Electrochemical Faceting of polycrystalline platinum in HF solutions

The electrochemical faceting of polycrystalline (pc) platinum yielding a (100)-preferred oriented electrode surface was accomplished in HF solutions by applying to the pc platinum electrode a square wave potential perturbation at 1 kHz in the 0.2 to 1.3 V range (vs rhe). SEM patterns of the resulting surfaces were also obtained. For HF concentrations up to 2 M no appreciable influence of the electrolyte concentration on the electrochemical faceting was noticed. Otherwise, the voltammetric response of the (100)-type preferred oriented platinum surface in the H-adatom potential range when compared to previously reported data resulted remarkably sensitive to the electrolyte composition. The discussion of results was based on the non-equilibrium adsorption conditions for anions under the periodic perturbation.     

Epoxy paint failure in B-52 fuel tanks: Part II. Influence of DIEGME concentration in the fuel on the failure process

A model has been proposed to explain the failure of the original BMS10-39 epoxy paint on upper vertical surfaces in B-52 fuel tanks. The model involves interaction of the paint with DIEGME, a fuel system ice inhibitor (FSII) in jet fuel, that is distilled from the liquid fuel. In this communication, distillation experiments used to support the model are refined to better match the mass transfer of vapor from fuel in a B-52 fuel tank at close to room temperature. The interaction of these lower temperature distillates with the paint affirms the earlier model. On the basis of these experiments it is proposed that paint failure may be controlled or eliminated by reducing the level of DIEGME in the fuel. Proposed changes in military jet fuel composition are detailed.     

Integration of prior knowledge of measurement noise in kernel density classification

Samples can be measured with different precisions and reliabilities in different experiments, or even within the same experiment. These varying levels of measurement noise may deteriorate the performance of a pattern recognition system, if not treated with care. Here we seek to investigate the benefit of incorporating prior knowledge about measurement noise into system construction. We propose a kernel density classifier which integrates such prior knowledge. Instead of using an identical kernel for each sample, we transform the prior knowledge into a distinct kernel for each sample. The integration procedure is straightforward and easy to interpret. In addition, we show how to estimate the diverse measurement noise levels in a real world dataset. Compared to the basic methods, the new kernel density classifier can give a significantly better classification performance. As expected, this improvement is more obvious for small sample size datasets and large number of features.     

Highly resistant dispensing nozzles based on zirconium dioxide for profiled CBCM. Part 1. Structure and physicomechanical properties of materials based on zirconium dioxide for producing CBCM dispensing nozzles

Technology is developed for preparing refractory components made of partially stabilized zirconium dioxide using an isostatic compaction press. Technology is provided for manufacturing dispensing nozzles using combined and separately stabilized zirconium dioxide, and also indices of the refractories obtained and imported materials are compared. __________ Translated from Novye Ogneupory, No. 3, pp. 127–131, March 2008.     

A light refractory concrete for thermal insulation

Compositions have been developed for nonshrinking vibrocast thermally insulating light refractory concretes with densities of 1.0, 1.3, 1.5, and 1.8 g/cm³ for temperatures of use up to 1400°C. The structure and properties have been examined for the concrete of density 1.3 g/cm³. __________ Translated from Novye Ogneupory, No. 4, pp. 29–32, April, 2008.     

Secondary Aluminum Production Waste — A Raw Material for the Refractory Industry

Secondary aluminum waste products, and processes that occur during heating and mineral formation on introducing fine periclase powder into the composition of waste products are studied. It is demonstrated that secondary aluminum production waste may be used as a raw material for synthesizing aluminomagnesia spinels. Translated from Novye Ogneupory, No. 6, pp. 15–18, June 2008.     

Total and Fractional Performance of Granular Dust Traps in Refractory Production

Methods are proposed for designing interpolation models for the preliminary determination and subsequent forecasting of general and fractional breakthrough coefficients for dust used with granular filters, as employed in energy-saving and high-performance dust trapping from technological gases and ventilation discharges in refractory production. The models are supplied with nomograms, which makes them widely suitable for experts working in environmental protection at refractory-producing organizations. The main factors are identified that influence the performance. The results are of interest to experts in related areas of industry such as building materials and engineering ceramics and so on. Translated from Novye Ogneupory, No. 4, pp. 64–67, April, 2008.     

Testing a new composition of periclase spinel objects

On the basis of periclase powder (70%) and aluminomagnesia spinel (30%), synthesized from secondary aluminum production waste and caustic magnesite, test objects are produced of periclase spinel composition satisfying the requirements of GOST 1579-006-00190495-98. The articles are successfully tested in the working layer for lining tunnel furnace cars of OAO Kombinat Magnezit. __________ Translated from Novye Ogneupory, No. 8, pp. 16–17, August 2008.     

Granular-structure chromium-bearing refractories: Properties and uses

Results are presented on the corrosion resistance of chromium-bearing refractories of granular structure acted on by corrosive molten slags, metals, and glasses. It is possible to recommend these refractories to customers for particular conditions of use. Chromium-bearing refractories increase the working lives of furnaces considerably. __________ Translated from Novye Ogneupory, No. 1, pp. 55–61, January, 2008.