ESTIMATION OF IRREDUCIBLE WATER SATURATION AND EFFECTIVE PORE SIZE OF MUDSTONES

A theoretical consideration of immobile water saturation in mudstone is made by means of a capillary model of a porous medium using the air and water absolute permeabilities of a sample. The calculated values of immobile water saturation of the Tertiary mudstones from Japan tend to support a generally-accepted concept; virtually all the water in mudstones is irreducible. Immobile or irreducible water saturation increases gradually with decrease of porosity of mudstones; 15% porosity is a critical value beyond which mudstones contain 100% immobile water in the pores.
Pore sizes of the mudstones estimated by the same model are considerably greater than those estimated by Welte (1972), and are more comparable with Momper's (1978) atypical pore size range of mudstone. The result of analysis indicates that radius of principal pores of the mudstones, which are effective on fluid flow, ranges from about 0.1–0.5 μm. The result thus suggests that even relatively large hydrocarbon molecules can effectively pass through the rock.     

Seismic proof test of a reinforced concrete containment vessel (RCCV): Part 3. Evaluation of seismic safety margin

In Japan, the Nuclear Power Engineering Corporation (NUPEC), sponsored by the Ministry of Economy, Trade and Industry (METI), had conducted a series of seismic reliability proving tests using full-scale or close to full-scale models to simulate an actual important equipment that is critical for seismic safety of nuclear power plants. The tests are intended to validate the seismic design and reliability with a sufficient margin even under destructive earthquakes. A series of tests was carried out on a reinforced concrete containment vessel (RCCV) for advanced boiling water reactor (ABWR) from 1992 to 1999. A large-scale high-performance shaking table at Tadotsu Engineering Laboratory, was used for this test. The test model and the results of pressure and leak tests are described in Part 1. Test procedures, input waves and the results of verification tests such as changes of stiffness, characteristic frequency and damping ratio, the failure of the model and the load–deformation relationship are described in Part 2. Part 3 reports the seismic design safety margin that was evaluated from the energy input during the failure test to a design basis earthquake. Part 4 will report simulation analysis results by a stick model with lumped masses.     

Effect of pre-nitridation treatment on the formation of anatase TiO2 films by anodization

High performance-anatase TiO₂ films were successfully formed on metallic titanium by anodization in an acidic electrolyte composed of H₂SO₄, H₃PO₄ and H₂O₂ subsequent to pre-nitridation treatment. The pre-nitridation treatment was carried out by pre-annealing metallic titanium under a nitrogen atmosphere of 0.1 MPa. The anodized films showed photocatalytic activity in photooxidization of the iodide anion into the tri-iodide anion. The nitridation treatment had a significant effect not only on the formation of anatase TiO₂ films but also on the photocatalytic activity of the anodized films.     

The effects of Li salts on the performance of a polymer actuator based on single-walled carbon nanotube-ionic liquid gel

The effects of Li salts (Lithium tetrafluoroborate (Li[BF₄]) and Lithium bis(trifluoromethanesulfonyl)imide (Li[TFSI])) on the electrochemical and electromechanical properties of an actuator using a polymer-supported single-walled carbon nanotube (SWCNT)-ionic liquid (IL) gel electrode were investigated. The ionic conductivities of the gel electrolyte layers with molar ratios of Li[BF₄]/1-ethlyl-3-methylimidazolium tetrafluoroborate (EMI[BF₄]) = 0.1 and 0.5, and Li[TFSI]/1-ethlyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide (EMI[TFSI]) = 0.1 and 0.3 were higher than those containing only EMI[BF₄] and only EMI[TFSI], respectively. We found a large capacitance value 65-96 F/g at a slow sweep rate 1 mV s⁻¹. The actuator containing Li salt/IL performed much better than that containing only IL. It is considered that the higher ionic conductivity of the gel electrolyte layer containing Li salt/IL produces the quick response actuator, and that the large capacitance gives a large generated strain.     

Polymeric reaction of polymer-monomer system irradiated by low energy electron beam. III. Adhesive property of pressure sensitive adhesive

Application of low-energy electron beam to nonsolvent-type pressure-sensitive adhesive is investigated. Adhesive properties such as peel strength, dead load strength, and ball tack were closely related to the reaction behavior (gel fraction and graft efficiency) of the acrylate polymer-monomer system. The reaction behavior is eluciadated by combining the measurements of gel fraction, infrared spectrum of gel, and molecular weight distribution detected by gel permeation chromatogrophy. It was found that the adhesive property of electro beamcured adhesives depends on the molecular weight of added polymer, monomer concentration, and irradiation dose. Graft polymerization and moderate crosslinking by electron beam irradiation especially contribute to superior high adhesive properties.     

Dynamic fracture analysis of a transverse wedge-loaded compact specimen

The J-integral method cannot be applied to the elastic plastic dynamic crack propagation, because unloading and inertia force may take place. From this point of view dynamic elastic plastic scheme using J-integral is developed.Using this dynamic finite element program an MRL type specimen is analyzed. As the result, the property of path-independence of the J-integral under the existence of inertia force and unloading is confirmed. Dynamic effects are considerably small in the MRL type specimen. Also the influence of plastic zone on the crack arrest toughness is shown.Finally the present result is compared with the request of ASTM 2nd round robin test program for crack arrest toughness.     

A new type of hybrid fish-like microrobot

In order to develop a new type of fish-like microrobot with swimming, walking, and floating motions, in our past research, we developed a hybrid microrobot actuated by ionic conducting polymer film (ICPF) actuators. But the microrobot had some problems in walking and floating motions. In this paper, we propose a concept of hybrid microrobot (see Fig. 1). The microrobot is actuated by a pair of caudal fins, a base with legs and an array of artificial swim bladders. We have developed a prototype of the base with legs and one artificial swim bladder, respectively, and carried out experiments for evaluating their characteristics. Experimental results show the base with legs can realize walking speed of 6 mm/s and rotating speed of 7.1 degrees/s respectively, and the prototype of the artificial swim bladder has a maximum floatage of 2.6 mN. The experimental results also indicate that the microrobot has some advantages, such as walking motion with 2 degrees of freedom, the walking ability on rough surface (sand paper), the controllable floatage, etc. This kind of fish-like microrobot is expected for industrial and medical applications.