FPGA based generic RO TRNG architecture for image confusion

Multimedia Tools and Applications - True Random Number Generator (TRNG) has become a central element of today’s secure communication. TRNGs developed through FPGA implementation have a...     

Surface characterization of passive film formed on nitrogen ion implanted Ti-6Al-4V and Ti-6Al-7Nb alloys using SIMS

The aim of this paper is to study the effect of N⁺ ion implantation on corrosion and phase formation on the implanted surfaces of Ti-6Al-4V and Ti-6Al-7Nb alloys. Nitrogen ion was implanted on Ti-6Al-4V and Ti-6Al-7Nb alloys at an energy of 70 and 100 keV, respectively using a 150 keV accelerator at different doses ranging from 5 × 10¹⁵ to 2.5 × 10¹⁷ ions/cm². Electrochemical studies have been carried out in Ringer’s solution in order to determine the optimum dose that can give good corrosion resistance in a simulated body fluid condition. The implanted surfaces of such modified doses were electrochemically passivated at 1.0 V for an hour. Secondary ion mass spectroscopy was used to study and characterize titanium oxide and titanium nitride layers produced on implanted surface and to correlate them with the corrosion resistance. The nature of the passive film of the implanted-passivated specimen was compared with the unimplanted-passivated as well as as-implanted specimens.     

Electrochemical copolymerization and characterization of aniline and isoprene in aqueous p‐toluene sulfonic acid solution

Uniform and adherent copolymer coating of poly(aniline‐co‐isoprene) was successfully formed on low‐carbon‐steel electrodes by potentiostatic electropolymerization. Electropolymerization was performed by using aqueous p‐toluene sulfonic acid solution as electrolyte. Applied potential and feed ratios of monomers (aniline and isoprene) were systematically varied and the reactions were done under aqueous conditions. The copolymer coatings were characterized by infrared spectroscopy and the formation of copolymer was confirmed by the presence of aliphatic secondary amine, aromatic secondary amine, and aliphatic CH stretch groups. The electronic structure of the copolymers was further investigated by using UV/Vis absorption spectroscopy. The electrochemistry of the formation of copolymers was studied by using cyclic voltammetry. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 84: 184–192, 2002; DOI 10.1002/app.10298     

Experimental and Computational Studies of Bis(thiourea) Lead Chloride: Semi-organic Material for NLO Applications

Silicon - Non liner optical single crystals of bis(thiourea) lead chloride (BTLC), belonging to the semi-organic material category, have been prepared by a slow solvent evaporation process. The...     

Studies on oxidation of benzo [a] pyrene by sunlight and ozone

The destruction of the carcinogen benzo[a]pyrene (BaP) by light is well known; laboratory workers are routinely advised to cover fluorescent lamps with yellow filters while treating samples containing BaP. However until recently the mechanism of oxidation by sunlight and ozone had not been studied in detail. Concentrations of benzo[a]pyrene in urban air are in the range of 5–10 μg/1000 m³. Oxidant concentrations (predominantly in the form of ozone) are reported to be in the range of 0.01 ppm (22 μg per m³). Thus a sampling system with a filter paper would filter about 22,000 μg of ozone passing through and collect about 5 μg of BaP for analysis. The effect of interactions of such large ozone concentrations with BaP deposited on the filter paper is reported; data for the oxidation rates for benzo[a]pyrene coated on quartz surface and exposed to ozone or sunlight are presented. The oxidation products were analysed by thin-layer chromatography and highpressure liquid chromatography. From about eight products detected in these experiments, three have been identified as quinones based on UV-absorption spectrometry and mass spectrometry. Oxidation rates as high as 100% per hour of exposure are observed when less than 0.1 μg of BaP is coated inside the quartz tubes and exposed to ozone or sunlight. Oxidation rates for benzo[a]pyrene (using tritiated BaP) were determined for two types of experimental conditions. In the first set, tritiated BaP was spotted onto a glass fibre paper and sampling continued for 24 h; the loss of BaP was found to be 88%. In the second set tritiated BaP was spotted at intervals of one hour, for eight hours, while sampling is being carried out and the loss of BaP during the period was estimated to be 50%.     

Effect of metal-ion-to-fuel ratio on the phase formation of bioceramic phosphates synthesized by self-propagating combustion

Synthetic calcium hydroxyapatite (HAP, Ca₁₀ (PO₄)₆ (OH)₂) is a well-known bioceramic material used in orthopedic and dental applications because of its excellent biocompatibility and bone-bonding ability due to its structural and compositional similarity to human bone. Here we report, for the first time, the synthesis of HAP by combustion employing tartaric acid as a fuel. Calcium nitrate is used as the source of calcium and diammonium hydrogen phosphate serves as the source of phosphate ions. Reaction processing parameters such as the pH, fuel-oxidant ratio and autoignition temperature are controlled and monitored. The products were characterized by powder x-ray diffraction, which revealed the formation of a hexagonal hydroxyapatite phase. Fourier transform infrared spectroscopy (FT-IR) spectra showed that the substitution of a carbonate ion occurs at the phosphate site. The morphology of the particles was imaged by scanning electron microscopy, which also revealed that the particles are of submicron size. Thermal analysis showed that the phase formation takes place at the time of combustion. Surface area and porosity analysis showed that the surface area is high and that the pores are of nanometer size. The mean grain size of the HAP powder, determined by the Debye–Scherrer formula, is in the range 20–30 nm. Chemical analyses to determine the Ca : P atomic ratio in synthesized ceramics were performed, and it was found to be 1 : 1.66.     

Mining the Web's link structure

The Web is a hypertext body of approximately 300 million pages that continues to grow at roughly a million pages per day. Page variation is more prodigious than the data's raw scale: taken as a whole, the set of Web pages lacks a unifying structure and shows far more authoring style and content variation than that seen in traditional text document collections. This level of complexity makes an “off-the-shelf” database management and information retrieval solution impossible. To date, index based search engines for the Web have been the primary tool by which users search for information. Such engines can build giant indices that let you quickly retrieve the set of all Web pages containing a given word or string. Experienced users can make effective use of such engines for tasks that can be solved by searching for tightly constrained key words and phrases. These search engines are, however, unsuited for a wide range of equally important tasks. In particular, a topic of any breadth will typically contain several thousand or million relevant Web pages. How then, from this sea of pages, should a search engine select the correct ones-those of most value to the user? Clever is a search engine that analyzes hyperlinks to uncover two types of pages: authorities, which provide the best source of information on a given topic; and hubs, which provide collections of links to authorities. We outline the thinking that went into Clever's design, report briefly on a study that compared Clever's performance to that of Yahoo and AltaVista, and examine how our system is being extended and updated     

Determination of substrate specificity for peptide deformylase through the screening of a combinatorial peptide library

Costimulatory molecules are critical in mediating Fas-dependent direct and bystander lysis. In direct lysis, the APC is the Fas-positive target. It presents Ag to the T cell, thereby activating the T cell. The activated T cell then up-regulates FasL, allowing it to kill the APC. In bystander lysis, the APC again induces FasL expression on the T cell, but the target is a third Fas-positive cell that may lack the appropriate MHC-restricting element to activate the T cell. This study shows that ICAM-1 and B7-1 can serve as important adhesion molecules in direct killing using CD4+ T cell effectors. In bystander killing, B7-1 appears to act as a signaling molecule as well. It has been demonstrated that lpr and gld mice are less susceptible to experimental allergic encephalomyelitis than their wild-type counterparts. In this study, we show that although microglia are poor targets of direct killing, they are capable of stimulating myelin basic protein-specific T cells to kill innocent Fas-positive targets. This presents a possible mechanism for the pathogenesis of experimental allergic encephalomyelitis.     

Assessment and modelling of the viability of a solar heating system for aquatic centres in southern Australia

Aquatic centres are large users of energy for water and space heating with an energy intensity which can be up to seven times that of a commercial office building in Australia. Much of the energy is used to heat water to relatively low temperatures, and therefore, solar energy technology is capable of providing this energy. In the residential sector, solar thermal systems for heating water and swimming pools are well-established. This is not the case for commercial swimming pools i.e. aquatic centres. In Australia, a program to encourage commercial pool operators to install solar systems was funded in the early 1980s. This paper has investigated the current use of and attitudes to solar systems in commercial pools through a survey of municipal pool operators in Victoria, southern Australia. The survey found that there has been very little increase in the use of solar energy and that perceived barriers to the use of the technology remain the same as they were nearly 30 years ago. Lack of roof area, poor payback periods and an inability of solar to meet pool heating needs are the most common misconceptions. The paper investigates these misconceptions by analysing the hot water needs of a large aquatic centre in Melbourne. It was found that there was sufficient roof area to accommodate a solar system that would provide a solar fraction of 0.60 and the simple payback period for a solar system using unglazed solar collectors was approximately 6.7 years at current gas prices. These are predicted to rise significantly making solar energy an even more attractive proposition for commercial pool heating. Failure of past incentives to stimulate the uptake of solar pool heating systems necessitates a revised approach. Key stakeholders (industry bodies, local governments, pool operators, manufacturers, relevant HVAC consultants and research organisations) all need to be involved in an exemplar project to demonstrate the technology’s viability for aquatic centres.     

Integrated Framework for Quantifying and Predicting Weather-Related Highway Construction Delays

Constant exposure to the environment makes highway construction highly dependent on weather. However, highway construction contracts are often unclear about the potential influence of weather-related delays on highway construction project schedules. There is a need to discourage litigation arising from weather-related delays by including in contracts a reasonable number of nonwork days as a consequence of adverse weather and providing an equitable criteria for the course of action when the predictions in the contracts turn out to be inaccurate. To address this need, an integrated framework consisting of the following two key components is proposed: (1) identification of attributes of weather that cause construction delays and (2) generation of synthetic weather sequences using a stochastic weather generator to quantify and provide probabilistic forecasts of weather threshold values. The utility of this framework is demonstrated through its application to construction work on a project in Texas. The use of probabilistic forecast of construction delay attributes provided by a semiparametric weather generator in this research is an example of interdisciplinary study to help address this problem. The result of the research is better decision support for agencies who wish to author contracts that more equitably allow for the influence of weather during construction.