred from design processes and methods used in the design of aircraft flight control systems to establish a modelling and design process for assessing the controllability of buildings. The paper describes a holistic approach to the modelling of the nonlinear and linear dynamics of the integrated building and its systems. This model is used to analyse the controllability of the building using Nonlinear Inverse Dynamics controller design methods used in the aerospace and robotics industry. The results show that this design approach can help the architects in their decisions on which building design and services to use. Furthermore, the results demonstrate how the same method can assist the control systems designer in developing complex control systems especially for buildings designed with a climate adaptive building (CAB) philosophy.