The Interplay of Growth Mechanism and Properties of ZnO Nanostructures for Different Applications (Small 44/2023)

This review provides a background on the structure and properties of ZnO nanostructures. ZnO nanostructures are advantageous for many applications in sensing, photocatalysis, functional textiles, and cosmetic industries, which are described in this review. Previous work using UV Visible (UV–vis) spectroscopy and scanning electron microscopy (SEM) for ZnO nanorod growth analysis in-solution and on a substrate for determination of optical properties and morphology is discussed, as well as their results in determining the kinetics and growth mechanisms. From this literature review, it is understood that the synthesis process greatly affects nanostructures and properties; and hence, their applications. In addition, in this review, the mechanism of ZnO nanostructure growth is unveiled, and it is shown that by having greater control over their morphology and size through such mechanistic understanding, the above-mentioned applications can be affected. The contradictions and gaps in knowledge are summarized in order to highlight the variations in results, followed by suggestions for how to answer these gaps and future outlooks for ZnO nanostructure research.     

Inertial Microfluidics with Integrated Vortex Generators Using Liquid Metal Droplets as Fugitive Ink

This work demonstrates a simple method for fabricating nearly spherical dome structures on top of lithographically defined microfluidic channels using gallium‐based liquid metal droplets as fugitive ink. The droplets remain stable during the pouring and curing of polydimethylsiloxane and can be easily removed by applying a basic solution. This facilitates the formation of domes with diameters of a few hundred micrometers patterned on the desired locations of the channel. The expansion of the channel at the interface of the dome leads to formation of a large vortex inside the dome. Experiments using high‐speed imaging along with numerical simulations show the utility of the vortex‐induced flow rotation for orbiting of human monocytes and polystyrene microbeads inside the dome. The lateral displacement of liquids caused by the vortex is further utilized for creating controllable multiband flow/color profiles within a T‐mixer. The method enables the fabrication of customized, complex, and 3D microfluidic systems utilizing planar microfabricated structures.     

An experimental study on the effects of temperature and asphaltene content on the rheological behavior of vacuum residues

In this study, the rheological behavior of five types of Iranian vacuum residues (VRs) containing different values of asphaltene content is investigated under the effects of a wide range of temperature and shear rate. Rheological tests showed that the asphaltene content of VRs plays an important role on the viscosity of these fluids. The samples with higher content of asphaltene have higher values of viscosity and also higher yield point. The Bingham plastic and Herschel–Bulkley models were successfully used to model the rheology and yield behavior of VR samples at a wide range of shear rate and temperature.     

Automated Folding of Origami Lattices: From Nanopatterned Sheets to Stiff Meta-Biomaterials

Folding nanopatterned flat sheets into complex 3D structures enables the fabrication of meta-biomaterials that combine a rationally designed 3D architecture with nanoscale surface features. Self-folding is an attractive approach for realizing such materials. However, self-folded lattices are generally too compliant as there is an inherent competition between ease-of-folding requirements and final load-bearing characteristics. Inspired by sheet metal forming, an alternative route is proposed for the fabrication of origamilattices. This ‘automated-folding’ approach allows for the introduction of sharp folds into thick metal sheets, thereby enhancing their stiffness. The first time realization of automatically folded origami lattices with bone-mimicking mechanical properties is demonstrated. The proposed approach is highly scalable given that the unit cells making up the meta-biomaterial can be arbitrarily large in number and small in dimensions. To demonstrate the scalability and versatility of the proposed approach, it is fabricated origamilattices with > 100 unit cells, lattices with unit cells as small as 1.25 mm, and auxetic lattices. The nanopatterned the surface of the sheets prior to folding. Protected by a thin coating layer, these nanoscale features remained intact during the folding process. It is found that the nanopatterned folded specimens exhibits significantly increased mineralization as compared to their non-patterned counterparts.     

Longitudinal Legendre polynomial expansion of electromagnetic fields for analysis of arbitrary-shaped gratings

The Legendre polynomial expansion method (LPEM), which has been successfully applied to homogenous and longitudinally inhomogeneous gratings [J. Opt. Soc. Am. B24, 2676 (2007)], is now generalized for the efficient analysis of arbitrary-shaped surface relief gratings. The modulated region is cut into a few sufficiently thin arbitrary-shaped subgratings of equal spatial period, where electromagnetic field dependence is now smooth enough to be approximated by keeping fewer Legendre basis functions. The R-matrix propagation algorithm is then employed to match the Legendre polynomial expansions of the transverse electric and magnetic fields across the upper and lower interfaces of every slice. The proposed strategy then enhances the overall computational efficiency, reduces the required memory size, and permits the efficient study of arbitrary-shaped gratings. Here the rigorous approach is followed, and analytical formulas of the involved matrices are given.     

Storing water in powder form by self-assembling hydrophobic silica nanoparticles

Water-rich powder containing up to 98% (by weight) of water and characterized by the same flow properties as dry powder was prepared by a simple mixing process. Each particulate consists of a microscopic water droplet surrounded by a network of self-associated hydrophobic fumed silica particles. The cohesion of the silica network, attributed to the van der Waals interactions, is reinforced by particle entanglements and is probably further enhanced by the fractal structure of the network. Once the network is created, the formed shells are strong enough to withstand gravity forces and external stresses. High hydrophobicity and micrometer-sized thickness of the shells ensure that the water phase is kept within the boundaries of the particulates, thus preventing water droplet coalescence. The conditions leading to the formation of water-rich powders strongly depend on the silica particle hydrophobicity.     

A new experimental investigation on upgrading of waxy crude oils by methacrylate polymers

Several methods have been used to reduce problems caused by wax precipitation during the production and/or transportation of waxy crude oil. Polymers are used to improve pour point and rheological behavior of waxy crude oils. In this work, the influence of the polymer inhibitors such as methacrylate polymers, as wax inhibitor, with different range of molecular weight and alkyl side chain carbons on the rheological behavior and pour point of two Iranian waxy crude oils were evaluated. Two Iranian waxy crude oils were selected on the basis of wax and asphaltene contents. The rheological behavior of these crude oils in absence and in presence of methacrylate polymer was studied. The rheological data cover the temperature range of–1 to 12°C. The results indicated that the performance of methacrylate polymer was dependent on the molecular weight, alkyl side chain carbons and the asphaltene content of crude oil. Methacrylate polymers with longer alkyl side chains than 18 carbons would perform best as wax inhibitors in two cases. Also, for crude oil with low asphaltene, higher molecular weight methacrylate polymer is the best flow improver and lower molecular weight methacrylate polymer showed good efficiency for crude oil with high asphaltene content.     

Electrochemical Insight into the Role of H2O2 in Galvanostatic Passivation of AISI 316L Austenitic Stainless Steel in Citric Acid Electrolyte

Metallurgical and Materials Transactions A - In this study, AISI 316L stainless steel was passivated under galvanostatic conditions in citric acid solutions in the absence and presence of hydrogen...     

A novel technique for residence time distribution (RTD) measurements in solids unit operations

This work presents a novel technique with fast response for Residence Time Distribution (RTD) measurements in gas-solid unit operations (e.g., fluidized bed reactors). This technique is based on an optical method which eliminates the requirement of knowing the velocity and concentration profiles at the exit section of the system. Experiments were carried out with SiC particles and a phosphorescent pigment used as a tracer. A concentration measurement system was developed to measure the tracer concentration in SiC/pigment mixtures. The corresponding pigment concentrations were evaluated at the bottom of this system using a photomultiplier. The pigment concentration was derived from the integral of the signal intensity received by the photomultiplier. Then, a calibration curve was established which provided the empirical relationship between the integral and pigment concentration. In order to validate this RTD measurement technique, a series of experiments was performed in a bubbling fluidized bed and the effect of the bed height was studied. It was shown that the experimental RTD curves were in good agreement with the theoretical RTD of bubbling fluidized beds. This solids RTD measurement technique can be used to provide a better understanding of the hydrodynamics of complex solids unit operations.