Elemental sulfur‐based polymeric materials: Synthesis and characterization

New elemental sulfur‐based polymeric materials called poly(sulfur‐random‐divinylbenzene) [poly(S‐r‐DVB)] were synthesized by ring opening polymerization via inverse vulcanization technique in the presence of a mixture of o‐, m‐, and p‐diviniylbenzene (DVB) as a cross‐linker. A clear yellow/orange colored liquid was obtained from the elemental sulfur melted at 160 °C and then by adding various amounts of DVB to this liquid directly via a syringe at 200 °C viscous reddish brown polymeric materials were obtained. The copolymers are soluble in common solvents like tetrahydrofuran, dichloromethane, and chloroform, and they can be coated on any surface as a thin film by a spray coating technique. The characterization of the materials was performed by using nuclear magnetic resonance, fourier transform infrared, and Raman spectroscopies. The morphological properties were monitored via scanning electron microscope technique. Thermal analysis showed that an increase in the amount of DVB in the copolymers resulted in an increase in the thermal decomposition temperature. On the other hand, poly(S‐r‐DVB) copolymers exhibited good percent transmittance as 50% T between 1500 and 13,000 nm in electromagnetic radiation spectrum, which makes them good candidates to be amenable use in military and surveillance cameras. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43655.     

Purification of silicon powder by the formation of thin porous layer followed by photo-thermal annealing

ABSTRACT: Porous silicon has been prepared using a vapor-etching based technique on a commercial silicon powder. Strong visible emission was observed in all samples. Obtained silicon powder with a thin porous layer at the surface was subjected to a photo-thermal annealing at different temperatures under oxygen atmosphere followed by a chemical treatment. Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) results indicate that silicon purity is im-proved from 99.1 to 99.994 % after annealing at 900 degreesC.     

Poly(2-aminobiphenyl), preparation,characterization, mechanism,and kinetics of the electropolymerization process

Electropolymerization of 2-aminobiphenyl was carried out on glassy carbon, gold, and platinum electrodes, in aqueous–organic solvent mixtures, using a potentiodynamic technique. The choice of organic solvent strongly influences the film formation. In a mixture of 60% acetonitrile and 40% 1.0M HClO₄, stable films were obtained. The poly(2-aminobiphenyl) films were characterized with cyclic voltammetry, where the electrochemical activity of the formed polymer films was investigated in acidic and neutral aqueous solutions containing perchlorates or in potassium ferrocyanide. The prepared films posses a remarkable stability in acidic aqueous solutions and are also stable in some organic solvents. The stability of the polymer films depends on the pH of the solution, and the mechanism of the polymerization process involves deprotonation and head-to-tail coupling of oxidized monomers with its oligomeric radical cations. The kinetics of the electropolymerization process was investigated by determining the charge consumed during the electropolymerization as a function of time at different concentrations of the electrolyte components. The electropolymerization process follows first-order kinetics with respect to the monomer and negative order with respect to HClO₄. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Accurate automatic analysis of cardiac cine images

Acquisition of noncontrast agent cine cardiac magnetic resonance (CMR) gated images through the cardiac cycle is, at present, a well-established part of examining cardiac global function. However, regional quantification is less well established. We propose a new automated framework for analyzing the wall thickness and thickening function on these images that consists of three main steps. First, inner and outer wall borders are segmented from their surrounding tissues with a geometric deformable model guided by a special stochastic speed relationship. The latter accounts for Markov-Gibbs shape and appearance models of the object-of-interest and its background. In the second step, point-to-point correspondences between the inner and outer borders are found by solving the Laplace equation and provide initial estimates of the local wall thickness and the thickening function index. Finally, the effects of the segmentation error is reduced and a continuity analysis of the LV wall thickening is performed through iterative energy minimization using a generalized Gauss-Markov random field (GGMRF) image model. The framework was evaluated on 26 datasets from clinical cine CMR images that have been collected from patients with eleven independent studies, with chronic ischemic heart disease and heart damage. The performance evaluation of the proposed segmentation approach, based on the receiver operating characteristic (ROC) and Dice similarity coefficients (DSC) between manually drawn and automatically segmented contours, confirmed a high robustness and accuracy of the proposed segmentation approach. Furthermore, the Bland-Altman plot is used to assess the limit of agreement of our measurements of the global function parameters compared to the ground truth. Importantly, comparative results on the publicly available database (MICCAI 2009 Cardiac MR Left Ventricle Segmentation) demonstrated a superior performance of the proposed segmentation approach over published methods.     

Purification of metallurgical-grade silicon powder via chemical attack by hydrofluoric and nitric acids followed by thermal treatment

We investigated a novel process for purifying metallurgical-grade silicon (MG-Si). MG-Si powder was first treated to form a thin porous silicon layer. This was heated at 900 °C under oxygen to weaken impurity–Si bonds. Samples were then chemically etched with dilute aqueous hydrofluoric acid. To understand the mechanisms in this purification process, structural, chemical composition and optical properties of MG-Si powder before and after treatment were characterized using Fourier-transform infrared (FTIR), inductively coupled plasma-atomic emission (ICP-AES), and photoluminescence (PL) spectroscopy techniques. FTIR studies of treated MG-Si powder revealed the formation of a thin porous silicon layer on the top surface, as evidenced by SiH_x vibration peaks. PL spectra show that 30-min HF etching of MG-Si led to an increase in red emission, indicating the formation of porous silicon and suggesting a decrease in impurities. ICP-AES revealed that the process led to significant decreases in the concentrations of 15 different elemental impurities.     

A novel hardware/software embedded system based on automatic censored target detection for radar systems

This paper presents a practical design exploration for a new application related to real-time, high-resolution target detection for radar systems. In this paper, an embedded architecture that combines the hardware and software components in a single platform is experienced using a field programmable gate array FPGA-based PC-board. The detection process utilises three techniques: namely, automatic censored ordered statistics detection (ACOSD), cell averaging (CA) and ordered statistics (OS) CFAR techniques, all of which operate in parallel to increase the accuracy of the detection and to reduce the false-alarm rate for both homogeneous and non-homogeneous environments. A prototype of the embedded system detector has been implemented for homogeneous and non-homogeneous environments on Stratix IV FPGA Board. The prototype operates at 200 MHz and performs real-time target detection with an execution delay of 0.27 μs, which is less than the critical time (0.5 μs) for high-resolution detection.     

Date-palm fibers media filters as a potential technology for tertiary domestic wastewater treatment

A number of municipal wastewater treatment systems were developed to improve effluent water quality, however economic aspects should be considered. This study was thus carried out to investigate the application of date-palm fibers filtration as an efficient method to economically remove turbidity, phosphorus, organics in term of COD and helminth eggs of secondary domestic wastewater from an activated sludge treatment process. Column experiments were investigated to study the efficiency of date-palm fibers filters media used in this work for the removal of targeted matter under operational conditions (flow rate, filter depth, and diameter of the fibers). The results indicate that diameter of the fibers had the most significant factor affecting the removal of targeted matter. Pilot test results indicated that date-palm fibers filtration removed up to 54.9% of turbidity, 80.6% of COD, 57.7% of phosphorus and 98% of helminth eggs. Definitely, it could be concluded that the date-palm fibers could offer an appreciable economic and environmental potential, which should be in a position to effectively contribute to the valorisation of such as date-palm by-products for domestic or industrial wastewater treatment in southern of Tunisia.     

Angiotensin converting enzyme‐inhibitory activity and antimicrobial effect of fermented camel milk (Camelus dromedarius)

This study aimed to determine the angiotensin converting enzyme‐inhibitory activity and antimicrobial effect of fermented camel milk. Samples were prepared either using Lactobacillus acidophilus and Streptococcus thermophilus or Lactobacillus helveticus and Str. thermophilus and labelled as S1 and S2, respectively. The IC₅₀ values of S1 and S2 samples ranged between 113–200 and 70–133 μg/mL, respectively. The antimicrobial effects of S1 and S2 samples against Bacillus cereus, Salmonella Typhimurium and Staphylococcus aureus were apparent after 12 h of incubation and continued until 15 days of storage, whereas unfermented camel milk exhibited no antimicrobial effects against any of the tested pathogens.     

On Special Curves According to Darboux Frame in the Three Dimensional Lorentz Space

In the light of great importance of curves and their frames in many different branches of science, especially differential geometry as well as geometric properties and the uses in various fields, we are interested here to study a special kind of curves called Smarandache curves in Lorentz 3-space. Then, we present some characterizations for these curves and calculate their Darboux invariants. Moreover, we classify TP, TU, PU and TPU-Smarandache curves of a spacelike curve according to the causal character of the vector, curve and surface used in the study. Besides, we give some of differential geometric properties and important relations between that curves. Finally, to demonstrate our theoretical results a computational example is given with graph.