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61.
Kang Cui Kunal S. Mali Klaus Müllen Michael Walter Steven De Feyter Stijn F. L. Mertens 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(46)
Ionic self‐assembly of charged molecular building blocks relies on the interplay between long‐range electrostatic forces and short‐range, often cooperative, supramolecular interactions, yet has been seldom studied in two dimensions at the solid–liquid interface. Here, we demonstrate anion‐driven switching of two‐dimensional (2D) crystal structure at the Au(111)/octanoic acid interface. Using scanning tunneling microscopy (STM), three organic salts with identical polyaromatic cation (PQPC6+) but different anions (perchlorate, anthraquinonedisulfonate, benzenesulfonate) are shown to form distinct, highly ordered self‐assembled structures. Reversible switching of the supramolecular arrangement is demonstrated by in situ exchange of the anion on the pre‐formed adlayer, by changing the concentration ratio between the incoming and outgoing anion. Density functional theory (DFT) calculations reveal that perchlorate is highly mobile in the adlayer, and corroborate why this anion is only resolved transiently in STM. Surprisingly, the templating effect of the anion persists even where it does not become part of the adlayer 2D fabric, which we ascribe to differences in stabilization of cation conformations by the anion. Our results provide important insight into the structuring of mixed anion–cation adlayers. This is essential in the design of tectons for ionic self‐assembled superstructures and biomimetic adaptive materials and valuable also to understand adsorbate–adsorbate interactions in heterogeneous catalysis. 相似文献
62.
Sahebrao B. Kashid Jaya R. Lakkakula Deepak S. Chauhan Rohit Srivastava Rajesh W. Raut 《IET nanobiotechnology / IET》2017,11(8):1046
Cotton fibres coated with biogenically fabricated silver nanoparticles (SNPs) are most sought material because of their enhanced activity and biocompatibility. After successful synthesis of SNPs on cotton fibres using leaf extract of Vitex negundo Linn, the fibres were studied using diffuse reflectance spectroscopy, scanning electron microscopy, nanoparticle tracking analysis, energy dispersive X‐ray, and inductively coupled plasma atomic emission spectrometry. The characterisation revealed uniformly distributed spherical agglomerates of SNPs having individual particle size around 50 nm with the deposition load of 423 μg of silver per gram of cotton. Antimicrobial assay of cotton–SNPs fibres showed effective performance against pathogenic bacteria and fungi. The method is biogenic, environmentally benign, rapid, and cost‐effective, producing highly biocompatible antimicrobial coating required for the healthcare industry.Inspec keywords: cotton, health care, nanoparticles, coatings, silver, fibres, nanofabrication, scanning electron microscopy, X‐ray chemical analysis, atomic emission spectroscopy, plasma applications, microorganisms, biotechnologyOther keywords: biocompatible antimicrobial cotton fibre coating, healthcare industry, bioorganic‐coated silver nanoparticle synthesis, biogenically fabricated silver nanoparticle, SNP, leaf extraction, Vitex negundo Linn, diffuse reflectance spectroscopy, scanning electron microscopy, nanoparticle tracking analysis, energy dispersive X‐ray spectrometry, inductively coupled plasma atomic emission spectrometry, uniformly distributed spherical agglomerate, antimicrobial assay, pathogenic bacteria, fungi, Ag 相似文献
63.
Influence of residual thermal stresses on fatigue crack growth life of discontinuous reinforcements in metal matrix composites 下载免费PDF全文
The fatigue life prediction model based on crack propagation from micro-structural features is derived and presented for planar and randomly oriented Discontinuous Reinforced Metal Matrix Composites (DRMMCs). The model contains the influence of micro-structural properties such as aspect ratio, volume fraction of particle/fibre and constraint between particle and the matrix. The effect of residual thermal stresses generated within the matrix during development of composite is considered. The particle/fibre plays a dominant role in the development of the cyclic plastic zone size ahead of the crack tip; moreover, it enhances the cyclic plastic deformation characteristics of DRMMC. The theoretical model-based evaluations for low cycle fatigue in DRMMCs are within the proximity of the experimental results. 相似文献
64.
Priyam Sinha Shruti Srivastava Nidhi Mishra Dhananjay Kumar Singh Suaib Luqman Debabrata Chanda 《Drug development and industrial pharmacy》2016,42(9):1434-1445
Purpose: To develop and optimize nanoemulsion (NE)-based emulgel (EG) formulation as a potential vehicle for topical delivery of tea tree oil (TTO).Methodology: Central composite design was adopted for optimizing the processing conditions for NE preparation by high energy emulsification method viz. surfactant concentration, co-surfactant concentration, and stirring speed. The optimized NE was developed into emulgel (EG) using pH sensitive polymer Carbopol 940 and triethanolamine as alkalizer. The prepared EG was evaluated for its pH, viscosity, and texture parameters, ex vivo permeation at 37?°C and stability. Antimicrobial evaluation of EG in comparison to conventional gel and pure TTO was also carried out against selected microbial strains.Results and discussion: Optimized NE had particle size and zeta potential of 16.23?±?0.411?nm and 36.11?±?1.234?mV, respectively. TEM analysis revealed the spherical shape of droplets. The pH of EG (5.57?±?0.05?) was found to be in accordance with the range of human skin pH. EG also illustrated efficient permeation (79.58?μL/cm2) and flux value (JSS) of 7.96?μL cm2/h through skin in 10?h. Viscosity and texture parameters, firmness (9.3?±?0.08?g), spreadability (2.26?±?0.06?mJ), extrudability (61.6?±?0.05?mJ), and adhesiveness (8.66?±?0.08?g) depict its suitability for topical application. Antimicrobial evaluation of EG with same amount of TTO as conventional gel revealed broader zones of growth inhibitions against all the selected microbial strains. Moreover, EG was also found to be nonirritant (PII 0.0833). These parameters were consistent over 90 d.Conclusion: TTO EG turned out to be a promising vehicle for the topical delivery of TTO with enhanced therapeutic efficacy. 相似文献
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68.
SV Singh PJ Benson X Hu A Pal H Xia SK Srivastava S Awasthi HA Zaren JL Orchard YC Awasthi 《Canadian Metallurgical Quarterly》1998,128(2):197-204
A commercial patient dose verification system utilizing non-invasive metal oxide semiconductor field effect transistor (MOSFET) dosimeters originally designed for radiotherapy applications has been evaluated for use at diagnostic energy levels. The system features multiple dosimeters that may be used to monitor entrance or exit skin dose and intracavity doses in phantoms in real time. We have characterized both the standard MOSFET dosimeter designed for radiotherapy dose verification and a newly developed "high sensitivity" MOSFET dosimeter designed for lower dose measurements. The sensitivity, linearity, angular response, post-exposure response, and physical characteristics were evaluated. The average sensitivity (free in air, including backscatter) of the radiotherapy MOSFET dosimeters ranged from 3.55 x 10(4) mV per C kg(-1) (9.2 mV R(-1)) to 4.87 x 10(4) mV per C kg(-1) (12.6 mV R(-1)) depending on the energy of the x-ray field. The sensitivity of the "high sensitivity" MOSFET dosimeters ranged from 1.15 x 10(5) mV per C kg(-1) (29.7 mV R(-1)) to 1.38 x 10(5) mV per C kg(-1) (35.7 mV R(-1)) depending on the energy of the x-ray field. The high sensitivity dosimeters demonstrated excellent linearity at high energies (90 and 120 kVp) and acceptable linearity at lower energies (60 kVp). The angular response was significant for free-in-air exposures, as illustrated by the sensitivity differences between the two sides of the dosimeter, but was excellent for measurements within a tissue equivalent cylinder. The post-exposure drift response is a complicated but reproducible function of time. Real-time monitoring requires little if any corrections for the post-exposure drift response. The MOSFET dosimeter system brings some unique capabilities to diagnostic radiology dosimetry including small size, real-time capabilities, nondestructive measurement, good linearity, and a predictable angular response. 相似文献
69.
PVC-Based 2,2,2-Cryptand Sensor for Zinc Ions 总被引:1,自引:0,他引:1
A PVC-based membrane of 2,2,2-cryptand exhibits a very good response for Zn(2+) in a wide concentration range (from 2.06 ppm to 6.54 × 10(3) ppm) with a slope of 22.0 mV/decade of Zn(2+) concentration. The response time of the sensor is <10 s, and the membrane can be used for more than 3 months without any observed divergence in potentials. The proposed sensor exhibits very good selectivity for Zn(2+) over other cations and can be used in a wide pH range (2.8-7.0). It has also been possible to use this assembly as an indicator electrode in potentiometric titrations involving zinc ions. 相似文献
70.
Kunal Sain Abhishek Dasgupta Utpal Garain 《International Journal on Document Analysis and Recognition》2011,14(1):75-85
Performance evaluation of mathematical expression recognition systems is attempted. The proposed method assumes expressions
(input as well as recognition output) are coded following MathML or TEX/LaTEX (which also gets converted into MathML) format. Since any MathML representation follows a tree structure, evaluation of
performance has been modeled as a tree-matching problem. The tree corresponding to the expression generated by the recognizer
is compared with the groundtruthed one by comparing the corresponding Euler strings. The changes required to convert the tree
corresponding to the expression generated by the recognizer into the groundtruthed one are noted. The number of changes required
to make such a conversion is basically the distance between the trees. This distance gives the performance measure for the
system under testing. The proposed algorithm also pinpoints the positions of the changes in the output MathML file. Testing
of the proposed evaluation method considers a set of example groundtruthed expressions and their corresponding recognized
results produced by an expression recognition system. 相似文献