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101.
Simoen E. Eneman G. Verheyen P. Loo R. Kristin De Meyer Claeys C. 《Electron Devices, IEEE Transactions on》2006,53(5):1039-1047
The impact of different processing factors on the low-frequency (LF) noise of nMOSFETs fabricated in strained-silicon (SSi) substrates will be described. It is shown that the use of an SSi substrate can yield improved LF noise performance compared with standard Czochralski silicon material. This is demonstrated for both full-wafer and selective epitaxial SSi material. The lower 1/f noise points to an improved gate oxide quality, i.e., with a lower interface and bulk defect density, and is correlated with the low-field mobility or transconductance of the transistors. At the same time, it will be demonstrated that there exist defect-related LF noise mechanisms, which generally give rise to excess generation-recombination (GR) noise. Associated with this GR noise, a degradation of either the OFF-state leakage current or the mobility (transconductance) of the devices is observed. It is clear that noise is a sensitive parameter to local defectiveness and may be a useful tool for both materials' characterization and the analysis of processing-related device degradation mechanisms. 相似文献
102.
During thermochemical conversion of biological material in a fluidized bed reactor the nutrients are remaining as dust in the product gas. Hot gas filtration represents a possibility to recover these minerals. The characteristics of this gas add up new technical tasks. The following article gives an account of long lasting experience of operation and optimization in a pilot plant. 相似文献
103.
Kristin Schrder Stephan Enthaler Benoît Join Kathrin Junge Matthias Beller 《Advanced Synthesis u0026amp; Catalysis》2010,352(10):1771-1778
The combination of iron(III) chloride, pyridine‐2,6‐dicarboxylic acid and formamidine ligands allows for the epoxidation of styrenes and conjugated dienes in excellent chemoselectivity and yields. 相似文献
104.
The flame retardancy mechanisms of three aryl phosphates, triphenyl phosphate (TPP), resorcinol bis(diphenyl phosphate) (RDP) and bisphenol A bis(diphenyl phosphate) (BDP), in a polycarbonate/acrylonitrile–butadiene–styrene (PC/ABS) blend are investigated and compared. Further, the influence of polytetrafluorethylene (PTFE) on viscosity and thermal decomposition is discussed in the systems PC/ABS and PC/ABS + BDP. Mechanisms are proposed based on the results of various methods. Thermogravimetric analysis, Fourier transform infrared spectroscopy and kinetics are used to study the pyrolysis. The fire behaviour is studied by means of cone calorimeter measurements at different heat fluxes and the flammability is specified by limiting oxygen index (LOI) and UL 94. Rheology measurements are used to illuminate the changed dripping behaviour due to PTFE. TPP shows only a gas phase action. RDP shows mainly a gas phase action and some condensed phase action. BDP shows a crucial condensed phase action in addition to a gas phase action. TPP and RDP are somewhat superior in terms of flammability (LOI), whereas BDP shows superior performance in forced flaming combustion (cone calorimeter). Synergistic effects between PTFE and BDP are found. Copyright © 2007 Society of Chemical Industry 相似文献
105.
Silvia Baena‐Ruano Carlos Jiménez‐Ot Inés M. Santos‐Dueñas Jorge E. Jiménez‐Hornero José L. Bonilla‐Venceslada Carmen Álvarez‐Cáliz Isidoro García‐García 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2010,85(7):908-912
BACKGROUND: The acetification process needs an overall study of the variables influencing it in order to establish their optimum values. Based on industrial experience and available literature, including a recently proposed model by the authors, among the variables most strongly influencing the acetification process are the ethanol concentration at the time the reactor is unloaded, the unloaded volume and the loading rate. To ensure economically efficient industrial production of vinegar, and to check the predictions of the aforementioned model, the influence of the final ethanol concentration at unloading time on the mean acetification rate and on productivity has been studied in this work. RESULTS: An increase in the final ethanol concentration from 0.5 to 3.5% (v/v) increased the mean overall acetification rate and acetic acid production by 38 and 26%, respectively. The increase was established mainly during the loading phase. CONCLUSIONS: The final ethanol concentration is a key variable for process optimization. If a high rate is desired then a product containing much unused substrate will be obtained, which may be industrially unacceptable. These results suggest the necessity to investigate other possibilities when high values for yield and productivity must to be achieved. Copyright © 2010 Society of Chemical Industry 相似文献
106.
Dirk Mehlhorn Dr. Rustem Valiullin Prof. Jörg Kärger Kristin Schumann Dr. Alfons Brandt Dr. Baldur Unger 《化学,工程师,技术》2011,83(12):2251-2259
The pulsed field gradient (PFG) NMR technique is applied for exploring the diffusion behavior of guest molecules in binderless NaX beads in comparison with the zeolite powder employed for their production. With both probe molecules applied (water, n‐hexane), the diffusivities in the powder and the beads are found to essentially coincide as long as the diffusion path lengths are sufficiently small in comparison with the extension of the individual particles (crystallites) of the powder. With increasing diffusion path lengths, characteristic deviations become observable that can be attributed to the differences in long‐range mass transfer through the intercrystalline void volume of the bed of crystallites and within the individual beads of the binderless molecular sieve, respectively. With these studies, PFG NMR demonstrates its potentials for simultaneously recording mass transfer phenomena in both the micro‐ and macropores of commercially produced binderless molecular sieves. 相似文献
107.
Leonardo Dueñas‐Osorio Javier Rojo 《Computer-Aided Civil and Infrastructure Engineering》2011,26(2):111-128
Abstract: The increased susceptibility of lifeline systems to failure due to aging and external hazards requires efficient methods to quantify their reliability and related uncertainty. Monte Carlo simulation techniques for network‐level reliability and uncertainty assessment usually require large computational experiments. Also, available analytical approaches apply mainly to simple network topologies, and are limited to providing average values, low order moments, or confidence bounds of reliability metrics. This study introduces a closed form technique to obtain the entire probability distribution of a reliability metric of customer service availability (CSA) for generic radial lifeline systems. A special case of this general formulation reduces to a simple sum of products equation, for which a recursive algorithm that exploits its structure is presented. This special‐case algorithm computes the probability mass function (PMF) of CSA for systems with M elements in operations, relative to conventional operations, and opens the possibility of finding recursive algorithms for the general radial case. Parametric models that approximate the CSA metric are also explored and their errors quantified. The proposed radial topology reliability assessment tools and resulting probability distributions provide infrastructure owners with critical insights for informed operation and maintenance decision making under uncertainty. 相似文献
108.
This paper describes the application of stable carbon isotope ratios as natural tracers in hydrocarbon reservoirs. Detailed mapping of hydrocarbon composition from closely spaced mud gas samples taken during drilling of horizontal production wells allows for the identification of reservoir compartmentalisation. This applies to reservoirs where fluid heterogeneities exist as a result of filling history or post accumulation hydrocarbon alteration. Case examples assessing fault seal properties are provided. An additional application of the methodology presented is in the detection of subtle spatial variations in reservoir rock quality that may have an influence on fluid flow within the reservoir.In several cases where fluid heterogeneities were detected in horizontal wells, subsequent time-lapse sampling of produced gas and stable carbon isotope measurements of these samples gave means for production allocation. The identification of lost production permitted the identification of an infill well target, and resulted in increased oil recovery by the drilling of a new production well.The use of gas isotopes in the evaluation of reservoir fluid heterogeneities and as natural tracers in the monitoring of reservoir fluids has proved useful in the understanding of reservoir connectivity and fluid flow. The work processes described give valuable insights and help improve reservoir management. 相似文献
109.
110.
Clinical and some epidemiological data conflict concerning the likelihood of suicide attempt in individuals with panic disorder (PD). The purpose of this study was to illuminate the panic disorder-suicide attempt association in the National Comorbidity Survey (NCS; R. C. Kessler et al., 1994). Specifically, suicide attempt histories of those 5,872 respondents answering "yes" or "no" to the suicide attempt question were regressed against lifetime diagnostic histories. Lifetime PD history, in the presence of other disorders, was unrelated to elevated risk of suicide attempt and did not account for additional variance. PD respondents who had made a suicide attempt were characterized by Comorbidity. Epidemiological respondents with lifetime histories of PD alone are not at heightened risk for self-reported suicide attempt. (PsycINFO Database Record (c) 2010 APA, all rights reserved) 相似文献