Hydrogen content variation for enhancing the lubricated tribological performance of DLC coatings with ester

There are many types of DLC (diamond-like carbon) coatings, which mainly differ from each other according to their hydrogen content, sp² and sp³-bonded carbon atoms and alloying elements (such as Ti, Cr, W or Zr). The lubricated tribological performance of these coatings depends on the lubricant. Controversially, the same lubricant delivers different tribological performances with differently produced DLC coatings. It has been observed that the presence of hydrogen has a remarkable effect on the tribological performance of DLC coatings in inert and vacuum environments. In this paper, the hydrogen content of two different types of DLC coatings, a-C:H:Me (metal containing hydrogenated amorphous carbon) and a-C:H, was varied, in order to obtain an optimized tribological behavior with a synthetic ester (TMP ester). The tribological performance of the coatings with TMP ester is examined in a pin-on-disk tribometer. It could be shown that increasing the hydrogen content in a DLC coating improves their tribological performance with TMP ester. Besides, a-C:H type of coatings is found to be more suitable for TMP ester regarding low friction coefficients.     

Emerging and re-emerging diseases of agricultural importance: why local perspectives matter

This paper examines local farmers’ perspectives about emerging and re-emerging infectious diseases (EIDs) of humans, crops and livestock and their impact on household food security in the Tanzania-Uganda interface ecosystem to the west of Lake Victoria. While it is increasingly accepted that such an approach could yield vital information not only regarding the extent of the impact of EIDs but also on practical strategies for their control, recent studies have examined only a narrow part of the disease-food security spectrum, often lacking a clear analysis of how local people conceptualise the co-occurrence, interactions and impact on food security of multiple plant, animal and human disease afflictions. Findings of the present study reveal that farmers perceive diseases as products of wider social, economic, environmental and institutional realities. They employ a wide range of names to describe disease problems and often such labels have nothing in common with the binomial nomenclature used in scientific taxonomy. Frequently, local people’s perceptions of severity of the impact of disease on food security are at variance with views held by experts. Consequently, disease control measures and strategies advocated by experts and policy makers are often not adhered to. This paper reveals that local or emic perspectives on diseases not only convey the sense of how local people feel and think about a particular disease but also how such knowledge shapes their response effort. Finally, the paper argues for a strategy to harness and incorporate aspects of local perspectives and practices into formal disease control programmes.     

Investigation of sodium sulfate phase transitions in a porous material using humidity- and temperature-controlled X-ray diffraction

Crystals growing in confined spaces can generate stress and are a major cause of damage in porous materials. To investigate such deleterious processes, appropriate in situ techniques are required. This paper describes the use of X-ray diffractometry under controlled conditions of temperature and relative humidity (RH-XRD) for the direct observation of phase transition reactions in a porous substrate. An improved environmental chamber without temperature gradients is presented and applied to the investigation of phase transformations in the system Na2SO4 + H2O. This salt is generally considered as particularly damaging and frequently used in accelerated weathering tests. It is demonstrated that RH-XRD can be successfully applied for the direct observation of several relevant phase transitions in glass frits used as porous substrates. The conversion of Na2SO4(III) to Na2SO4(V) and the hydration of Na2SO4(V) both proceed fairly rapidly as true solid-state reactions without deliquescence of the educt phases. In contrast, crystallization from solution is kinetically hindered as there is a strong tendency of aqueous Na2SO4 to form supersaturated solutions also in narrow pores. The important implications of this behavior of the salt are also briefly discussed in the paper.     

3D optical coherence tomography as new tool for microscopic investigations of nucleate boiling on heated surfaces

Boiling phenomena are an important aspect in security and efficiency for technical applications with high heat flux like nuclear reactors. This study presents optical coherence tomography (OCT) as a novel modality for three-dimensional and two-dimensional time resolved imaging of nucleate boiling on heated surfaces on a microscopic scale with high spatial (<10 μm) and temporal (>25 frames per second) resolution. Within this study, a borosilicate glass plate coated with an optically transparent and electrically conductive indium tin oxide (ITO) layer with a thickness of approximately 100 nm was used as heating surface. The combination of these two properties allows optical inspection of the nucleate boiling from the backside by OCT focused on the formation, growth and detachment of single bubbles. We demonstrated for the first time that OCT is an excellent tool to acquire two-dimensional and three-dimensional images of the base of vapor bubbles from the backside of the heated surface. The acquired images allow for instance the temporally resolved measurement of the bubble diameter, diameter of the bubble base and the contact angle. Exploiting the phase information of the acquired OCT signal stacks allows imaging the movement of the bubble surrounding fluid. We think that OCT will provide many new insights into the boiling phenomena at the bubble base. The recent enhancement of the acquisition rates of OCT systems will facilitate four-dimensional imaging of single bubble evaporation procedures in the nearer future.     

Effects of modality change on health-related quality of life

Patients with end‐stage renal disease (ESRD) requiring renal replacement have impaired health‐related quality of life (HRQoL), and there is general consensus that HRQoL improves with successful transplant and evidence of improvement with frequent hemodialysis. This study reports changes in HRQoL associated with changes in treatment modality to daily hemodialysis (DHD) and transplant among patients requiring renal replacement. This cohort study had assessments at baseline and 6‐month following modality change. Subjects were nondiabetic individuals receiving conventional hemodialysis who (a) remained on conventional hemodialysis (n = 13), (b) changed to daily hemodialysis (DHD) (n = 10), or (c) received a living donor transplant (n = 20). Thirty‐four healthy controls were assessed once for comparison. HRQoL was measured using the Kidney Disease Quality of Life Instrument. The Physical Functioning and Physical Composite Scale scores were primary outcomes. Transplantation resulted in significant improvements in six of eight generic scales and the physical composite scale (PCS). Those changing to DHD had significant improvements in Physical Function and PCS scales. Those remaining on dialysis remained lower than controls on all scales except for Vitality; the transplant group remained lower than controls only on the Vitality and General Health scales. Transplant resulted in significant improvements in four of the seven disease‐specific scales (symptoms, effects, and burden of kidney disease, work). DHD resulted in improvements in the effects of kidney disease. Modality change to transplant results in significant improvement in HRQoL, achieving levels similar to controls. Change to daily hemodialysis improves only select HRQoL domains and remains low in disease‐specific domains.     

Prospective reciprocal relations between physical activity and depression in female adolescents.

Objective: Although an inverse correlation between physical activity and depression among adolescents has been found in research, this relation has seldom been examined prospectively. Thus, we tested whether physical activity reduces risk for future escalations in depression and whether depression decreases likelihood of future change in physical activity. Method: Data from a longitudinal study involving annual assessments of 496 adolescent girls (mean age = 13 years, SD = 0.73) followed over a 6-year period were analyzed to address these questions. Results: Using analyses that controlled for several covariates, we found that physical activity significantly reduced risk for future increases in depressive symptoms and risk for onset of major–minor depression. Further, depressive symptoms and major–minor depression significantly reduced future physical activity. However, predictive effects were modest for both. Conclusions: Results support a bidirectional relation between exercise and depression and imply that interventions that increase physical activity may reduce risk for depression among this high-risk population. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Influence of Strain Rate,Temperature, Plastic Strain,and Microstructure on the Strain Rate Sensitivity of Automotive Sheet Steels

This work identifies the influence of strain rate, temperature, plastic strain, and microstructure on the strain rate sensitivity of automotive sheet steel grades in crash conditions. The strain rate sensitivity m has been determined by means of dynamic tensile tests in the strain rate range 10^?3–200 s^?1 and in the temperature range 233–373 K. The dynamic flow curves have been tested by means of servohydraulic tensile testing. The strain rate sensitivity decreases with increasing plastic strain due to a gradual exhausting of work hardening potential combined with adiabatic softening effects. The strain rate sensitivity is improved with decreasing temperature and increasing strain rate, according to the thermally activated deformation mechanism. The m‐value is reduced with increasing strength level, this decrease being most pronounced for steels with a yield strength below 400 MPa. Solid solution alloying with manganese, silicon, and especially phosphorous elements lowers the strain rate sensitivity significantly. Second phase hardening with bainite and martensite as the second constituent in a ferritic matrix reduces the strain rate sensitivity of automotive sheet steels. A statistical modeling is proposed to correlate the m‐value with the corresponding quasistatic tensile flow stress.     

Failure probability prediction based on condition monitoring data of wind energy systems for spare parts supply

The feasibility of maintenance processes relies on the availability of spare parts. Spare part inventory planning is capital intensive. It is based on demand forecasting, which possesses a high potential in reducing inventories. Even if condition monitoring systems are installed in technical systems, condition monitoring information is barely used to predict the failure probability of units. Therefore, an enhanced forecast model, which integrates SCADA information, has been developed. This leads to more accurate spare part demand forecasts. The approach presented in the paper is based on data mining, the proportional hazards model (PHM) and a binomial distribution. It has been validated with maintenance data of wind energy systems.