Evidence of flexoelectricity in polymer-dispersed liquid crystals

The linear electro-optic response of polymer-dispersed liquid crystal films has been studied. Micrometer-sized droplets of a cyanobiphenyl mixture (E7) were formed in a Norland Optical Adhesive 65 photopolymer by photopolymerization-induced phase separation. Samples with various average nematic droplet sizes were systematically investigated. The temperature dependence of the first-harmonic electro-optic spectra was obtained. Peculiar peaks and double peaks in the phase spectra were found at temperatures close to the clearing point. Samples with narrow distributions of droplet sizes were characterized by a double peak of the amplitude spectra in the low-frequency range. A flexoelectric origin of the first-harmonic spectra in confined nematic systems is discussed.     

Thermodynamics of Chemical Interactions in the CdTe–ZnTe–O2–C System during Melt Growth of Cd1 – x Zn x Te Crystals

Thermodynamic analysis is used to identify the possible chemical reactions of CdTe and ZnTe with the container material and gaseous atmosphere during Bridgman growth. Thermodynamic parameters of carbide and oxycarbide formation in the growth system are evaluated. The calculation results are consistent with the well-known fact that oxygen-containing impurities can be removed from the growth charge by calcination in hydrogen. Moreover, as shown in experiment, the removal of oxygen from the charge ensures a substantial decrease in the carbon content of the crystals.     

Phase regression approach for estimating the parameters of a noisy multifrequency signal

A novel approach for estimating the parameters of a multifrequency signal from discrete samples corrupted by additive noise is presented. An established mathematical model indicates that noise influence on the discrete phase and amplitude spectra is equivalent to additive phase and amplitude noise, respectively. On this basis, a simple algorithm is proposed to estimate the frequency and phase of each sinusoid component by linear regression on the phase spectra of segmented signal blocks, while an amplitude estimator is directly derived from the spectrum of the window function. The circular nature of the phase spectrum is thoroughly explored. Also, an algorithmic scheme is presented. The derived variances of the estimators show that for a noisy signal this approach provides superior accuracy over the traditional approaches. Simulations and engineering application confirm the validity of the presented method.     

Cyclic mode of neptunium, americium and curium transmutation in heavy-water reactor

Characteristics of process of transmutation of neptunium, americium and curium from spent nuclear fuel in heavy-water reactor during first 10 lifetimes and at transition to equilibrium mode are calculated. During transmutation, dangerous nuclides, first of all, ²⁴⁴Cm and ²³⁸Pu are accumulated. They cause an increase of radiotoxicity. At first 10 cycles of transmutation, the radiotoxicity is increased by 8.7 times in comparison with radiotoxicity of initial load of transmuted actinides. Heavy-water reactor with thermal power of 1000 MW can transmute neptunium, americium and curium extracted from 3.7 VVER-1000 type reactors. It means, that the required power of transmutation reactor makes about 8% of thermal power of VVER-1000 type reactors.     

Presenting information on the small-screen interface: effects of table formatting

This study explored strengths and limitations of table formatting choices by engaging twenty-eight participants in information searches in online tables, presented on a small-screen interface (Palm IIIc). Table length across conditions was held constant at three screens long (24 rows total) but varied from one to three screens wide (approximately 35, 70, and 105 characters per line). Target information was positioned in either the upper left, lower left, upper right, or lower right quadrants. Data collected were time on task, error rate, and level of participants' confidence in their answers. Experimenters found that increased horizontal scrolling imposed the heaviest burden on information search. This study supports restricting table widths to one screen on handheld computers. If necessary, however, tables can go to two screens wide without critical detriment to usability. While ruled line formatting is slightly better than interface character in providing visual support for the burden of horizontal scrolling, neither formatting option adequately compensates for the added burden.     

Optimization of a photopolymerizable holographic recording material based on polyvinylalcohol using angular responses

Acrylamide-based holographic recording materials have significant advantages and the composition of these materials has been optimized in terms of energetic sensitivity and diffraction efficiency. As a result, diffraction gratings with an efficiency of almost 80% for energetic exposures of 35 mJ/cm² and a spatial frequency of 1000 lines/mm in photosensitive films 65 μm thick have been obtained. In this paper we present the effects of intensity, thickness, and variation in the concentration of each component by studying the angular responses of the diffraction gratings recorded in each composition.     

1.6 Tbit/s (40/spl times/40 Gbit/s) DPSK transmission over 3/spl times/100 km of TeraLight fibre with direct detection

By transmitting 40 channels over 300 km of TeraLight fibre, it is shown that optical differential phase shift keying can be used in 100 GHz-spaced 40 Gbit/s systems, with direct detection and a simple receiving filter. Chromatic dispersion tolerance around 300 ps/nm is also measured, compared to 70 ps/nm for NRZ.     

Programmable group-delay module using binary polarization switching

We demonstrate the first programmable group-delay module based on polarization switching. With a unique binary tuning mechanism, the device can generate any differential group delay value from -45 to +45 ps with a resolution of 1.40 ps, or any true-time-delay value from 0 to 45 ps with a resolution of 0.7 ps. The delay varying speeds for both applications are under 1 ms and can be as fast as 0.1 ms. We evaluate both the dynamic and static performances of the device while paying special attention to its dynamic figures of merit for polarization-mode dispersion emulation and compensation applications. Our experiment shows that the device exhibits a negligible transient-effect induced power penalty (<0.2 dB) in a 10-Gb/s nonreturn-to-zero system.     

Positively Thermo‐Sensitive Monodisperse Core–Shell Microspheres

In this paper, we report on a novel family of monodisperse thermo‐sensitive core–shell hydrogel microspheres that is featured with high monodispersity and positively thermo‐responsive volume phase transition characteristics with tunable swelling kinetics, i.e., the particle swelling is induced by an increase rather than a decrease in temperature. The microspheres were fabricated in a three‐step process. In the first step, monodisperse poly(acrylamide‐co‐styrene) seeds were prepared by emulsifier‐free emulsion polymerization. In the second step, poly(acrylamide) or poly[acrylamide‐co‐(butyl methacrylate)] shells were fabricated on the microsphere seeds by free radical polymerization. In the third step, the core–shell microspheres with poly‐ (acrylamide)/poly(acrylic acid) based interpenetrating polymer network (IPN) shells were finished by a method of sequential IPN synthesis. The proposed monodisperse core–shell microspheres provide a new mode of the phase transition behavior for thermo‐sensitive “smart” or “intelligent” monodisperse micro‐actuators that is highly attractive for targeting drug delivery systems, chemical separations, sensors, and so on.     

Formation of C49-TiSi2 in flash memories: a nucleation controlled phenomenon?

The formation of Ti silicides has been examined in flash memories with 0.25 μm linewidth by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. It has been observed that, after the first rapid thermal process and the selective metal etch, there is no silicide on the source and on a majority of drain contacts while C49-TiSi₂ is found on the gate. A pre-amorphisation implant increases drastically the formation of C49-TiSi₂ in the drain zone while modifications of annealing conditions have little impact. These results indicate that the formation of C49-TiSi₂ is most likely controlled by nucleation and that this nucleation is sensitive to both the width and the length of the reaction zone. The formation of a Ti rich silicide may play an important role in this nucleation by decreasing the driving force for the formation of C49-TiSi₂. Curiously enough, the formation of C49-TiSi₂ appears thus as a major concern for the salicide process in flash memories.